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Natural fatty acids

There also exist natural fatty acids with four or more double bonds, fatty acids with hydroxy groups in the molecule, and certain cyclic fatty acids. [Pg.173]

The organophilic part R can come from a natural fatty acid whose carbon number is around 18 and whose chain contains a number of unsaturated bonds. Dimers of fatty acids (Cgg diacids) have also been used. [Pg.347]

To overcome these difficulties, drilling fluids are treated with a variety of mud lubricants available from various suppHers. They are mostly general-purpose, low toxicity, nonfluorescent types that are blends of several anionic or nonionic surfactants and products such as glycols and glycerols, fatty acid esters, synthetic hydrocarbons, and vegetable oil derivatives. Extreme pressure lubricants containing sulfurized or sulfonated derivatives of natural fatty acid products or petroleum-base hydrocarbons can be quite toxic to marine life and are rarely used for environmental reasons. Diesel and mineral oils were once used as lubricants at levels of 3 to 10 vol % but this practice has been curtailed significantly for environmental reasons. [Pg.183]

In recent years, especially in the USSR and Europe, synthetic fatty acids, prepared via hydrocarbon oxidation, have been used to prepare fatty amines (2,9). In 1978 Eastern Europeans produced an estimated 0.55 biUion kg of synthetic fatty acids with odd and even numbers of carbon atoms, whereas in the United States, production of natural fatty acids with even carbon atom chain-length acids was 435 million kg. To date, there has been no significant production of synthetic fatty acids in the United States. [Pg.218]

Natural Fatty Acids Report," in Chemical Economics Handbook, SRI International, Menlo Park, Calif., 1988. [Pg.97]

FIGURE 8.1 The structures of some typical fatty acids. Note that most natural fatty acids coutaiu au even number of carbon atoms and that the double bonds are nearly always ck and rarely conjugated. [Pg.240]

Having greater resemblance to natural fatty acids are the products of the coordination-catalyzed hydrocarboxylation of olefins with water and carbon monoxide (Reppe reaction) [58] ... [Pg.30]

It is important to keep in mind that any extraction of organic matter from soil will include both naturally occurring organic matter and organic contaminants. Separating the two at some later stage of analysis is thus an essential analytical step. For example, extraction of soil with hexane or dichloromethane will extract both l,l,l-trichloro-2,2-di(4-dicholorphenyl)ethane (DDT), a contaminant, and octadecanoic acid, a natural fatty acid. Also, the herbicide 2,4-dichlorophenoxy acetic acid, a contaminant, and indole-3-acetic acid, a natural plant hormone, are both extracted by water (see Figure 12.3). These... [Pg.251]

Trans fatty acids The phospholipids in the plasma and in membranes of all cells contain long-chain polynnsatnrated fatty acids (PUFA). During periods of growth and development of organs, PUFAs are reqnired for phospholipid synthesis. The PUFAs are, of conrse, obtained from dietary triacylglycerol and phospholipids. The donble bonds in most natural fatty acids are cis not trans Nonetheless trans fatty acids do occur in dietary fats. If the diet contains trans fatty acids, they might be incorporated into the phospholipids along with the cis fatty acids and hence into membranes. The presence of these abnormal fatty acids will modify the stmctnre of the phospholipids which conld impair the fnnction of the membrane. There are two main sonrces of trans fatty acids in the diet foods produced from ruminants contain trans fatty... [Pg.356]

Bradley MO, Webb NL, Anthony FH, Devanesan P, Witman PA, Hemamalini S, Chander MC, Baker SD, He L, Horwitz SB, Swindell CS. (2001) Tumor targeting by covalent conjugation of a natural fatty acid to paclitaxel. Clin Cancer Res 7 3229-3238. [Pg.170]

The leaving group is the enolate anion of acetyl-CoA, and the reaction thus cleaves off a two-carbon fragment from the original fatty acyl-CoA. Since the nucleophile is coenzyme A, the other product is also a coenzyme A ester. In fact, the reaction generates a new fatty acyl-CoA, shorter by two carbons, which can re-enter the P-oxidation cycle. Most natural fatty acids have an even number of carbons, so the process continues until the original fatty acid chain is cleaved completely to acetyl-CoA fragments. [Pg.388]

