Inductively coupled plasma mass sector

Multiple-collector inductively coupled plasma mass spectrometry (MC-ICPMS) combines sector-field ICPMS with a multiple collector detector system and has recently emerged as an alternative to TIMS for precise U-Th isotope measurement. The full potential of MC-ICPMS has yet to be realized. Yet despite this, its performance in high precision isotope measurement already challenges and, in some cases, surpasses that ever achieved by TIMS (e.g., Lee and Halliday 1995 Blichert-Toft and Albarede 1997). 

Choi MS, Francois R, Sims K, Bacon MP, Brown-Leger S, Fleer AP, Ball L, Schneider D, Pichat S (2001) Rapid determination of °Th and Pa in seawater by desolved micro-nebulization Inductively Coupled Plasma magnetic sector mass spectrometiy. Mar Chem 76 99-112... 

Shen C-C, Edwards RL, Cheng H, Dorale JA, Thomas RB, Moran SB, Weinstein S, Edmonds HN (2002) Uranium and thorium isotopic and concentration measurements by magnetic sector inductively coupled plasma mass spectrometry. Chem Geol 185 165-178 Shen GT, Dunbar RB (1995) Environmental controls on uranium in reef corals. Geochim Cosmochim Acta 59 2009-2024... 

Bensimon M, Bourquin J, Parriaux A (2000) Determination of ultra-trace elements in snow samples by inductively-coupled plasma source sector field mass spectrometry using ultrasonic nebulization. J Anal Atom Spectrom 15 731-734... 

Halliday AN, Lee D-C, Christensen JN, Walder AJ, Freedman PA, Jones CE, Hall CM, Yi W, Teagle D (1995) Recent developments in inductively coupled plasma magnetic sector multiple collector mass spectrometry. Int J Mass Spectr Ion Proc 146 21-33... 

Figure 5.22 Schematic of laser ablation inductively coupled plasma mass spectrometer a laser ablation system (wa velength 213 nm) is coupled to a double-focusing sector field ICP-MS (Element, Thermo Fisher Scientific, Bremen). The cooled laser ablation chamber using two Peltier elements was developed in the author s laboratoryJ26 (M. V. Zoriy, M. Kayser, A. Izmer, C. Pickhardt and J. S. Becker, Int. J. Mass Spectrom., 242, 297 (2005). Reproduced by permission of Elsevier.)...

Elemental analysis by mass spectrometiy was performed using a Perkin-Elmer Sciex ELAN 6000 Inductively Coupled Plasma—Mass Spectrometer (ICP-MS) and a ThermoFinnigan Element 2 Inductively Coupled Plasma Sector Field Mass Spectrometer. The iron oxide colored fibers (Table III, 16, 17) were weighed into the following aliquots (1) 1 mg rabbit hair (RH), (2) 5 mg RH, (3) 1 mg of milkweed (MW), (4) 5 mg MW and (5) a mixture of 2.5 mg RH and MW each. These samples were combined with concentrated nitric acid. Wanning the mixture to just below boiling temperature for 5 to 7 minutes did not result in total digestion. Hence, the incubation time in the water bath was increased to 30 minutes. Afterward, these samples were analyzed in the spectrometer. 

Kim, C. S. and Kim, C. K., Determination of Pu isotopes in seawater by an on-line sequential injection technique with sector field inductively coupled plasma mass spectrometry, Anal. Chem., 74, 3824—3832, 2002. 

Truscott, J. B., Jones, P., Fairman, B. E., and Evans, E. H., Determination of actinide elements at femtogram per gram levels in environmental samples by on-line solid phase extraction and sector-field-inductively coupled plasma-mass spectrometry, Anal. Chim. Acta, 433, 245-253, 2001. 

M. Krachler, A. Alimonti, F. Petrucci, K. J. Irgoli , F. Forestiere, S. Caroli, Analytical problems in the determination of platinum-group metals in urine by quadrupole and magnetic sector E>eld inductively coupled plasma mass spectrometry, Anal. Chim. Acta, 363 (1998), ID 10. 

