Molasses alcohol

In more detail the nutrient medium used may contain sources of carbon such as starch, hydrolyzed starch, sugars such as lactose, maltose, dextrose, sucrose, or sugar sources such as molasses alcohols, such as glycerol and mannitol organic acids, such as citric acid and acetic acid and various natural products which may contain other nutrient materials in addition to carbonaceous substances. 

Molasses-Alcohol. — On overlaying 5 cc. of alcohol on 5 cc. of concentrated sulphuric acid, no rose-red zone should form within one hour at the contact-surfaces of the two liquids. 

Synonyms and trade names absolute alcohol, absolute ethanol, anhydrous alcohol, anhydrol, cologne spirit, molasses alcohol, potato ethanol, grain alcohol, spirit of wine, cologne spirit Use and exposure Ethyl alcohol is a flammable, colorless, and mildly toxic solvent. It is a versatile solvent and miscible in all proportions with water and many organic solvents it is incompatible with strong... 

The Business Scents Eau de Parfum formulation (Figure 9.1) contains 78% denatured ethanol. The source of this ethanol (e.g. synthetic or natural grain starch, sugar beet, or molasses alcohol) can give rise to a different odour in the end product, and thus it is important to know what type of alcohol is likely to be used. Denaturants (which deter... 

MOLASSES ALCOHOL (64-17-5) Forms explosive mixture with air [flash point 55°F/13°C 68°F/20°C (80%) 72°F/22°C (60%) 79°F/26°C (40%)]. Reacts, possibly violently, with strong oxidizers, bases, acetic anhydride, acetyl bromide, acetyl chloride, aliphatic amines, bromine pentafluoride, calcium oxide, cesium oxide, chloryl perchlorate, disulfuryl difluoride, ethylene glycol methyl ether, iodine heptafluoride, isocyanates, nitrosyl perchlorate, perchlorates, platinum, potassium-fert-butoxide, potassium, potassium oxide, potassium peroxide, phosphorus(III) oxide, silver nitrate, silver oxide, sulfuric acid, oleum, sodium, sodium hydrazide, sodium peroxide, sulfinyl cyanamide, tetrachlorosilane, s-triazine-2,4,6-triol, tiiethoxydialuminum tribromide, triethylaluminum, uranium fluoride, xenon tetrafluoride. Mixture with mercury nitrate(II) forms explosive mercury fulminate. Forms explosive complexes with perchlorates, magnesium perchlorate (forms ethyl perchlorate), silver perchlorate. Flow or agitation of substance may generate electrostatic charges due to low conductivity. 

SYNONYMS alcohol, cologne spirit, ethanol, ethyl hydrate, ethyl hydroxide, grain alcohol, methylcarbinol, molasses alcohol. 

GRAIN ALCOHOL METHYLCARBINOL MOLASSES ALCOHOL POTATO ALCOHOL... 

Essia Ngang, JJ-,F. Letourneau, E. Wolniewicz, and P. Villa. 1990. Inhibition of beet molasses alcoholic fermentation by lactobacilli. Appl. Microbiol. Biotech-nol. 33 490-493. 

Soluble in water and alcohol. It is a very feeble base. It occurs in beets and mangolds and many other plants, and can conveniently be prepared from beet molasses. 

Until World War 1 acetone was manufactured commercially by the dry distillation of calcium acetate from lime and pyroligneous acid (wood distillate) (9). During the war processes for acetic acid from acetylene and by fermentation supplanted the pyroligneous acid (10). In turn these methods were displaced by the process developed for the bacterial fermentation of carbohydrates (cornstarch and molasses) to acetone and alcohols (11). At one time Pubhcker Industries, Commercial Solvents, and National Distillers had combined biofermentation capacity of 22,700 metric tons of acetone per year. Biofermentation became noncompetitive around 1960 because of the economics of scale of the isopropyl alcohol dehydrogenation and cumene hydroperoxide processes. 

