Hazardous waste, liquid

Hazardous waste liquid Waste liquid containing organic halogen or metal plating can be made nonhazardous. 

Specifying one s label and/or placard is a fairly simple matter once the proper shipping name has been determined. If the label manufacturer has any difficulty at all in day to day operations, it is with those companies who have not properly identified the hazard class for their particular compound. In the waste area, it often appears that the proper shipping name. Hazardous Waste, Liquid, n.o.s. has become a convenient catch-all for materials where the hazards are not known. Proper testing of the material is essential for it is only in that manner one may be certain what the hazard class really is. 

Hazardous Waste. liquid or solid. 9189 31 Tetra-oxocyclononane ... 

Lead waste and scrap in non-dispersible form (e.g. not powders, sludges, dusts or solids containing encased hazardous waste liquids). 

Liquid Injection. Liquid injection units are the most common type of incinerator today for the destmction of Hquid hazardous wastes such as solvents. Atomizers break the Hquid into fine droplets (100—150 microns) which allows the residence time to be extremely short (0.5—2.5 s). The viscosity of the waste is very important the waste must be both pumpable and capable of being atomized into fine droplets. Both gases and Hquids can be incinerated in Hquid injection units. Gases include organic streams from process vents and those from other thermal processes in the latter case, the Hquid injection incinerator operates as an afterburner. Aqueous wastes containing less than 75% water can be incinerated in Hquid injection units. 

The generation of hazardous wastes by spillage must also be considered. The quantities of hazardous wastes that are involved in spiUage usually are not known. After a spUl, the wastes requiring collection and disposal are often significantly greater than the amount of spiUed wastes, especially when an absorbing material, such as straw, is used to soak up liquid hazardous wastes or when the soU into which a hazardous liquid waste has percolated must be excavated. Both the straw and hquid and the soU and the liqmd are classified as hazardous wastes. 

Noncontainerized hazardous wastes containing free liquids, whether or not adsorbents have been added. 

Veiy small containers, such as ampules, and containers holding liquids for use other than storage, such as batteries, which may be disposed directly in a hazardous-waste landfill. 

Small lab-pack containers of hazardous waste if they are first placed in nonlealdug, larger containers. These containers must be Filled to capacity and surrounded by enough absorbent material to contain the liquid contents of the lab pack. The resultant container must then be placed in a larger container packed with absorbent material which will not react with, become decomposed by, or ignited by the contents of the inside containers. Incompatible wastes may not be packed and disposed of together in this manner. 

Applications Deep-well injection has been used principally for liquid wastes that are difficult to treat and dispose of by more conventional methods and for hazardous wastes. Chemical, petrochemical, and pharmaceutical wastes are those most commonly disposed of with this method. The waste may be liquid, gases, or solids. The gases and solids are either dissolved in the liquid or are carried along with the liquid. 

Table 28-2 lists some of the currently used pretreatments and ultimate disposal methods for hazardous wastes (6). Pretreatment refers almost entirely to thickening or dewatering processes for liquids or sludges. This process not only reduces the volume of the waste but also allows easier handling and transport. 

Tittlebaum, Marty E., Roger Seals, Frank Cartledge, Stephanie Engels, Louisiana State University. State of the Art on Stabilization of Hazardous Organic Liquid Wastes and Sludges. Critical Reviews in Environmental Control, Volume 15, Issue 2,1985. 

Handling hazardous ehemieals has beeome part of most people s everyday living. Just eonsider gasoline, and how most people fill their own tanks. In the manufaeturing arena, ehemieals are eommonplaee. On hazardous waste sites there are a variety of unknown ehemieal substanees and other hazards that may take the form of a solid, liquid, or gas. The eflfeets of exposure to toxie ehemieals may either be immediate (e.g., aeid burns) or delayed (e.g., lung damage from inhaling asbestos). There are four routes of ehemieal exposure that exist ... 

Liquid injection incinerators are currently the most commonly used type of incinerator for hazardous waste disposal. A wide variety of units are marketed today, mainly horizontally and vertically fired types a less common unit is the tangentially fired vortex combustor. 

The key to efficient destruction of liquid hazardous wastes lies in minimizing unevaporated droplets and unrcacted vapors. Just as for the rotary kiln, temperature, residence time, and turbulence may be optimized to increase destruction efficiencies. Typical combustion chamber residence time and temperature ranges arc 0.5-2 s and 1300-3000°F. Liquid injection incinerators vary in dimensions and have feed rates up to 1500 gal/h of organic wastes and 4000 gal/h of aqueous waste. 

A large fraction of the hazardous waste generated in industry is in the form of dilute aqueous solutions. The special challenges of separation in highly dilute solutions may be met by the development of new, possibly liquid-filled, membranes by processes involving selective concentration of toxic chemicals on the surfaces of particles or by the use of reversed micelles. 

Roll and coil coating systems utilize liquid coating materials with organic solvents, which must be stored, manifested, and disposed of according to 40 CFR Part 262 if classified as hazardous waste under 40 CFR Part 261. 

Liquid coating materials with low organic solvent content should be used to minimize the amount of volatile organic compounds that will be volatized and to reduce the volume of solid and liquid hazardous waste created. 

Hazardous waste identification begins with an obvious point in order for any material to be a hazardous waste, it must first be a waste. However, deciding whether an item is or is not a waste is not always easy. For example, a material (like an aluminum can) that one person discards could seem valuable to another person who recycles that material. U.S. EPA therefore developed a set of regulations to assist in determining whether a material is a waste. RCRA uses the term solid waste in place of the common term waste. Under RCRA, the term solid waste means any waste, whether it is a solid, semisolid, or liquid. The first section of the RCRA hazardous waste identification regulations focuses on the definition of solid waste. For this chapter, you need only understand in general terms the role that the definition of solid waste plays in the RCRA hazardous waste identification process. 

U.S. EPA proposed a concentration-based hazardous waste listing for certain waste solids and liquids generated from the production of paint on February 13, 2001.20 Following a review of the public comments and supplemental analyses based on those public comments, U.S. EPA determined that the paint wastes identified in the proposal do not present a substantial hazard to human health or the environment. Therefore, U.S. EPA did not list these paint production wastes as hazardous. See the April 4, 2002, final determination regarding these hazardous waste listings for additional information.21... 

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