T. P. Fischer, S. Shuttleworth, P. A. O Day, Determination of trace and platinum-group elements in high ionic-strength volcanic Buids by sector beld inductively coupled plasma mass spectrometry (ICP-MS), Fresenius J. Anal. Chem., 362 (1998), 457D464. 

C. Frazzoli, R. Cammarone, S. Caroli, Investigation of palladium and platinum contamination in food by means of sector Feld inductively coupled plasma mass spectrometry, 2006, Food Addit. Contam., 23 (2007), 1D7. 

M. Krachler, T. Prohaska, G. Koellensperger, E. Rossipal, G. Stingeder, Concentrations of selected trace elements in human milk and in infant formulas determined by magnetic sector field inductively coupled plasma-mass spectrometry, Biol. Trace Elem. Res., 76 (2000), 97-112. 

C. F. Harrington, S. Elahi, S. A. Merson, P. Ponnampalavanar, A method for the quantitative analysis of iron speciation in meat by using a combination of spectrophoto-metric methods and high-performance liquid chromatography coupled to sector t>eld inductively coupled plasma mass spectrometry, Anal. Chem., 73 (2001), 4422D4427. 

A. M. Featherstone, A. T. Townsend, G. A. Jacobson, G. M. Peterson, Comparison of methods for the determination of total selenium in plasma by magnetic sector inductively coupled plasma mass spectrometry, Anal. Chim. Acta, 512 (2004), 319D327. 

This multiauthored book aims at highlighting the role played by atomic and mass spectrometry (with particular reference to atomic absorption spectrometry, inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry) in supporting and promoting research and control of foodstuffs and food commodities as regards both essential and potentially toxic chemical elements. The progress made so far in this field is overviewed and emphasis is put on the open problems that require further investment and development in the public and private sectors. 

Begerov, J., Turfeld, M., Duneman, L. Determination of physiological palladium, platinum, iridium and gold levels in human blood using double focusing magnetic sector field inductively coupled plasma mass spectrometry. J. Anal. At. Spectrom. 12, 1095-1098 (1997)... 

CV-AAS, Cold Vapour Atomic Absorption Spectrometry ETA-AAS, Electrothermal Atomization Atomic Absorption Spectrometry FAAS, Flame Atomic Absorption Spectrometry FIG-AAS, Flydride Generation Atomic Absorption Spectrometry ICP-AES. Inductively Coupled Plasma Atomic Emission Spectrometry ID-MS, Isotopic Dilution Mass Spectrometry HR-ICP-MS, Magnetic Sector High Resolution Inductively Coupled Plasma Mass Spectrometry NAA, Neutron Activation Analysis Q-ICP-MS, Quadrupole Inductively Coupled Plasma Mass Spectrometry Z-ETA-AAS, Zeeman Electrothermal Atomization Atomic Absorption Spectrometry... 

Becker J. S. and Dietze H. J. (1998) Ultratrace and precise isotope analysis by double-focusing sector field inductively coupled plasma mass spectrometry, J Anal At Spectrom 13 1057-1063. 

Zheng, B., Hinlelmann, H. Hyphenation of high performance liquid chromatography with sector field inductively coupled plasma mass spectrometry for the determination of ultra-trace level anionic and cationic arsenic compounds in freshwater fish. J Anal At Spectrom 2004,19, 191-195. Pergantis, S. A., Heithmar, E. M., Hinners, T. A. Speciation of arsenic animal feed additives by microbore high-performance liquid chromatography with inductively coupled plasma mass spectrometry. Analyst 1997, 122, 1063-1068. 

Rosenthal, Y., Field, M. P. Sherrell, R. M. 1999. Precise determination of element/calcium ratios in calcareous samples using sector field inductively coupled plasma mass spectrometry. Analytical Chemistry, 71, 3248-3253. 

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