Graft polymerizations

Grafting of polymers Graft polymerization Graft versus host disease Grahamite Graham s salt Grain... 

In all manufacturing processes, grafting is achieved by the free-radical copolymerization of styrene and acrylonitrile monomers in the presence of an elastomer. Ungrafted styrene—acrylonitrile copolymer is formed during graft polymerization and/or added afterward. 

Decabromodiphenyl Oxide—Polyacrylate Finishes. An alternative to the diffusion technique is the appHcation of decabromodiphenyl oxide on the surface of fabrics in conjunction with binders (131). Experimental finishes using graft polymerization, in situ polymerization of phosphoms-containing vinyl monomers, or surface halogenation of the fibers also have been reported (129,130,132,133). 

Etherification and esterification of hydroxyl groups produce derivatives, some of which are produced commercially. Derivatives may also be obtained by graft polymerization wherein free radicals, initiated on the starch backbone by ceric ion or irradiation, react with monomers such as vinyl or acrylyl derivatives. A number of such copolymers have been prepared and evaluated in extmsion processing (49). A starch—acrylonitrile graft copolymer has been patented (50) which rapidly absorbs many hundred times its weight in water and has potential appHcations in disposable diapers and medical suppHes. 

Polystyrene (PS). Common appHcations include packaging, food containers, and disposable tableware toys furniture, appHances, television cabinets, and sports goods and audio and video cassettes. For some of these appHcations, PS is modified by blending or graft polymerization with SBR to form impact polystyrene, which is less sensitive to breakage. Expandable polystyrene is widely used in constmction for thermal insulation. 

ABS (acrylonitrile—butadiene-styrene) resins are two-phase blends. These are prepared by emulsion polymerization or suspension grafting polymerization. Products from the former process contain 20—22% butadiene those from the latter, 12—16%. 

There are only a limited number of commercial apphcations of bulk or solution polymerization of chloroprene. These involve graft polymerization of adhesives and production of Hquid polymers. 

We have found that in the system of presulfate initiator, the PVAc latexes are not dissolved transparently in the methanol-water mixture [8], and in the system of HPO initiator, the extraction of the polymer from the PVAc latex films with acetone greatly depends on the polymerization condition [9]. These results suggest that if a polymerization method can be found in which the grafting polymerization of VAc onto PVA is controlled to the minimum, a large portion of PVAc in the latex film will have a chance of extraction with solvents. In this Chapter, the preparations of the unique porous films from the PVAc latexes containing PVA as a protective colloid by an extraction of the PVAc particles with acetone and the characteristic properties of the porous films are summarized. 

The use of ceric ions to initiate graft polymerization was first discussed by Mino and Kaizerman in 1958 [12]. Schwab and coworkers [13] were among the first to extend this method to the grafting of cellulose. Following their work, numerous papers have appeared in the literature on the grafting of vinyl monomers onto cellulose by this technique. 

Graft polymerization of methylmethacrylate monomer onto pulps of different residual lignin contents using ceric ammonium nitrate as the initiator was carried out to study the influence of this residual lignin on the graft-ability of these pulps (Fig. 3). From this figure one can... 

Yu et al. [31] pointed out that hydroxymethene radical will react with Ce(lV) ion to form a carbonyl group very quickly, and then it can further oxidize to form carbonyl radical. Therefore, the grafting polymerization would take place on the carbonyl radical as the following ... 

Recently, Zhao et al. [34,47], and Qiu et al. [21] have reported the graft polymerization of AAM onto macro-... 

A large number of SAHs described in the literature combine synthetic and natural macromolecules in the network structure. The natural components are usually starch, cellulose, and their derivatives. It is assumed that introduction of rigid chains can improve mechanical properties (strength, elasticity) of SAH in the swollen state. Radical graft polymerization is one of the ways to obtain such SAH. 

We think, therefore, that the conformation, chain and segment mobilities in the attached macromolecules can play a significant role in the shielding behavior of the polymeric stationary phase as well as in the processes of its formation of complexes with solutes. Obviously, the chromatographic studies relevant to composite supports suffer from a lack of information on the structure of the attached polymer. Nevertheless, we will attempt to point out some relevant data from independent studies on polymer adsorption and/or graft polymerization. 

Graft polymerization can be accomplished provided that active sites are available on the surface for reaction with monomers. Two fundamental methods of creating... 

The creation of active sites as well as the graft polymerization of monomers may be carried out by using radiation procedures or free-radical initiators. This review is not devoted to the consideration of polymerization mechanisms on the surfaces of porous solids. Such information is presented in a number of excellent reviews [66-68]. However, it is necessary to focus attention on those peculiarities of polymerization that result in the formation of chromatographic sorbents. In spite of numerous publications devoted to problems of composite materials produced by means of polymerization techniques, articles concerning chromatographic sorbents are scarce. As mentioned above, there are two principle processes of sorbent preparation by graft polymerization radiation-induced polymerization or polymerization by radical initiators. We will also pay attention to advantages and deficiencies of the methods. 

Radiation-induced graft polymerization may be carried out by the following procedures [69] ... 

The above results prove the potential of the graft polymerization technique for the preparation of composite sorbents. The next section will be devoted to the application of such materials in the chromatography of biopolymers. 

Chromatographic Packings Prepared by Graft Polymerization of Monomers... 

The authors of [317] investigated compositions based on PS, PMMA and styrene-acrylonitrile copolymer grafted to various fillers and found that it was possible, in this manner, to obtain particles with a grafted polymeric coating of sufficiently homogeneous thickness. 

Block and Graft Polymerization , ed. R. J. Ceresa, John Wiley, New York, 1973. 

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