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That the widths are nonzero at all means that uncertainty will precede measurements endeavored by the chemist. As in Figure 3.10, a thermodynamic measurement attaches to Shannon information in a nontrivial way. Figure 3.12 then shows the contrasts in the Figure 3.11 examples. If the chemist queries the left-side pressure at a resolution of 50kgTIV i, there are 20 or so states that will manifest frequently, and which he or she can discriminate. The plot shows the sum of weighted surprisals as a function of state index i—the lower p values correspond to lower i. There is about 30% more information, approximately 3.8 bits, trapped via a system 1 measurement compared with system 2. Clearly, when an equation of state is used to anticipate a quantity such as pressure, there are more issues at play than a correction term to add or subtract. To be precise, an equation of state furnishes an estimate of an average of a physical quantity subject to fluctuations. [Pg.81]

Lubricants. Petroleum lubricants continue to be the mainstay for automotive, industrial, and process lubricants. Synthetic oils are used extensively in industry and for jet engines they, of course, are made from hydrocarbons. Since the viscosity index (a measure of the viscosity behavior of a lubricant with change in temperature) of lube oil fractions from different cmdes may vary from +140 to as low as —300, additional refining steps are needed. To improve the viscosity index (VI), lube oil fractions are subjected to solvent extraction, solvent dewaxing, solvent deasphalting, and hydrogenation. Furthermore, automotive lube oils typically contain about 12—14% additives. These additives maybe oxidation inhibitors to prevent formation of gum and varnish, corrosion inhibitors, or detergent dispersants, and viscosity index improvers. The United States consumption of lubricants is shown in Table 7. [Pg.367]

The first appearance of the term "alkyd resin" in the subject index of Chemicaly bstracts 2iS. in 1929, under Resins. It was not until 1936 that Alkyd Resins was Hsted in its alphabetical place, but stiU appeared as "See Resinous Products." The proliferation of Hterature on alkyd resins peaked from the 1940s through the 1960s. Research activities on alkyds in the United States, as indicated by the number of pubHcations, has apparentiy tapered off since the 1970s. Readers interested in alkyd history can find more detailed historical reviews elsewhere (1 4). [Pg.31]

In 1899 Thoms isolated an alcohol from Peru balsam oil, which he termed peruviol. This body was stated to have powerful antiseptic properties, but has not been further investigated until Schimmel Co. took up the subject. The oil after saponification was fractionated, and after benzyl alcohol had distilled over, a light oil with characteristic balsamic odour passed over. It boiled at 125° to 127° at 4 mm., and had a specific gravity 0 8987, optical rotation -1- 12° 22, and refractive index 1-48982. This body appeared to be identical with Hesse s nerolidol, whilst in physical and chemical properties it closely resembles peruviol. The characters of the various preparations were as follows —... [Pg.125]

Sach-verhslt, m., -verhaltnis, n. state of affairs, sachverstUndig, a. experienced, expert. Sach-versUiadiger, m. expert, authority, -ver-zeichms, n, subject index, -waiter, m. lawyer, attorney, -wdrterbuchi n, encyclopedia. [Pg.375]

Information on laboratory safety is available from many places. The public library usually has material on federal, state, and local safety regulations. The Index to Books in Print, also available at libraries, lists all material published by subject, author, and title. Scientific book publishers will be glad to add new names to their mailing lists for announcements of new publications on safety. [Pg.38]

My former student Guy Montgomery, who is now a researcher at the Mount Sinai School of Medicine in New York City, demonstrated experimentally that placebo pain reduction cannot be completely explained by the patient s emotional state - or by any other factor that should affect a person s whole body instead of just part of it. He put a placebo cream on the index finger of one hand of his subjects and nothing at all on their other hand. Then he induced pain by putting heavy weights on the subjects index... [Pg.137]

It is not surprising that the data produced as total petroleum hydrocarbons (EPA 418.1) suffer from several shortcomings as an index of potential ground-water contamination or health risk. In fact, it does not actually measure the total petroleum hydrocarbons in the sample but rather, measures a specific range of hydrocarbon compounds. This is caused by limitations of the extraction process (solvents used and the concentration steps) and the reference standards used for instrumental analysis. The method specifically states that it does not accurately measure the lighter fractions of gasoline [benzene-toluene-ethylbenzene-xylenes fraction (BTEX)], which should include the benzene-toluene-ethylbenzene-xylenes fraction. Further, the method was originally a method for water samples that has been modified for solids, and it is subject to bias. [Pg.231]

