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Alkyl reaction with

My teaching experience was, however, only secondary to my research interest. Through my initial research work involving reactions of fluorinated carbohydrates I became interested in Friedel-Crafts acylation and subsequently alkylation reactions with acyl or alkyl fluo-... [Pg.57]

Side-chain anionic alkylation reactions with aromatic compounds take place when cataly2ed with strong basic catalysts, like Na—K (228). The yield is 83% when o-xylene reacts with butadiene... [Pg.347]

Quaternization of the enamine has been the more frequent result of alkylation reactions with cyclic enamines 114,277-279), but some successful carbon alkylations have been reported 280-282). [Pg.354]

Brown and Grayson reported that the rate of alkylation reactions with benzyl chloride was third order overall first order in aromatic component, first order in AICI3, and first order in benzyl chloride. This indicates that a rate determining nucleophilic attack by the aromatic component on a polar alkyl chloride-aluminum... [Pg.149]

The results of these alkylation reactions with allyidichlorosilane (1) in the presence of aluminum chloride catalyst are summarized in Table II. [Pg.151]

As shown in Table 3, after a pretreatment performed at 333 K, the activity of the K3P sample increased with time on stream (TOS), giving rise to a high production of dimethylhexanes (DMH) and of olefins (Cg" ). After a dehydratation performed at 423 K, the conversion of C4= and the selectivities towards TMP were initially high. As generally observed in the aliphatic alkylation reaction with solid acids, the decrease of the catalyst activity was accompanied by a concomitant decrease of the selectivity in TMP and an increase of the selectivities in DMH and olefins (C4 dimerization) indicating... [Pg.597]

The syn TS is favored by about 1 kcal/mol, owing to reduced eclipsing, as illustrated in Figure 1.4. An experimental study using the kinetic enolate of 3-(/-butyl)-2-methylcyclopentanone in an alkylation reaction with benzyl iodide gave an 85 15 preference for the predicted cis-2,5-dimethyl derivative. [Pg.27]

Maleic acid imides (maleimides) are derivatives of the reaction of maleic anhydride and ammonia or primary amine compounds. The double bond of a maleimide may undergo an alkylation reaction with a sulfhydryl group to form a stable thioether bond (Chapter 2, Section 2.2). Maleic anhydride may presumably undergo the same reaction with cysteine residues and other sulfhydryl compounds. [Pg.107]

The technology and chemistry of isoalkane-alkene alkylation have been thoroughly reviewed for both liquid and solid acid catalysts (15) and for solid acid catalysts alone (16). The intention of this review is to provide an up-to-date overview of the alkylation reaction with both liquid and solid acids as catalysts. The focus is on the similarities and differences between the liquid acid catalysts on one hand and solid acid catalysts, especially zeolites, on the other. Thus, the reaction mechanism, the physical properties of the individual catalysts, and their consequences for successful operation are reviewed. The final section is an overview of existing processes and new process developments utilizing solid acids. [Pg.255]

Scheme 10.10. Radical mechanism in alkylation reactions with alkyl halides. Scheme 10.10. Radical mechanism in alkylation reactions with alkyl halides.
IV. Friedel-Crafts Alkylation Reaction with Organosilicon Compounds. 50... [Pg.41]

FRIEDEL-CRAFTS ALKYLATION REACTION WITH ORGANOSILICON COMPOUNDS... [Pg.50]

Rhodium-Catalyzed Allylic Alkylation Reaction with Stabilized Carbon Nucleophiles... [Pg.194]

S)-Aspartic acid has been converted to derivatives (181) and (182) which undergo alkylation reactions with stereoselectivities that are enantiomerically complement-... [Pg.215]

Glick et al. (134) and Goren and Barnard (135, 136) have shown that in the alkylation reaction with bromoacetate ion the principal alkylation at histidine occurs as described below but that in addition Met 30 is alkylated. This modification has no effect on enzymic activity and is not affected by the histidine alkylations. Phosphate and sulfate do not inhibit the reaction but pyrophosphate and 2 -CMP do. [Pg.682]

