Infrared techniques

Nondestmctive testing (qv) can iaclude any test that does not damage the plastic piece beyond its iatended use, such as visual and, ia some cases, mechanical tests. However, the term is normally used to describe x-ray, auclear source, ultrasonics, atomic emission, as well as some optical and infrared techniques for polymers. Nondestmctive testing is used to determine cracks, voids, inclusions, delamination, contamination, lack of cure, anisotropy, residual stresses, and defective bonds or welds in materials. 

Frequency-Modulation Spectroscopy. Frequency-modulation spectroscopy (tins) is a high sensitivity null-background infrared technique for measuring absorbances down to 10 with fast acquisition speeds. Fms involves frequency-modulating a laser source at COq to produce a carrier frequency having sidebands at cJq where is an integral multiple of the modulation frequency. Dye lasers and many other single-line sources can... 

Gas chromatographic or infrared techniques ate commonly used to monitor the purity of methylene chloride shipments. 

RAIRS is a non-destructive infrared technique with special versatility - it does not require the vacuum conditions essential for electron spectroscopic methods and is, therefore, in principle, applicable to the study of growth processes [4.270]. By use of a polarization modulation technique surfaces in a gas phase can be investigated. Higher surface sensitivity is achieved by modulation of the polarization between s and p. This method can also be used to discriminate between anisotropic near-sur-face absorption and isotropic absorption in the gas phase [4.271]. 

Carbon monoxide and carbon dioxide can be measured using the FTIR techniques (Fourier transform infrared techniques see the later section on the Fourier transform infrared analyzer). Electrochemical cells have also been used to measure CO, and miniaturized optical sensors are available for CO 2 monitoring. 

Other Techniques Continuous methods for monitoring sulfur dioxide include electrochemical cells and infrared techniques. Sulfur trioxide can be measured by FTIR techniques. The main components of the reduced-sulfur compounds emitted, for example, from the pulp and paper industry, are hydrogen sulfide, methyl mercaptane, dimethyl sulfide and dimethyl disulfide. These can be determined separately using FTIR and gas chromatographic techniques. 

Isotherm A line in a flow system or on a graph connecting points of equal temperature, or a mathematical or graphical relationship between two variables at constant temperature. Or a display using lines on a drawing to show constant-temperature contour lines, as from thermal imaging with infrared techniques. 

Unlike other infrared techniques, thermal or infrared imaging provides the means to scan the infrared emissions of complete machines, process or equipment in a very short time. Most of the imaging systems function much like a video camera. The user can view the thermal... 

Inclusion of thermography into a predictive maintenance program will enable you to monitor the thermal efficiency of critical process systems that rely on heat transfer or retention electrical equipment and other parameters that will improve both the reliability and efficiency of plant systems. Infrared techniques can be used to detect problems in a variety of plant systems and equipment, including electrical switchgear, gearboxes, electrical substations, transmissions, circuit breaker panels, motors, building envelopes, bearings, steam lines, and process systems that rely on heat retention or transfer. 

Hetsroni G, Gurevich M, Mosyak A, Rozenblit R (2003) Surface temperature measurement of a heated capillary tube by means of an infrared technique. Meas Sci Technol 14 807-814 Hetsroni G, Gurevich M, Mosyak A, RozenbUt R (2004) Drag reduction and heat transfer of surfactants flowing in a capillary tube. Int J Heat Mass Transfer 47 3797-3809 Hetsroni G, Mosyak A, Pogrebnyak E, Yaiin LP (2005) Eluid flow in micro-channels Int J Heat Mass Transfer 48 1982-1998... 

High performance spectroscopic methods, like FT-IR and NIR spectrometry and Raman spectroscopy are widely applied to identify non-destructively the specific fingerprint of an extract or check the stability of pure molecules or mixtures by the recognition of different functional groups. Generally, the infrared techniques are more frequently applied in food colorant analysis, as recently reviewed. Mass spectrometry is used as well, either coupled to HPLC for the detection of separated molecules or for the identification of a fingerprint based on fragmentation patterns. ... 

It is only since 1980 that in situ spectroscopic techniques have been developed to obtain identification of the adsorbed intermediates and hence of reliable reaction mechanisms. These new infrared spectroscopic in situ techniques, such as electrochemically modulated infrared reflectance spectroscopy (EMIRS), which uses a dispersive spectrometer, Fourier transform infrared reflectance spectroscopy, or a subtractively normalized interfacial Fourier transform infrared reflectance spectroscopy (SNIFTIRS), have provided definitive proof for the presence of strongly adsorbed species (mainly adsorbed carbon monoxide) acting as catalytic poisons. " " Even though this chapter is not devoted to the description of in situ infrared techniques, it is useful to briefly note the advantages and limitations of such spectroscopic methods. 