The third edition contains major improvements over the previous two editions. I have updated references. Each reaction is now supplemented with two to three representative examples in synthesis to showcase its synthetic utility. As Emil Fischer stated Science is not an abstraction but as a product of human endeavor it is inseparably bound up in its development with the personalities and fortunes of those who dedicate themselves to it. To that end, I added biographical sketches for most of the chemists who discovered or developed those name reactions. Furthemore, I have significantly beefed up the subject index to help the reader navigate the book more easily. [Pg.660]

Skin conductance represents changes in the electrical activity of skin. Resting skin conductance level (SCL) and the number of nonspecific fluctuations (spontaneous skin conductance responses [SCRs] seen in a resting state) are thought to reflect arousal. Skin conductance responses are also seen 1 to 3 seconds after stimulus onset, when they index the orienting reflex, which measures allocation of attention to the stimulus. Although SC arousal studies show some consistency, 4 out of 10 showed underarousal in antisocial-spectrum subjects no specific links to violence are reported (Scarpa and Raine, 1997). [Pg.216]

Collect the statistical weights into statistical weight matrices (of dimension Vj.j X v , where v,- is the number of rotational isomeric states of bond i), one per skeletal bond subject to conformational change, indexing rows and columns of the matrices with the RIS of the bond. The generic statistical weight matrix for bond i is termed U,-. [Pg.2]

Examples of the reduction of the number of equations abound. With adiabatic reactors in the steady state, the temperature is a function of the composition (see [A, D, F] and the introductions to papers under Adiabatic in the Index of Subjects in Publications.) This is the case also with the catalyst particle (see I, Ch. 2, and [81, 122] and Example 9). Examples of reduction in the number of equations because one or more can be solved immediately are given in Example 12 see also [280] and [310]. [Pg.27]

The parametric approach, which is not strictly needed for a single Gray-Scott reaction, works very well for an arbitrary number of parallel reactions and for continuous mixtures. Figure 16 shows a case of two parallel reactions for which an isola and a mushroom coexist. Because the notions of continuous mixtures and reactions will be treated in Chapter 8, G H and in the group of papers listed in the Index of Subjects in Publications under the heading Continuous mixtures, we can be very brief and start with the nondimensional equations. Let x be the index of the mixture whose species are /4(x). The steady-state concentration of the material with index in (x, x + dx) is V(x)dx, the feed concentration a(x)dx and the conversion U(x) = 1 - V/(x)/a(x), the last being defined only for values of x for which a(x) is not zero. B, the autocatalytic agent, forms itself as an undifferentiated product whose concentration is W. The rate of the first reaction, and hence p,(x), depends on the... [Pg.57]

It is impossible to discuss all papers which have appeared on the subjects included in this review (in order to keep it within reasonable limits) most of the important papers are included, and this review should give the reader an insight in the state of the art of solid state infra-red spectroscopy. The attention of the reader is drawn to the existence of Science Citation Index if a reference of this paper is used as a leading reference, Science Citation Index will quickly yield a list of other works which have cited the particular reference, enabling him to do a relatively complete literature search in a short time. [Pg.62]

In order to integrate further some of the various reactions mentioned, and to detect its presence by other methods, the vessels of the rat s mesoappendix were employed as a test object (Chambers-Zweifach preparation, 12). A good correlation between the presence of a vasoexcitor material-like substance in the extracts and the presence of hypertension was found. When the whole rat was used for assay, a much cruder index, sizable quantities of active pressor material were isolated from the blood only of those patients showing at least a degree of renal impairment (lessened ability to concentrate urine, etc.). In general it may be stated unequivocally that patients with severe hypertension have in their arterial blood extractable substances which are pressor for the rat there are less or undemonstrable amounts in blood of less severe or neurogenic hypertensive patients there is little or none in blood of normotensive subjects a vasoexcitor material-like activity is exerted by blood from most hypertensive patients adenyl compounds, having a depressor action, present in extracts of blood are less prevalent in those from hypertensive patients the active rat pressor material (pherentasin) is probably aminelike in nature, is not a protein, but may be a simple peptide or an amine. [Pg.14]

As stated previously, the MWT should be considered as one index from a set of indices for a subject or patient. Furthermore, the reason for doing an MWT evaluation is important. If the subject or patient is being evaluated as part of a fit-ness-for-duty examination in connection with a safety-sensitive job, the range of acceptable performance might be narrowed. If the subject or patient is being evaluated to determine whether an experimental intervention has improved ability to remain awake, then the focus may be shifted from average sleep latency to a metric reflective of change from baseline. [Pg.36]

The USPTO classifies claimed subject matter according to an internal classification system whose mysteries are not completely fathomable to the common man. The Index to the United States can be found at www.uspto.gov/web/patents/classification/uspcindex/indextouspc.html. [Pg.40]


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INDEX state

Subject index

Subject index solid-state

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