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Even-numbered carbon chains

The de novo synthesis of fatty acids in the mammary gland utilizes mainly acetate and some (3-hydroxybutyrate. These precursors arise from the microbial fermentation of cellulose and related materials in the rumen. Once in the mammary gland, acetate is activated to acetyl-CoA. The mechanism of fatty acid synthesis essentially involves the carboxylation of acetyl-CoA to malonyl-CoA, which is then used in a step-wise chain elongation process. This leads to a series of short-chain and medium-chain length fatty acids, which differ by two CH2 groups (e.g., 4 0, 6 0, 8 0, etc.) (Hawke and Taylor, 1995). These are straight-chain, even-numbered carbon fatty acids. However, if a precursor such as propionate, valerate or isobutyrate, rather than acetate, is used, branched-chain or odd-numbered carbon fatty acids are synthesised (Jenkins, 1993 see Chapter 2). [Pg.4]

As previously discussed, covalent compounds contain carbon chains, or infrastructures. These carbon chains are numbered so chemists are able to name them. Because the rules that govern the system of numbering can be tricky for beginners to learn, we will not go into to much depth. In the following illustration, butane is shown with correct numbering. Thereafter, another more complicated structure is shown with correct numbering, followed by an even more complicated structure. In each of these examples, the numbering demonstrates how compounds can be numbered and labeled for proper identification. [Pg.9]

The carbon chain is numbered to give the triple bond the lowest possible numbers even though that results in higher position numbers for the methyl substituents. [Pg.1059]

The FabH proteins play a major role in specifying product diversity. E. coli FabH is specific for acetyl-CoA as the primer and this organism makes only straight-chain, even-numbered fatty acids. The FabH from gram-positive bacteria that produce branched-chain fatty acids are selective for five- and seven-carbon branched-chain precursors derived from amino acids. In Mycobacterium tuberculosis, the FabH prefers long-chain fatty acids and this organism is characterized by the presence of very long-chain mycolic acids in the membrane. [Pg.66]

The common range of saturated fatty acids has a straight chain, even number of carbons and chain length of 12 to 22 carbons. Myristic acid with 14 carbons is designated as 14 0 (or 14 carbons with no double bond), palmitic acid with 16 carbons as 16 0, and stearic acid with 18 carbons, as 18 0. [Pg.1]

The fourth process used to produce phthalate alcohols is the Ziegler process and the Ziegler displacement process. In the Ziegler process straight chain even-numbered carbon alcohols are produced from ethylene. Triethylaluminum is produced from aluminum, hydrogen, and ethylene. With the addition of more... [Pg.5703]

Straight-chain even-numbered fatty acids with 10 to more than 30 carbon atoms and containing one cis-doubie bond have been characterised from natural... [Pg.6]

The fatty acids occur in nature chiefly as glycerides see fats), which constitute the most important part of the fats and oils, and as esters of other alcohols, the waxes. The naturally occurring fatty acids are mostly the normal straight-chain acids with an even number of carbon atoms. [Pg.173]

As a consequence of the alternative distribution of an even number (2n) TT electrons on an odd number (2n - 1) carbon atoms, centers of the methine chain susceptible to nucleophilic attack are effectively the even carbons atoms starting from nitrogen, as it has been proven experimentally (103), particularly with a ketomethyiene giving a neutrocyanine compound (53, 67). [Pg.72]

Knott s rule concerns the importance of the place of the nitrogen atom replacing a methine carbon in the conjugated chain when the atom is separated from the active auxochromic atoms by an odd number of conjugated atoms, the shift is bathochromic. It is hypsochromic when there is an even number, Tne importance of the shift could establish a measure of M effect of various heterocyclic nuclei (79. 124). Many papers have been published, and examples have been given to verify these rules (79-84). [Pg.78]

Acetyl coenzyme A is the biosynthetic precursor to the fatty acids, which most often occur naturally as esters Fats and oils are glycerol esters of long chain carboxylic acids Typically these chains are unbranched and contain even numbers of carbon atoms... [Pg.1101]

Fats and oils (Section 26 2) Tnesters of glycerol Fats are solids at room temperature oils are liquids Fatty acid (Section 26 2) Carboxylic acids obtained by hydro lysis of fats and oils Fatty acids typically have unbranched chains and contain an even number of carbon atoms in the range of 12-20 carbons They may include one or more double bonds... [Pg.1283]

Fatty acids derived from animal and vegetable sources generally contain an even number of carbon atoms siace they are biochemically derived by condensation of two carbon units through acetyl or malonyl coenzyme A. However, odd-numbered and branched fatty acid chains are observed ia small concentrations ia natural triglycerides, particularly mminant animal fats through propionyl and methylmalonyl coenzyme respectively. The glycerol backbone is derived by biospeciftc reduction of dihydroxyacetone. [Pg.122]