The amide ions are powerful bases and may be used (i) to dehydrohalogenate halo-compounds to alkenes and alkynes, and (ii) to generate reactive anions from terminal acetylenes, and compounds having reactive a-hydrogens (e.g. carbonyl compounds, nitriles, 2-alkylpyridines, etc.) these anions may then be used in a variety of synthetic procedures, e.g. alkylations, reactions with carbonyl components, etc. A further use of the metal amides in liquid ammonia is the formation of other important bases such as sodium triphenylmethide (from sodamide and triphenylmethane). [Pg.117]


See other pages where Alkyl reaction with is mentioned: [Pg.298]    [Pg.38]    [Pg.700]    [Pg.467]    [Pg.840]    [Pg.708]    [Pg.165]    [Pg.76]    [Pg.183]    [Pg.217]    [Pg.42]    [Pg.50]    [Pg.51]    [Pg.82]    [Pg.18]    [Pg.38]    [Pg.443]    [Pg.455]    [Pg.700]    [Pg.639]    [Pg.168]   
See also in sourсe #XX -- [ Pg.3 , Pg.23 ]




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1- Alkylimidazoles, reaction with alkyl radicals

1-Alkyl -ones, reaction with ammonia

2- Alkyl-4 -aminoimidazoles, reaction with

2-Pyrazolines, 1-alkyl-, reaction with

6-Alkyl-2,2 -bipyridines, reaction with

9-Alkyl-3-methylguanines. reaction with

Acetylide anions reactions with alkyl halides

Acid-catalyzed reactions with tertiary alkyl group

Alcohols reaction with alkyl halides

Alkenes reaction with alkyl halides

Alkenes, reaction with alkyl azides

Alkenes, reaction with alkyl hydroperoxides

Alkenes, reaction with alkyl hydroperoxides, table

Alkyl aryl sulfoxides, chiral, reaction with

Alkyl azides reactions with epoxides

Alkyl bromides, reaction with sodium

Alkyl bromides, reaction with sodium cyanide

Alkyl chlorides reaction with saturated nitrogen

Alkyl chlorides, reaction with wood

Alkyl groups alcohol reactions with hydrogen halides

Alkyl hahde reaction with

Alkyl hahde reaction with alcohols

Alkyl hahde reaction with amines

Alkyl halide reaction with Gilman reagents

Alkyl halide reaction with carboxylate ions

Alkyl halide reaction with phthalimide ion

Alkyl halide reaction with thiourea

Alkyl halide reaction with tributyltin hydride

Alkyl halides Compounds with halogen elimination reaction

Alkyl halides alcohol reactions with hydrogen

Alkyl halides reaction with acetylides

Alkyl halides reaction with water

Alkyl halides reactions with ambident

Alkyl halides reactions with organocopper reagents

Alkyl halides reactions with sulfur

Alkyl halides synthetic reactions with

Alkyl halides with chlorine, reaction

Alkyl halides with nitrogen, reaction

Alkyl halides, reaction with aluminum

Alkyl halides, reaction with indole Grignard

Alkyl halides, reaction with indole Grignard reagents

Alkyl halides, reactions with arene

Alkyl halides, reactions with arene Table

Alkyl halides, reactions with trimethylsilyl

Alkyl hydroperoxides reaction with transition metals

Alkyl hypohalites, reactions with amines

Alkyl iodides by reaction of hydrogen iodide with

Alkyl iodides, reaction with sodium

Alkyl isocyanates reaction with

Alkyl lithiums, reaction with pyridines

Alkyl metals, a-selenocarbonyl compound homologation reactions with carbonyl compounds

