Support reactors

Reactor options are determined primarily by the physical properties of the waste and the chemical and biochemical properties of the contaminants. System characteristics can favor a particular reactor option. If the waste is found in groundwater, then a continuous supported reactor is desirable, while a suspended... 

At the designer s discretion, buildings, structures, systems, portions of systems, and components that are not safety-related but support reactor operation or investment protection. 

Reactor Vessel Supports Steam Generator Supports Reactor Coolant Pump Supports... 

Inner control rods in the fuel region to support reactor startup and shutdown ... 

Outer control rods in the replaceable reflector region to support reactor power control and... 

Failure to complete fluidization of the support will result in poor-quality synthesis. Fluidization depends on solvent density/viscosity, volume/amount of the support, reactor design, and gas pressure. To achieve proper fluidization for a given volume/amount of support, a specific amount of solvent/solution is needed. A general correlation between mass of controlled-pore glass beads (most commonly used support), and solvent/solution is given in Table 1 and Fig. 2. 

Chapter 6.2.2.5 of the Safety Analysis Report (SAR) lists the Central Control Room instrumentation associated with the AACS. The Instrumentation list In the SAR was compared by the staff against the system s safety functions as listed in the RTIR. No deficiencies were found. The staff considers the system instrumentation to be adequate to support reactor restart. 

This analysis, which is performed to support reactor restart, shall consider postulated fire events when off-site power is available as well as when there is a coincident loss-of-off-site power. (See SER section 6.3.1, "Electrical Power Systems," for the definition of on-site and off-site power.)... 

Among the symbolic names suggested were MENTOR and MONITOR, DATUM and ORACLE. Among the abbreviations (more correctly known as acronyms) were LEOPARD, standing for low energy pile for reactor development, and ZEST, for zero-energy support reactor. 

Catalytic gas-phase reactions play an important role in many bulk chemical processes, such as in the production of methanol, ammonia, sulfuric acid, and nitric acid. In most processes, the effective area of the catalyst is critically important. Since these reactions take place at surfaces through processes of adsorption and desorption, any alteration of surface area naturally causes a change in the rate of reaction. Industrial catalysts are usually supported on porous materials, since this results in a much larger active area per unit of reactor volume. 

Another important reaction supporting nonlinear behaviour is the so-called FIS system, which involves a modification of the iodate-sulfite (Landolt) system by addition of ferrocyanide ion. The Landolt system alone supports bistability in a CSTR the addition of an extra feedback chaimel leads to an oscillatory system in a flow reactor. (This is a general and powerfiil technique, exploiting a feature known as the cross-shaped diagram , that has led to the design of the majority of known solution-phase oscillatory systems in flow... 

Industrial appHcations often require that bulk materials or Hquids be weighed in hoppers, silos, tanks, or reactor vessels, referred to collectively as vessels. Because they come in such a wide variety of si2es, shapes, and capacities, scales using these vessels as load receivers are not typically available as standard products. Vessels are usually custom-fabricated to suit a particular appHcation, then mounted on a scale. Some can be mounted on a standard scale such as a bench, portable, or floor scale. More typically, a number of weigh modules are used to support the vessel. This offers the scale designer great flexibiHty but certain precautions are necessary in order to constmct an accurate scale. Some of the more important factors associated with the design of vessel scales are discussed herein. 

The original German process used either carbonyl iron or electrolytic iron as hydrogenation catalyst (113). The fixed-bed reactor was maintained at 50—100°C and 20.26 MPa (200 atm) of hydrogen pressure, giving a product containing substantial amounts of both butynediol and butanediol. Newer, more selective processes use more active catalysts at lower pressures. In particular, supported palladium, alone (49) or with promoters (114,115), has been found useful. 

The MTO process employs a turbulent fluid-bed reactor system and typical conversions exceed 99.9%. The coked catalyst is continuously withdrawn from the reactor and burned in a regenerator. Coke yield and catalyst circulation are an order of magnitude lower than in fluid catalytic cracking (FCC). The MTO process was first scaled up in a 0.64 m /d (4 bbl/d) pilot plant and a successfiil 15.9 m /d (100 bbl/d) demonstration plant was operated in Germany with U.S. and German government support. 

This reaction is first conducted on a chromium-promoted iron oxide catalyst in the high temperature shift (HTS) reactor at about 370°C at the inlet. This catalyst is usually in the form of 6 x 6-mm or 9.5 x 9.5-mm tablets, SV about 4000 h . Converted gases are cooled outside of the HTS by producing steam or heating boiler feed water and are sent to the low temperature shift (LTS) converter at about 200—215°C to complete the water gas shift reaction. The LTS catalyst is a copper—zinc oxide catalyst supported on alumina. CO content of the effluent gas is usually 0.1—0.25% on a dry gas basis and has a 14°C approach to equihbrium, ie, an equihbrium temperature 14°C higher than actual, and SV about 4000 h . Operating at as low a temperature as possible is advantageous because of the more favorable equihbrium constants. The product gas from this section contains about 77% H2, 18% CO2, 0.30% CO, and 4.7% CH. ... 

CVD reactors can have one of several configurations. Each has particular advantages and disadvantages. Reactors that support wafers horizontally have difficulty controlling the deposition uniformity over all the exposed wafers. Reactors having vertical wafer support produce uniform deposition, but are mechanically complex. Barrel reactors are not suited for extended operation at temperatures greater than 1200°C. 

Cold-roUed alloys of lead with 0.06 wt % teUurium often attain ultimate tensile strengths of 25—30 MPa (3625—5350 psi). High mechanical strength, excellent creep resistance, and low levels of alloying elements have made lead—teUurium aUoys the primary material for nuclear shielding for smaU reactors such as those aboard submarines. The aUoy is self-supporting and does not generate secondary radiation. 

Ethjlben ne Synthesis. The synthesis of ethylbenzene for styrene production is another process in which ZSM-5 catalysts are employed. Although some ethylbenzene is obtained direcdy from petroleum, about 90% is synthetic. In earlier processes, benzene was alkylated with high purity ethylene in liquid-phase slurry reactors with promoted AlCl catalysts or the vapor-phase reaction of benzene with a dilute ethylene-containing feedstock with a BF catalyst supported on alumina. Both of these catalysts are corrosive and their handling presents problems. 

The fifth component is the stmcture, a material selected for weak absorption for neutrons, and having adequate strength and resistance to corrosion. In thermal reactors, uranium oxide pellets are held and supported by metal tubes, called the cladding. The cladding is composed of zirconium, in the form of an alloy called Zircaloy. Some early reactors used aluminum fast reactors use stainless steel. Additional hardware is required to hold the bundles of fuel rods within a fuel assembly and to support the assembhes that are inserted and removed from the reactor core. Stainless steel is commonly used for such hardware. If the reactor is operated at high temperature and pressure, a thick-walled steel reactor vessel is needed. 

Concern about the potential diversion of separated reactor-grade plutonium has led to a reduction ia U.S. governmental support of development of both plutonium recycle and the Hquid metal reactor. This latter ultimately depends on chemical reprocessing to achieve its long-range purpose of generating more nuclear fuel than it bums ia generating electricity. 

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