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Magnesium, reaction with alkyl halides form Grignard reagents

The reaction of metals with alkyl halide to form alkylmetal compounds is typical for lithium and magnesium. This so-called direct synthesis was applied to the preparation of both cyclopropyllithium" and derivatives and cyclopropylmagnesium halides under the standard preparative conditions of Grignard reagents without ring cleavage (equation 1). [Pg.499]

The answer is D. Alkyl magnesium halide or Grignard reagent can react with carbon dioxide to form carboxylic salts. The description of the reaction mentioned in the question also says that the reaction occured in acidic conditions. Under acidic conditions, the salt is converted to a carboxylic acid. So statement II is true. Furthermore, alkyl magnesium halide (Grignard reagent) acts as the nucleophile in the reaction. So statement III is tme. [Pg.442]

Studies on the reaction of magnesium with phenyl and alkyl halides at low temperature in the solid phase to form Grignard reagents point to Scheme 7. ... [Pg.302]


See other pages where Magnesium, reaction with alkyl halides form Grignard reagents is mentioned: [Pg.747]    [Pg.3]    [Pg.352]    [Pg.621]    [Pg.14]    [Pg.499]    [Pg.744]    [Pg.531]    [Pg.250]    [Pg.531]    [Pg.269]    [Pg.397]    [Pg.352]    [Pg.679]    [Pg.73]    [Pg.377]    [Pg.352]    [Pg.188]    [Pg.135]    [Pg.258]    [Pg.40]    [Pg.290]    [Pg.26]    [Pg.151]    [Pg.220]    [Pg.377]    [Pg.75]    [Pg.193]    [Pg.63]    [Pg.285]    [Pg.202]    [Pg.1274]    [Pg.742]    [Pg.743]    [Pg.743]    [Pg.751]    [Pg.855]    [Pg.642]    [Pg.276]    [Pg.17]    [Pg.168]    [Pg.488]    [Pg.295]    [Pg.106]    [Pg.848]    [Pg.196]   
See also in sourсe #XX -- [ Pg.143 , Pg.211 ]

See also in sourсe #XX -- [ Pg.143 , Pg.211 ]




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Alkyl Grignard reagents

Alkyl Grignards

Alkyl halides Grignard reaction

Alkyl halides reactions

Alkyl halides with magnesium

Alkyl halides, alkylation reactions

Alkyl reaction with

Alkyl reagents

Alkylating reagents

Alkylation with alkyl halides

Grignard reaction: alkylation

Grignard reagents reactions

Grignard reagents with halides

Grignard with halides

Halides magnesium

Halides reagents

Halides, alkyl reaction with magnesium

Halides, magnesium. Grignard

Halides, magnesium. Grignard reagents

Magnesium Grignard reactions

Magnesium Grignard reagent

Magnesium alkyl halides

Magnesium forms

Magnesium reactions

Magnesium reactions with

Magnesium reagents

Magnesium-alkyl halide reaction

Reaction with Grignard reagents

Reaction with alkyl halides

Reactions alkylating reagents

Reagent alkyl halides

Reagents alkylation

With Grignard Reagents

With alkyl halides

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