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Halides, alkyl, reaction with cyanoborohydride

Reactions.—New systems for the reduction of alkyl halides to alkanes include mixtures of lithium aluminium hydride with transition-metal chlorides (such as Ni or Co" chlorides) and some complex metal hydrides of copper, especially the THF-soluble Li4CuHs. Details of the application of sodium cyanoborohydride to the reduction of halides (and sulphonate esters) in dipolar aprotic solvents have been published. Virtually all other functional groups are inert to this convenient, mild, and efficient system, which has been used to develop a one-pot deoxygenation of primary alcohols (Scheme 39) via the iodides. The alternative cyanoborohydride reagents (55) and the polymeric (56) are also discussed. ... [Pg.130]

See other pages where Halides, alkyl, reaction with cyanoborohydride is mentioned: [Pg.20]    [Pg.440]    [Pg.1827]    [Pg.211]   
See also in sourсe #XX -- [ Pg.336 ]



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Alkyl halides reactions

Alkyl halides, alkylation reactions

Alkyl reaction with

Alkylation with alkyl halides

Cyanoborohydride alkylation

Reaction with alkyl halides

With alkyl halides

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