Microbial-enhanced oil recovery involves injection of carefully chosen microbes. Subsequent injection of a nutrient is sometimes employed to promote bacterial growth. Molasses is the nutrient of choice owing to its low (ca 100/t) cost. The main nutrient source for the microbes is often the cmde oil in the reservoir. A rapidly growing microbe population can reduce the permeabiHty of thief zones improving volumetric sweep efficiency. Microbes, particularly species of Clostridium and Bacillus, have also been used to produce surfactants, alcohols, solvents, and gases in situ (270). These chemicals improve waterflood oil displacement efficiency (see also Bioremediation (Supplement)). 

More recently, interest has developed in the use of enzymes to catalyze the hydrolysis of cellulose to glucose (25—27). Domestic or forest product wastes can be used to produce the fermentation substrate. Whereas there has been much research on alcohol fermentation, whether from cereal grains, molasses, or wood hydrolysis, the commercial practice of this technology is primarily for the industrial alcohol and beverage alcohol industries. About 100 plants have been built for fuel ethanol from com, but only a few continue to operate (28). 

The subject of fermentation alcohol has always been of considerable interest to several tropical countries, but until the oil crisis of 1973, other than Brazil (197), only India appeared to appreciate the importance of fermentation alcohol as a strategic material in its economy. Ethanol prices in India have been maintained at an extremely low level by processing cane molasses, which has been a waste product of negligible value (197). 

Acrolein has been detected in effluent water streams from industrial and municipal sources. Municipal effluents from Dayton, Ohio, for example, contained between 20 and 200 pg acrolein/L in 6 of 11 analyzed samples (USEPA 1980 Beauchamp et al. 1985). Acrolein is also a component of many foods, and processing may increase the acrolein content (USEPA 1980). Acrolein has been identified in raw turkey, potatoes, onions, coffee grounds, raw cocoa beans, alcoholic beverages, hops (USEPA 1980), white bread, sugarcane molasses, souring salted pork, and cooked bluefin tuna (Thunnus thynnus) (Beauchamp et al. 1985). 

Rubbing alcohol Lamp oil Note Color the lamp oil and rubbing alcohol with food dyes Molasses Antifreeze Ivory liquid (white) Palmolive liquid (green) T TM Joy Dawn (blue) Mineral oil All layers, except the mineral oil, can be colored with a drop or two of food coloring... 

Butyl alcohol can be obtained from carbohydrates (such as molasses and grain) by fermentation. Acetone and ethanol are also produced. Synthetic processes account for the majority of current-day production. Propylene and synthesis gas give -butyl alcohol. Isobutyl alcohol is a byproduct. 

A plant for the fermentation of sulfite waste liquor in America was built at Mechanicsville, New York, by the West Virginia Pulp and Paper Company in 1914. The alcohol stills and some of the other equipment were imported from Germany and were considered the most modern at that time. In comparison to present American stills, these were very inefficient because they were wasteful of steam and did not recover all the alcohol. This plant reused the yeast from a previous fermentation for succeeding fermentations. The plant produced about 221,000 gallons of alcohol per year in 1919. In later years, because of the inefficiency of the alcohol stills with dilute alcohol solutions, molasses was added to the sulfite waste liquor to increase the alcohol content. The plant operated until 1939, when it was closed because of obsolescence. 

The ethyl alcohol fermentation is of course an age-old process and is so well known that little need be said about it here. The acetone-butanol fermentation is perhaps the next most important industrial fermentation process, although starch in the form of maize has been largely used as the basic material more recently suitably treated molasses has been used. The fermentation, a relatively rapid process requiring about thirty hours, produces about 60 parts of butanol, 30 parts of acetone and 10 parts of ethyl alcohol. These products already have large uses in industry and other uses are being explored. One possibility is the use of butanol in motor fuel. Jean has described a fuel, called Jeanite, consisting mainly of butanol and ethyl alcohol, which shows some promise. Of course the admixture of ethyl alcohol with petroleum is well known and an increased use of this mixture is probable. 

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