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Water and Solvent

In a Lewis-acid catalysed Diels-Alder reaction, the first step is coordination of the catalyst to a Lewis-basic site of the reactant. In a typical catalysed Diels-Alder reaction, the carbonyl oxygen of the dienophile coordinates to the Lewis acid. The most common solvents for these processes are inert apolar liquids such as dichloromethane or benzene. Protic solvents, and water in particular, are avoided because of their strong interactions wifti the catalyst and the reacting system. Interestingly, for other catalysed reactions such as hydroformylations the same solvents do not give problems. This paradox is a result of the difference in hardness of the reactants and the catalyst involved... [Pg.28]

In a second attempt to extend the scope of Lewis-acid catalysis of Diels-Alder reactions in water, we have used the Mannich reaction to convert a ketone-activated monodentate dienophile into a potentially chelating p-amino ketone. The Mannich reaction seemed ideally suited for the purpose of introducing a second coordination site on a temporary basis. This reaction adds a strongly Lewis-basic amino functionality on a position p to the ketone. Moreover, the Mannich reaction is usually a reversible process, which should allow removal of the auxiliary after the reaction. Furthermore, the reaction is compatible with the use of an aqueous medium. Some Mannich reactions have even been reported to benefit from the use of water ". Finally, Lewis-acid catalysis of Mannich-type reactions in mixtures of organic solvents and water has been reported ". Hence, if both addition of the auxiliary and the subsequent Diels-Alder reaction benefit from Lewis-acid catalysis, the possibility arises of merging these steps into a one-pot procedure. [Pg.114]

The metallic salts of trifluoromethanesulfonic acid can be prepared by reaction of the acid with the corresponding hydroxide or carbonate or by reaction of sulfonyl fluoride with the corresponding hydroxide. The salts are hydroscopic but can be dehydrated at 100°C under vacuum. The sodium salt has a melting point of 248°C and decomposes at 425°C. The lithium salt of trifluoromethanesulfonic acid [33454-82-9] CF SO Li, commonly called lithium triflate, is used as a battery electrolyte in primary lithium batteries because solutions of it exhibit high electrical conductivity, and because of the compound s low toxicity and excellent chemical stabiUty. It melts at 423°C and decomposes at 430°C. It is quite soluble in polar organic solvents and water. Table 2 shows the electrical conductivities of lithium triflate in comparison with other lithium electrolytes which are much more toxic (24). [Pg.315]

Fig. 1. Pressure required for propagation of decomposition flame through commercially pure acetylene free of solvent and water vapor in long horizontal pipes. Gas initially at room temperature ignition by thermal nonshock sources. Curve shows approximate least pressure for propagation (0), detonation,... Fig. 1. Pressure required for propagation of decomposition flame through commercially pure acetylene free of solvent and water vapor in long horizontal pipes. Gas initially at room temperature ignition by thermal nonshock sources. Curve shows approximate least pressure for propagation (0), detonation,...
Diketones. y-Diketones contain two carbonyl groups separated by two carbon atoms. With the exception of 2,5-hexanedione which is a high boiling Hquid, 1,4-diketones ate low melting white soHds with only faint odors. Lower members are soluble in organic solvents and water. Properties of representative 1,4-diketones are shown in Table 14. [Pg.499]

Inorg nic Colora.nts. In addition to various white pigments, other inorganic colorants such as those Hsted in Table 9 are used in a number of cosmetic products. These usually exhibit excellent lightfastness and are completely insoluble in solvents and water. [Pg.293]

Sephasorb HP (ultrafine, prepared by hydroxypropylation of crossed-linked dextran) can also be used for the separation of small molecules in organic solvents and water, and in addition it can withstand pressures up to 1400 psi making it useful in HPLC. These gels are best operated at pH values between 2 and 12, because solutions with high and low pH values slowly decompose them (see further in Chapter 6). [Pg.24]

When the relationship between the distribution coefficient of a solute and solvent composition, or the corrected retention volume and solvent composition, was evaluated for aqueous solvent mixtures, it was found that the simple relationship identified by Purnell and Laub and Katz et al. no longer applied. The suspected cause for the failure was the strong association between the solvent and water. As a consequence, the mixture was not binary in nature but, in fact, a ternary system. An aqueous solution of methanol, for example, contained methanol, water and methanol associated with water. It follows that the prediction of the net distribution coefficient or net retention volume for a ternary system would require the use of three distribution coefficients one representing the distribution of the solute between the stationary phase and water, one representing that between the stationary phase and methanol and one between the stationary phase and the methanol/water associate. Unfortunately, as the relative amount of association varies with the initial... [Pg.124]

Variety of form. Rubber base adhesives can be supplied for assembly operations as solvent or water-borne dispersions, hot melts, precast films, extruded tapes or reinforced films. In addition solvent and water-borne dispersions can be supplied as single or two-components systems. [Pg.576]

Arecoline, CgHj 302N. This, the most important alkaloid of areca nut, is an odourless, alkaline oil, b.p. 209°, volatile in steam, miseible with most organic solvents and water, but extractable from the latter by ether in presence of dissolved salts. The salts are crystalline, but usually deliquescent the hydrobromide, B. HBr, forms slender prisms, m.p. 177-9°, from hot alcohol the aurichloride, B. HAUCI4, is an oil, but the platinichloride, B2. H2PtClg, m.p. 176°, crystallises from water in orange-red rhombs. The methiodide forms glancing prisms, m.p. 173-4°. [Pg.12]