In lipid metabolism, ds-trans isomerism is particularly important. For example, double bonds in natural fatty acids (see p.48) usually have a as configuration. By contrast, unsaturated intermediates of p oxidation have a trans configuration. This makes the breakdown of unsaturated fatty acids more complicated (see p. 166). Light-induced cis-trans isomerization of retinal is of central importance in the visual cycle (see p.358). [Pg.8]

The table lists the full series of aliphatic carboxylic acids that are found in plants and animals. In higher plants and animals, unbranched, longchain fatty acids with either 16 or 18 carbon atoms are the most common— e.g., palmitic and stearic acid. The number of carbon atoms in the longer, natural fatty acids is always even. This is because they are biosynthesized from C2 building blocks (see p.168). [Pg.48]

Butyric acid is one of the simplest fatty acids. Fatty acids, which are the building units of fats and oils, are natural compounds of carbon chains with a carboxyl group (-COOH) at one end. Most natural fatty acids have an unbranched carbon chain and contain an even number of carbon atoms because during biosynthesis they are built in two carbon units from acetyl coenzyme A (CoA). Butyric acid is an unsaturated fatty acid, which means all carbon-carbon bonds are single bonds. Common names for fatty acids stem from their natural sources. In addition to butyric acid, some other common saturated fatty acids include lauric acid, palmitic acid, and stearic acid. Lauric acid was first discovered in Lauraceae (Laurus nobilis) seeds, palmitic oil was prepared from palm oil, and stearic acid was discovered in animal fat and gets its name from the Greek word stear for tallow. [Pg.52]

Most natural fatty acids are even-numbered. What is the product of the final thiolase reaction to form an odd-chain fatty acid Give a brief explanation. [Pg.533]

Three fatty acids comprise an oil and are usually referred to as just acids. Caprylic acid (octanoic acid or 1-heptanecarboxylic acid) is the most antimicrobial emulsified fatty acid compared to capric and oleic (higher in molecular weight compared to caprylic acid). Oleic acid (d.v-9-octadcccnoic) and caprylic acid are natural fatty acids found in vegetable and marine oils. The oleic acid or similar low... [Pg.103]

NEUDOSAN. Neudosan is a product based on potassium salts of natural fatty acids. In accordance with the manufacturer s recommendations it was used at 2—4% at full bloom with 1000 litres of water/ha. Although a good... [Pg.104]

Polyanhydrides prepared from fatty acids are good candidates for the delivery of hydrophilic drugs due to the desired hydrophobicity of the natural fatty acids in the main chain of the polyanhydrides 11). These polyanhydrides have two series of acid monomers one has longer carbon chain, such as dimer erucic or oleic acid another has shorter carbon chain, such as sebacic acid (2). Fatty acids can be incorporated into the polymer chain by one of two ways by... [Pg.89]

Finally, the search for a strategic bond is always simplified when even a first glance analysis leads to the identification of those bonds that clearly cannot be considered strategic. The latter include bonds in aromatic rings (see, however, an exception in Vollhardt s synthesis of estrone) or heteroaromatic rings, as well as bonds which are located in readily available fragments (such as monosaccharides, amino acids, natural fatty acids, etc.). [Pg.283]

Unsaturated fatty acid (Section 10.6A) A fatty acid having one or more carbon-carbon double bonds in its hydrocarbon chain. In natural fatty acids, the double bonds have the Z configuration. [Pg.1212]

The list of natural fatty acids exceeds 1000, but commercial interest is limited to a smaller number— perhaps around 20. Ignoring the lipid membrane, rich in ot-lino-lenic acid and present in all green tissue, the three dominant acids in the plant kingdom are palmitic, oleic, and linoleic, sometimes accompanied by stearic acid and by linolenic acid. Others, occuring in specialty oils, include myristic, lauric, erucic, hexadecenoic, petroselinic, y-linolenic acid, eleostearic and isomers, ricinoleic, and vemolic (Table 1). [Pg.264]