Alkyl metals, a-selenocarbonyl compound homologation reactions with enals

Alkyl metals, a-selenocarbonyl compound homologation reactions with enones

Alkyl nitrites, reaction with

Alkyl phosphates, reaction with

Alkyl phosphates, reaction with compounds

Alkyl reaction with ethylene

Alkyl reaction with nucleophilic complexes

Alkyl reactions with strong acids

Alkyl sulfonates reaction with superoxides

Alkyl tert, amines, reaction with

Alkylation Reactions with Imidazolidinone Enamines

Alkylation reactions phenols with alkyl halides

Alkylation with Carbonyl Compounds The Prins Reaction

Alkyne anions reaction with alkyl halides

Aluminum alkyls reaction with propylene

Aluminum alkyls reactions with

Ammonia reaction with alkyl halides

Antimony, reaction with alkyl halides

Azide ion reaction with alkyl halides

Azides, alkyl reactions with ketones

Azinium compounds, N-alkyl-, substituent displacement reaction with nucleophiles

Benzene, alkylation reaction with

Benzene, trichlorodialkylation coupling reactions with primary alkyl Grignard

Benzylic reaction with alkyl halides

Boranes, alkyl reaction with aldehydes

Bromine reaction with alkyls

Butadiene, reaction with lithium alkyls

Butane, 1,2-epoxybenzene alkylation with Friedel-Crafts reaction

Butyrolactones, reactions with alkyl halide

By Reaction with Alkyl Halides

By Reaction with Metals and Alkylating Agents

Carbene complexes, alkyl pentacarbonylalkylation reaction with carbonyl compounds

Carbocation alkyl halide reaction with Lewis

Carbon-centered alkyl radicals reaction with

Carboxylates reaction with alkyl sulfonates

Catalytic asymmetric cross-coupling reactions with secondary alkyl halides

Cellobiosides, alkyl and aryl poly-0acetyl-«- , reaction with hydrogen bromide heptaacetate

Chlorine reaction with alkyls

Chlorosulfites, alkyl, reaction with carboxylic acid

Copper reactions with alkyl halides

Cross-coupling reactions alkyl halides with Grignard reagents

Cross-coupling reactions with alkyl halides

Cyanamide reaction with alkyl halides

Cyanides, metal, reaction with alkyl halides

Cyanocuprates, reactions with alkyl halides

Cyclohexanones reactions with alkyllithium and alkyl Grignard

Dithiane anions reaction with alkyl halides

Dithioacetals, alkylation reaction with base

Enolate anions reaction with alkyl halides

Enolate anions, dianions reaction with alkyl halides

Enolate anions, esters, reaction with alkyl halides

Enolates reaction with alkyl halide

Ethers reaction with alkyl halides

Ethers, alkyl vinyl reaction with tetracyanoethylene

Ethylene, 1,1-dichlorocoupling reactions with alkyl Grignard reagents

Ethylene, l-bromo-2-phenylthiocoupling reaction with alkyl Grignard reagents

Ethylene, l-bromo-2-phenylthiocoupling reaction with secondary alkyl Grignard reagents