The number of branches in HDPE resins is low, at most 5 to 10 branches per 1000 carbon atoms in the chain. Even ethylene homopolymers produced with some transition-metal based catalysts are slightly branched they contain 0.5—3 branches per 1000 carbon atoms. Most of these branches are short, methyl, ethyl, and -butyl (6—8), and their presence is often related to traces of a-olefins in ethylene. The branching degree is one of the important stmctural features of HDPE. Along with molecular weight, it influences most physical and mechanical properties of HDPE resins. [Pg.379]

In recent years, especially in the USSR and Europe, synthetic fatty acids, prepared via hydrocarbon oxidation, have been used to prepare fatty amines (2,9). In 1978 Eastern Europeans produced an estimated 0.55 biUion kg of synthetic fatty acids with odd and even numbers of carbon atoms, whereas in the United States, production of natural fatty acids with even carbon atom chain-length acids was 435 million kg. To date, there has been no significant production of synthetic fatty acids in the United States. [Pg.218]

Waxes are mixtures of esters of long-chain carboxylic acids with long-chain alcohols. The carboxylic acid usually has an even number of carbons from 16 through 36( while the alcohol has an even number of carbons from 24 through 36. One of the major components of beeswax( for instance, is triacontyl hexadecanoate, the ester of the C30 alcohol triacontanol and the C16 acid hexa-... [Pg.1061]

One of the most striking features of the common fatty adds is that they have an even number of carbon atoms (Table 27.1, p. 1062). This even number results because all fatty acids are derived biosynthelically from acetyl CoA by sequential addition of two-carbon units to a growing chain. The acetyl CoA, in turn, arises primarily from the metabolic breakdown of carbohydrates in the glycolysis pathway that weTl see in Section 29.5. Thus, dietary carbohydrates consumed in excess of immediate energy needs are turned into fats for storage. [Pg.1138]

The fatty adds commonly encountered in biological systems are straight chained alkanoic or alkenoic adds, containing an even number of carbon atoms (usually Ch-Ch). natural n Senera / these fatty adds can be produced readily by extraction of the lipids from sources natural sources and saponifying the neutral triglycerides. This is satisfactory providing a mixture of fatty acids is acceptable. Purification of spedfic fatty adds from the saponification mixture increases the costs considerably. [Pg.333]

The diamine part has six methylene units and the diacid part four methylene units and two acid carbon atoms. Thus, it has an even number of methylene units in both die diamine and the diacid part, which gives the polymer chain regularity so it is able to crystallize easily. [Pg.166]

Alkanesulfonates are the petrochemically derived sulfur analogs of soaps, which are alkane carboxylates based on renewable resources. The main difference between alkanesulfonates and soaps is, however, that alkanesulfonates consist of a rather complex mixture of homologs with different carbon chain lengths and isomers with an almost statistical distribution of the functional group along the hydrophobic carbon chain (Fig. 1), whereas soap is a mixture of homologs of alkane 1-carboxylates with an even number of carbon atoms. [Pg.144]

The Ziegler process produces linear alcohols with an even number of carbon atoms and is based on the polymerization of ethylene under catalytic conditions, generally with triethylaluminum as in the Alfol and the Ethyl processes. The distribution of alkyl chains depends on the version of the process employed but the alcohols obtained after fractionation can be equivalent to those obtained from fats and oils or have purpose-made distributions depending on the fractionation conditions. [Pg.225]

The Krafft temperature for a homologous series rises as the chain length increases but with independent and different curves for even or odd members [80]. Figure 7 shows the Krafft temperatures of sodium alcohol sulfates ranging from 11 to 18 carbon atoms where the two different curves for odd- and even-numbered series and the alternancy of values can be clearly observed. Lange and Schwuger explain this effect as caused by the different crystal structures of the even and odd numbers. [Pg.242]

Fatty acids occur mainly as esters in natural fats and oils but do occur in the unesterified form as free fatty acids, a transport form found in the plasma. Fatty acids that occur in natural fats are usually straight-chain derivatives containing an even number of carbon atoms. The chain may be saturated (containing no double bonds) or unsaturated (containing one or more double bonds). [Pg.111]

The melting points of even-numbered-carbon fatty acids increase with chain length and decrease according to unsaturation. A triacylglycerol containing three sam-rated fatty acids of 12 carbons or more is solid at body temperature, whereas if the fatty acid residues are 18 2, it is liquid to below 0 °C. In practice, natural acylglyc-erols contain a mixture of fatty acids tailored to suit their functional roles. The membrane lipids, which must be fluid at all environmental temperatures, are... [Pg.114]


See other pages where Even-numbered carbon chains is mentioned: [Pg.113]    [Pg.165]    [Pg.44]    [Pg.122]    [Pg.5]    [Pg.231]    [Pg.602]    [Pg.140]    [Pg.392]    [Pg.728]    [Pg.369]    [Pg.1072]    [Pg.444]    [Pg.473]    [Pg.1072]    [Pg.183]    [Pg.239]    [Pg.85]    [Pg.206]   
See also in sourсe #XX -- [ Pg.18 ]




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Carbon number

Even numbers

Numbering chains

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