In a decade, the advanced lipid analytical technology that defines DHA as a natural fatty acid of marine oils from a deep-sea shark described around 1994 (118) has been surpassed by nondestructive NMR measurement of DHA in situ (Table 7). Thus, advanced analytical technology is supporting with new developments the benefits from marine oil omega-3 fatty acids in our daily lives. [Pg.1671]

The principal raw materials from which the natural fatty acids are derived are tallow, cmde tall oil, coconut, palm kernel, and soybean oils. [Pg.2981]

R. Modler, R. Gubler, and K. Yagi, Natural Fatty Acids, Chemical Economics Handbook, SRI, Menlo Park, California, 2002. [Pg.3034]

Strategies based on the Simmons-Smith reaction are presently developed for the synthesis of polycyclopropanes of defined absolute and relative stereochemistry in relation with natural product 10, a fascinating natural fatty-acid amide nucleoside that shows promise as an antifungal drug [35, 37],... [Pg.804]

In case of the direct reaction of the natural oil or lower alkyl ester of natural fatty acid and the amine the reaction method for producing the amide derivatives is as follows That is, about 1 mol of the said oils and 1 to 100 equivalent mols of the said amines are mixed in the absence or presence of solvents such alcohols as methanol, ethanol or the like, such aromatic hydrocarbons as benzene, toluene, xylene or the like, such halogenoalkanes as methylene chloride, chloroform, carbon tetrachloride or the like, and such alkenes or alkanes as petroleum ether, benzene, gasoline, ligroin or cyclohexane, such ethers as tetrahyrofuran, dioxane and the like, or a mixture thereof, and the mixture is subjected to the reaction in the absence or presence of catalyst amount or equimolar amount to the amine of an auxiliary agent of condensation, such as alkoholate of alkali metal, i.e. lithium, methylate, lithium ethylate, sodium methylate, sodium ethylate, potassium-t-butylate and the like, or acidic auxiliary agents, i.e. p-toluenesulfonic acid and the like, thereby to yield the amide derivatives. In this reaction, a formal alcohol may be removed from the reaction system. [Pg.112]

The natural fatty acid amides are mixtures of saturated fatty acid amides and unsaturated fatty acid amides. The present invention is based on the fact that the unsaturated fatty acid amides can be isolated very easily from a mixture of fatty acid amides by treating the fatty acid amides with urea or thiourea. The unsaturated fatty acid amides have more effective biological activity. [Pg.117]

Seki, T. N-Substituted Amides of Natural Fatty Acids 1970 US 3,551,462 Seki, T. et al N-Substituted Octadecadienoic Acid Amides as Cholesterol Lowering Agents 1971 US 3,621,043... [Pg.182]


See other pages where Natural fatty acids is mentioned: [Pg.220]    [Pg.190]    [Pg.268]    [Pg.221]    [Pg.52]    [Pg.270]    [Pg.352]    [Pg.556]    [Pg.277]    [Pg.38]    [Pg.5]    [Pg.171]    [Pg.59]    [Pg.34]    [Pg.934]    [Pg.47]    [Pg.1943]    [Pg.361]    [Pg.488]    [Pg.315]    [Pg.112]    [Pg.113]   
See also in sourсe #XX -- [ Pg.3 , Pg.4 , Pg.5 , Pg.6 , Pg.7 , Pg.8 , Pg.9 , Pg.10 , Pg.11 , Pg.12 , Pg.13 , Pg.14 , Pg.15 , Pg.16 , Pg.17 , Pg.18 , Pg.30 ]




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Acidity nature

Fatty acid natural sources

Fatty acids naturally occurring

Fatty acids, from natural oils

Fatty acids, from natural oils hexabromide test for

Fatty acids, from natural oils unsaturated

How Nature makes fatty acids

N-Substituted Amides of Natural Fatty Acids

Natural fatty acid monoglycerides

Natural product fatty-acid derived substances

Unsaturated fatty acid naturally occurring

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