Standard practices for GC-IR analysis have been described (ASTM E 1642-94). Griffiths [200] has discussed GC-FTIR designs. Sample preparation methods for hyphenated infrared techniques, in particular GC-FTIR, have been reported [201]. The technique has been reviewed repeatedly [167,183,201-204] a monograph [205] has appeared. 

I. Noda, A.E. Dowrey and C. Marcott, Characterization of polymers using polarization-modulation infrared techniques Dynamic infrared linear dichroism (DIRLD) spectroscopy. 

This catalytic cycle, generating acetyl iodide from methyl iodide, has been demonstrated by carbonylation of anhydrous methyl iodide at 80°C and CO partial pressure of 3 atm using [(C6H5)4As][Rh(CO)2X2] as catalysts. After several hours reaction, acetyl iodide can be identified by NMR and infrared techniques. However, under anhydrous conditions some catalyst deactivation occurs, apparently by halogen abstraction from the acetyl iodide, giving rhodium species such as frans-[Rh(CO)2I4] and [Rh(CO)I4] . Such dehalogenation reactions are common with d8 and d10 species, particularly in reactions with species containing weak... 

As a consequence, the development paths of surface Raman and infrared techniques will, given their different strengths and weaknesses, probably continue to proceed along divergent avenues of chemical application. Nevertheless, it seems inevitable that both will contribute in an increasingly important fashion to the detailed molecular-level elucidation of reactive as well as stable electrochemical systems. 

The combustion infrared technique has been used for the analysis of diluted sludges [34], Schaffer et al. [34] have used a blender to prepare suspensions of samples of this type. After the sample was homogenized, a microlitre syringe was used to remove a 20pL aliquot from the blender. However, the method described by Schaffer et al. [34] does not necessarily allow for the isolation of a representative portion of the sample in a 20pL aliquot [35]. This was found to be particularly true if the sample contained large particles which settled rapidly, and it must be assumed that the precision... 

The infrared technique has been described in numerous publications and recent reviews were published by Davies and Giangiacomo (2000), Ismail et al. (1997) and Wetzel (1998). Very few applications have been described for analysis of additives in food products. One interesting application is for controlling vitamin concentrations in vitamin premixes used for fortification of food products by attenuated total reflectance (ATR) accessory with Fourier transform infrared (FTIR) (Wojciechowski et al., 1998). Four vitamins were analysed - Bi (thiamin), B2 (riboflavin), B6 (vitamin B6 compounds) and Niacin (nicotinic acid) - in about 10 minutes. The partial least squares technique was used for calibration of the equipment. The precision of measurements was in the range 4-8%, similar to those obtained for the four vitamins by the reference HPLC method. 

Clay speciation analysis, dominated by the use of short-wave infrared techniques, highlights variations in the clay alteration associated with these deposits. The presence of a key species, such as illite, may be locally significant, but absolute amounts of each clay relative to alteration intensity are typically unattainable from these types of analyses. 

Elemental composition C 52.96%, 0 47.04%. It may be analyzed by treatment with water. The product malonic acid formed may be measured quantitatively by direct injection of aqueous solution into a GC for FID detection. Alternatively, the aqueous solution may be evaporated and the residue may be derivatized to methyl ester and identified by mass spectrometry. Also, the gas may react with ammonia or an amine, and the amide derivative may be identified and quantitatively determined by GC-FID, GC-NPD, GC/MS or infrared techniques. 

Detection techniques. Detection techniques commonly used for CO include two infrared techniques, TDLS and NDIR (also known as gas filter correlation, GFC), and gas chromatography with various detectors. The principles behind TDLS and NDIR have been... 

Infrared techniques, including TDLS (Schiff et al., 1994b) and matrix isolation FTIR (Griffith and Schuster, 1987), have been applied to S02, with detection limits of 500 and 10 ppt, respectively. 

Many polymers are too tough to be ground even at liquid nitrogen temperatures. Consequently, surface techniques are often used. Internal reflectance or attenuated total reflectance (ATR) is the second most commonly used infrared technique [38-40]. For soft or pliable polymers or solutions, ATR is an extremely versatile technique and the spectrum is similar to a transmission spectrum. Unlike transmission, the spectrum obtained is independent of sample thickness. 

CVt = 0.25/1.96 = 0.128. The number 0.128 is the largest true precision for a net error at +25% at the 95% confidence level. The number 1.96 is the appropriate t - statistic from the t distribution at the same confidence level. Since the coefficient of variation of pump error is assumed to be 5%, a method should have a CV analysis <0.102 to meet the CV accuracy standard. Tables IV and V7 shows that the infrared technique meets this requirement. 

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