Abrasive resistance

Polybutylene exhibits high tear, impact, and puncture resistance. It also has low creep, excellent chemical resistance, and abrasion resistance with coilability. 

The abrasion resistance of ionomers is outstanding, and ionomer Aims exhibit optical clarity. In composite structures ionomers serve as a heat-seal layer. 

Its principal advantages are high resilience and good abrasion resistance. 

It possesses resistance to oils up to 120°C and excellent abrasion resistance and adhesion to metal. 

Spandex fibers are available as fine as 1.1 tex (10 den), and the finest extmded latex thread available is about 16 tex (140 den). The availabihty of spandex fibers in such fine sizes and their unique properties compared to mbber, eg, dyeabiUty, high modulus, abrasion resistance, and whiteness, has allowed extensive penetration into hosiery and sportswear markets. 

From 1910 onward waste filament yam had been chopped into short lengths suitable for use on the machinery designed to process cotton and wool staples into spun yams. In the 1930s new plants were built specifically to supply the staple fiber markets. During World War II the production of staple matched that of filament, and by 1950, staple viscose was the most important product. The new spun-yam oudets spawned a series of viscose developments aimed at matching the characteristics of wool and cotton more closely. Viscose rayon was, after all, silk-like. Compared with wool it lacked bulk, residence, and abrasion resistance. Compared to cotton, it was weaker, tended to shrink and crease more easily, and had a rather lean, limp hand. 

In the sheeting market, the low density polyethylenes are less important than the high density resins. The high density resins have excellent chemical resistance, stress-crack resistance, durabiUty, and low temperature properties which make them ideal for pond liners, waste treatment faciUties, and landfills. In thicker section, HMW-HDPE sheet makes good containers, trays, tmck-bed liners, disposable items, and concrete molds. The good durabiUty, abrasion resistance, and light weight are critical elements for its selection. 

Cellular mbber has been used extensively as shoe soles, where its combination of cushioning abiUty and wear resistance, coupled with desirable economics, has led to very wide acceptance. In this case the cushioning properties are of minor importance compared with the abrasion resistance and cost. Other significant cushioning appHcations for cellular mbbers and latex foam mbbers are as carpet underlay and as cushion padding ia athletic equipment. 

Catalysis is usually accompHshed through the use of tertiary amines such as triethylenediamine. Other catalysts such as 2,4,6-/m(/V,/V-dimethylaminomethyl)phenol are used in the presence of high levels of cmde MDI to promote trimerization of the isocyanate and thus form isocyanurate ring stmctures. These groups are more thermally stable than the urethane stmcture and hence are desirable for improved flammabiUty resistance (236). Some urethane content is desirable for improved physical properties such as abrasion resistance. 

The abihty of organically modified ceramics based on alumina, zkconia, titania, or siUca (and mixtures of each) to function as abrasion-resistant coatings has also been studied (62). Eor example, polycarbonate, when coated with an epoxy—aluminosihcate system, experiences a significant reduction in the degree of hazing induced by an abrader, as compared to uncoated polycarbonate. 

Some amorphous copoly(ether—sulfone) fkms have been prepared (117) with Ts around 130°C with no loss in weight up to 400°C in ak or N2. Other backbones iavestigated in this class of polymers are copoly(ether—amides) (118) and copoly(ether—ketones) (119). These polymers show good mechanical properties, flow characteristics, and abrasion resistance. 

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