Formates, alkyl chloroanhydride synthesis reactions with amides

Friedel-Crafts Alkylation Reaction with Organosilicon Compounds

Friedel-Crafts reaction with alkyl halides

Gilman cuprates, reactions with alkyl halides

Grignard reaction: alkylation with cadmium chloride

Grignard reaction: alkylation with carbonyl compounds

Grignard reaction: alkylation with mercury halides

Grignard reagents coupling reactions with alkyl halides

Grignard reagents, alkyl reaction with cyclohexanone

Grignard reagents, reaction with alkyl halides

Halide ions reaction with alkyl halides

Halides coupling reactions with primary alkyl Grignard

Halides, alkyl intramolecular reactions with

Halides, alkyl reaction with NaSH

Halides, alkyl reaction with acetoacetic ester anions

Halides, alkyl reaction with acid salts

Halides, alkyl reaction with alkoxides

Halides, alkyl reaction with alkynes

Halides, alkyl reaction with aluminum hydride reagents

Halides, alkyl reaction with amide anions

Halides, alkyl reaction with amines

Halides, alkyl reaction with aromatic compounds

Halides, alkyl reaction with carbanions

Halides, alkyl reaction with carboxylic acid salts

Halides, alkyl reaction with cyanohydrins

Halides, alkyl reaction with enamines

Halides, alkyl reaction with hexamethylenetetramine

Halides, alkyl reaction with hydrazone anions

Halides, alkyl reaction with hydrogen sulfide

Halides, alkyl reaction with hydroxide

Halides, alkyl reaction with ketone enolate anions

Halides, alkyl reaction with ketones

Halides, alkyl reaction with lithium

Halides, alkyl reaction with magnesium

Halides, alkyl reaction with malonate anions

Halides, alkyl reaction with metals

Halides, alkyl, reaction with Bu3SnH

Halides, alkyl, reaction with Lewis acids

Halides, alkyl, reaction with Subject

Halides, alkyl, reaction with acid dianions

Halides, alkyl, reaction with amino ester enolates

Halides, alkyl, reaction with amino-alcohols

Halides, alkyl, reaction with azide

Halides, alkyl, reaction with cuprates

Halides, alkyl, reaction with cyanide

Halides, alkyl, reaction with cyanoborohydride

Halides, alkyl, reaction with dimethyl sulfide

Halides, alkyl, reaction with ester dianions

Halides, alkyl, reaction with ester enolates

Halides, alkyl, reaction with ferrate

Halides, alkyl, reaction with imides

Halides, alkyl, reaction with lactone enolates

Halides, alkyl, reaction with malonate enolates

Halides, alkyl, reaction with nitrile enolates

Halides, alkyl, reaction with nitro compounds

Halides, alkyl, reaction with organocuprates

Halides, alkyl, reaction with organolithium reagents

Halides, alkyl, reaction with phthalimide

Halides, alkyl, reaction with succinimide

Halides, alkyl, reaction with sulfides

Heck-type Reaction of Alkyl Halides with Styrenes

Hydrazine reaction with alkyl phthalimides

Hydrazine, reaction with acrylonitrile from alkylation of diphenylmethane

Hydrogen bromide reaction with alkyl alcohols

Hydrogen peroxide reaction with alkyl benzenes

Hydroperoxides, alkyl reaction with base

Hydroxide, potassium reaction with alkyl halides

Hydroxy halides, alkylation reaction, with alkali

Imidazoles reaction with alkyl radicals

Imidazoles, l-benzyl-2-alkyl-4,5-dihydromethiodide salt reactions with organometallic compounds

Imines, alkylation reaction with cyanide

Indole, alkyl-, reaction with carbenes

Iodide, potassium reaction rates with alkyl halides

Iodide, sodium reaction with alkyl halides

Iron alkyls, carbonylation reactions with nucleophiles

Iron, reaction with alkyl halides

Isothiocyanates, alkyl, reaction with

Ketones, preparation by alkylation reaction with dimethylformamide and

LiAlH4, reaction with alkyl halides

Lithium diphenylcuprate reaction with alkyl bromide

Lithium, vinylalkylation reaction with alkyl halides

Magnesium reaction of with alkyl and aryl halide

Magnesium reaction with alkyl halides, mechanism

Magnesium, reaction of with alkyl and

Magnesium, reaction of with alkyl and aryl

Magnesium, reaction with alkyl halides form Grignard reagents

Metal phosphites reaction with alkyl halides

Metal-mediated Schmidt Reactions of Alkyl Azides with Alkenes and Alkynes

Nitrite, sodium reaction with alkyl halides

Nitrites reaction with alkyl sulfonates

Nitroxide with alkyl radicals, reaction

Nucleophiles reaction with alkyl

Organocopper compounds, reactions with alkyl halides

Organocuprates reaction with alkyl tosylates

Organometallic compounds reaction with alkyl halides

Organozinc reagents cross-coupling reactions with alkyl halides

Oxazine anions, reaction with alkyl halides

Oxazine anions, reaction with alkyl halides alkylation

Oxygen reaction with alkyl radicals

Palladium, phenylbis catalysis arylmagnesium halide reaction with alkyl halides

Phosphines reaction with alkyl halides

Phosphines reaction with alkyl halides, kinetics

Phosphoramidate, N- diethyl ester reaction with alkyl bromides

Phosphoramidic acid, N- diethyl ester reaction with alkyl halides

Phosphorane, iminovinylidenetriphenylphosphonium ylide synthesis reactions with alkyl halides

