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Cyanocuprates, reactions with alkyl halides

Table 8.24. Reaction of Higher Order Cyanocuprates with Alkyl Halides... Table 8.24. Reaction of Higher Order Cyanocuprates with Alkyl Halides...
Allyl halides are also alkylated by zinc cyanocuprates. Allylic bromides, iodides and chlorides react successfully with these reagents, and a number of functional groups in the allylic halide (ester, sulfide, sulfoxide, ether, alkyl halides, acetals) stand up well to the conditions of reaction (equations 29 and 30)41 3. The regiochemistry of attack is predominantly Sn2. 1,3-Dichloroalkenes can be made to undergo two successive coupling reactions to this point, only two identical R group incorporations have been reported (equation 31)44. [Pg.1284]


See other pages where Cyanocuprates, reactions with alkyl halides is mentioned: [Pg.181]    [Pg.216]    [Pg.919]    [Pg.1277]    [Pg.265]    [Pg.679]    [Pg.727]    [Pg.156]    [Pg.216]    [Pg.223]    [Pg.591]    [Pg.934]    [Pg.685]   
See also in sourсe #XX -- [ Pg.1277 , Pg.1278 ]




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Alkyl halides reactions

Alkyl halides, alkylation reactions

Alkyl reaction with

Alkylation with alkyl halides

Cyanocuprates

Cyanocuprates, reactions

Reaction with alkyl halides

With alkyl halides

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