Reaction with, alkylating agents phosphorus chloride

Like the red solutions obtained from and NaOR, the red phosphides derived from phosphorus and organometallic reagents were found to react with alkylating agents to give tertiary phosphines s) Addition of butyl chloride to the reaction mixture from phenyllithium and (ratio 2 2 1) in ether gave di-butylphenylphospliine (37%) and butyldiphenylphosphine (44%). Similar products were obtained from the reactions of 4-methoxyphenyllithium, 3-trifluoro-methylphenyllithium or phenylsodium witli phosphorus and butyl halides ... 

MERCURY(n) NITRATE (10045-94-0, anhydrous 7783-34-8, monohydrate) Hg(N03)2 H,0 Noncombustible solid. Light sensitive. A powerful oxidizer accelerates the burning of combustible materials. Violent reaction, or may form explosive materials, with reducing agents, including hydrides, nitrides, phosphorus, stannous chloride, and sulfides alkyl esters (forms explosive alkyl nitrates) combustible materials (especially if finely divided), phosphinic acid, hypophosphoric acid, metal powders petroleiun hydrocarbons. Forms heat- and/or shock-sensitive compounds with acetylene (forms explosive mercmy acetylide), ethanol and other alcohols (may form explosive mercury fulminates), ferrocene, isobutene, phosphine gas (forms heat- and shock-sensitive precipitate) potassiiun cyanide, sulfur. Incompatible with strong acids, acetic anhydride, ammonia, ammonium hexacyanofenate(II), organic azides, citric acid, hydrazinium perchlorate, isopropyl chlorocarbonate, nitrosyl perchlorate, sodium thiosulfate, sulfamic acid, thiocyanates, hydrozoic acid, methyl isocyanoacetate, sodium peroxyborate, trinitrobenzoic acid, urea nitrate. Aqueous solution corrodes metals. 

URANIUM NITRATE or URANYL NITRATE (10102-06-4) NjO,U Noncombustible solid radioactive material. A powerful oxidizer accelerates the burning of combustible materials. Violent reaction with many materials reducing agents, including hydrides, nitrides, and sulfides alkyl esters combustible materials, ethers, fuels, organic substances, powdered metals phosphorus tin(II) chloride. Incompatible with cellulose. Reacts with water producing weak solution of nitric acid. Contact with steam may cause explosion. Attacks many plastics, rubber, and coatings. Attacks most metals in the presence of moisture. 

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