Phosphorus, reaction with alkyl halides

Phthalimide, alkyl, reaction with

Phthalimide, alkyl, reaction with hydrazine

Primary alkyl coupling reactions with alkenyl halides

Primary alkyl coupling reactions with aromatic halides

Primary alkyl reactions with alkenyl halides

Primary alkyl reactions with epoxides

Proteins reactions with alkylating agents

Purine, 6-chlorocoupling reactions with primary alkyl Grignard reagents

Purine, 6-methylthiocoupling reactions with primary alkyl Grignard reagents

Pyridine reaction with alkyl-, aryl-lithiums

Pyridine, reactions with—continued alkylation

Pyridine, reactions with—continued alkyls

Pyridines reactions with alkyl radicals

Pyridinium reaction with alkyl nitrite

Pyridinium salts reactions with alkyl radicals

Quinaldine reaction with alkyl radicals

Quinoline reaction with alkyl radicals

Radicals, coupling reactions with alkyl halides

Reaction of Alkyl Substituents with an a-Functional group

Reaction of Alkyl, Alkenyl, and Aryl Halides with Metals

Reaction of Amines with Alkyl Halides

Reaction of Lithiated Bis(methylthio)methane with Alkyl Halides

Reaction of alkyl halides with sulfites and sulfinic acids

Reaction of stabilized carbanions (enolates) with alkyl halides (enolate alkylation)

Reaction with Alkyl and Aryl Halides

Reaction with Alkyl-or Aryllithium

Reaction with alkyl chlorosulfites

Reaction with alkyl halides

Reaction with alkyl halides to form

Reaction with alkyl hydroperoxides

Reaction with alkyl radicals

Reaction with, alkylating agents

Reaction with, alkylating agents diazonium salts

Reaction with, alkylating agents hydrazine

Reaction with, alkylating agents phosphorus chloride

Reactions diamagnetic metal alkyl complexes with

Reactions of Alkyl Azides with Epoxides

Reactions of Transition Metal Compounds with Alkylating or Arylating Reagents

Reactions with 2-Alkyl Groups

Reactions with Alkyl and Thiyl Radicals

Reactions with Alkylating and Acylating Agents

Reactions with Simple Alkyl Halides

Reactions with activated alkyl halides

Reactions with alkyl pentacarbonyl carbene anions

Reactions with epoxides alkylation

Reactions with epoxides secondary alkyl

Reactions with epoxides tertiary alkyl

Reactivity, alkyl halides with reactions

Rhodium-Catalyzed Allylic Alkylation Reaction with Stabilized Carbon Nucleophiles

Schmidt Rearrangement Reactions with Alkyl Azides

Secondary alkyl halides acetylide anion reactions with

Selenides reactions with alkyl metals

Silver cyanide, reaction with alkyl

Silver cyanide, reaction with alkyl halides in synthesis of isocyanides

Silver nitrate, reaction with alkyl halides

Silver oxide, reaction with boron alkyls

Silver reaction with alkyl halides

Sodium acetylide reaction with, alkyl halides

Sodium alkyl thiolates, reaction with

Sodium alkyl thiolates, reaction with halogen substituted metal complexes

Sodium reaction with alkyl halides

Sodium sulfide, reaction with alkyl halides

Stoichiometric reactions of isocyanides with metal alkyls

Sulfones anions, reaction with alkyl halides

Sulfoxides, alkyl aryl reactions with carbonyl compounds

Synthetic reactions with alkyl

Tertiary alkyl coupling reactions with alkenyl halides

Tetracarbonylferrate reaction with alkyl halides

The Reaction with Alkyl Halides

The reaction of alkyl radicals with

Thiocyanates reaction with alkyl halides

Thioethers reaction with alkyl halides

Thiol reaction with alkyl halides

Thiolate ions reaction with alkyl halides

Thiols reaction with alkyl halides

Thioureas reaction with alkyl halides

Titanium complexes, reaction with carbon alkyls

Triphenylphosphine reaction with alkyl halides

Triphenylphosphine, reaction with alkyl

Zinc alkyls reactions with

Zinc, reaction with alkyl halides

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