K. Grob and Z. Li, Intr oduction of water and water-containing solvent mixtures in capillary gas cliromatography. II. Wettability of precolumns by mixtures of organic solvents and water retention gas techniques , ]. Chromatogr. 473 391-400 (1989). [Pg.43]

This method also has only limited applications. The reason for this is that the distribution coeffidents of amino adds between organic solvent and water phases are generally small. There are some possibilities given in literature which are based on the alteration of the amino add. [Pg.251]

The raw product thus obtained is freed from solvent and water by vacuum distillation (7). The separation of the paraffin is performed under vacuum at temperatures above 220°C in a thin film evaporator (8) in the presence of overheated steam. The paraffin-containing solvent and the paraffin are recirculated to the process without further purification. [Pg.150]

Asymmetrical triesters of phosphoric acid of the general formula ROPO (OR,)2 (R = C8 i4 alkyl R, = C, 3 alkyl) were obtained in approximately 70% yield by treatment of a higher fatty alcohol and a Ci 3 alcohol with P0C13 in hexane or pyridine at <0°C. The products were soluble in nonpolar organic solvents and partially soluble in polar organic solvents and water. But the foamforming ability and foam stability of the compounds in water were low [11]. [Pg.557]

A mixture of monolauryl phosphate sodium salt and triethylamine in H20 was treated with glycidol at 80°C for 8 h to give 98% lauryl 2,3-dihydro-xypropyl phosphate sodium salt [304]. Dyeing aids for polyester fibers exist of triethanolamine salts of ethoxylated phenol-styrene adduct phosphate esters [294], Fatty ethanolamide phosphate surfactant are obtained from the reaction of fatty alcohols and fatty ethanolamides with phosphorus pentoxide and neutralization of the product [295]. A double bond in the alkyl group of phosphoric acid esters alter the properties of the molecule. Diethylethanolamine salt of oleyl phosphate is effectively used as a dispersant for antimony oxide in a mixture of xylene-type solvent and water. The composition is useful as an additive for preventing functional deterioration of fluid catalytic cracking catalysts for heavy petroleum fractions. When it was allowed to stand at room temperature for 1 month it shows almost no precipitation [241]. [Pg.615]

The diastereoselection of the Diels Alder reaction of methyl acrylate with cyclopentadiene was investigated [74] in microemulsions prepared with isooctane oil, CTAB as surfactant and 1-butanol as cosurfactant, and the results were compared with those found in pure solvents and water (Table 6.12). In emulsions rich in 1-butanol and formamide (entries 1 and 4) the reaction was slow (72 h) and the diastereoselectivity was practically the same as that... [Pg.282]

Cured phenol-formaldehydes are resistant to attack by most chemicals. Organic solvents and water have no effect on them, though they will swell in boiling phenols. Simple resins are readily attacked by sodium hydroxide solutions, but resins based on phenol derivatives, such as cresol, tend to be less affected by such solutions. Simple phenol-formaldehyde polymers are resistant to most acids, though formic and nitric acids will tend to attack them. Again, cresol-based polymers have resistance to such attack. [Pg.14]

Tetrachlorodibenzo-p-dioxin (TCDD) (I), an occasional contaminant in 2,4,5-T and other trichlorophenol derivatives, is the most toxic of the commonly-encountered dioxins (8) and it received most of our attention. Its low solubility in common solvents and water (ca. 2 ppb) limited our experiments since the products were difficult to identify by the conventional techniques of organic chemistry. However, TCDD has an absorption maximum at 307 nm in methanol—well within the solar spectrum observed at the earth s surface and near the region of maximum intensity (310-330 nm) of the UV lamps used in previous experiments (H 29). [Pg.46]

The zeolite nanocrystals have attracted the considerable attention of many researchers [1-5]. The syntheses of several types of zeolites with different nanometer sizes, such as silicalite-1, ZSM-5, A-type and Y-type, have been reported. Recently, micellar solutions or surfactant-containing solutions have been used for the preparation of zeolite nanoerystals [4,5], We have also successMIy prepared silicalite nanoerystals via hydrothermal synthesis using surfactants. In this study, we demonstrate a method for preparing mono-dispersed silicalite nanoerystals in a solution consisting of surfiictants, organic solvents and water. [Pg.185]

According to Eq. (2), the real and chemical energies of transfer differ by the term containing the difference in surface potentials of a given solvent and water (see Section XIV). [Pg.26]

The difference between the surface potentials of two solvents (e.g., an organic solvent and water) may also be measured by means of the following voltaic cells " (Fig. 12) ... [Pg.45]


See other pages where Water and Solvent is mentioned: [Pg.1633]    [Pg.152]    [Pg.44]    [Pg.46]    [Pg.2]    [Pg.316]    [Pg.211]    [Pg.212]    [Pg.337]    [Pg.338]    [Pg.339]    [Pg.354]    [Pg.462]    [Pg.110]    [Pg.141]    [Pg.455]    [Pg.873]    [Pg.24]    [Pg.41]    [Pg.28]    [Pg.129]    [Pg.67]    [Pg.68]    [Pg.425]    [Pg.425]    [Pg.13]    [Pg.214]    [Pg.228]    [Pg.45]   
See also in sourсe #XX -- [ Pg.100 ]




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