Soil, properties factors

Many factors affect the mechanisms and kinetics of sorption and transport processes. For instance, differences in the chemical stmcture and properties, ie, ionizahility, solubiUty in water, vapor pressure, and polarity, between pesticides affect their behavior in the environment through effects on sorption and transport processes. Differences in soil properties, ie, pH and percentage of organic carbon and clay contents, and soil conditions, ie, moisture content and landscape position climatic conditions, ie, temperature, precipitation, and radiation and cultural practices, ie, crop and tillage, can all modify the behavior of the pesticide in soils. Persistence of a pesticide in soil is a consequence of a complex interaction of processes. Because the persistence of a pesticide can govern its availabiUty and efficacy for pest control, as weU as its potential for adverse environmental impacts, knowledge of the basic processes is necessary if the benefits of the pesticide ate to be maximized. 

Soil is distinguished by the complex nature of its composition and of its interaction with other environmental factors. No two soils are exactly alike, and extremes of structure, composition and corrosive activity are found in different soils. Climatic factors of rainfall, temperature, air movement and sunlight can cause marked alterations in soil properties which relate directly to the rates at which corrosion will take place on metals buried in these soils. 

Combination electrical methods Tomashov and Mikhailovsky describe a method developed in the Soviet Union. This test is essentially a combination of resistivity measurement and polarisation rates on iron electrodes in soil in situ. The usefulness and value of this procedure has not as yet been determined by practical application by corrosion engineers. The development of this combination test does, however, represent an attempt to integrate some of the complex factors controlling corrosion rates in soil. Much more research on these factors and methods of measurement should in the future enable the corrosion engineer to evaluate soil properties with respect to application of corrosion-alleviating operations. 

Jenny (1941) attempted to quantitatively relate the factors of soil formation to soil properties such as N, C, or clay content, depth of leaching... 

Because borrow soils will be mixed and modified during placement, the cover soil for an ET landfill cover, as constructed, will be unique to the site. However, the soil properties may be easily described. The design process requires an evaluation of whether or not the proposed soil and plant system can achieve the goals for the cover. Numerous factors interact to influence ET cover performance. A mathematical model is needed for design that is capable of (1) evaluating the site water balance that is based on the interaction of soil, plant, and climate factors and (2) estimating the performance of an ET landfill cover during extended future time periods. 

KoC is an important parameter which describes the potential for movement or mobility of pesticides in soil, sediment and groundwater. Because of the structural complexity of these agrochemical molecules, the above simple relationship which considers only the chemical s hydrophobicity may fail for polar and ionic compounds. The effects of pH, soil properties, mineral surfaces and other factors influencing sorption become important. Other quantities, KD (sorption partition coefficient to the whole soil on a dry weight basis) and KqM (organic matter-water partition coefficient) are also commonly used to describe the extent of sorption. K0M is often estimated as 0.56 KoC, implying that organic matter is 56% carbon. 

An assessment of the rates and duration of phenolic acid production from a residue is an important first step. Laboratory and field studies for assessing the dynamics of phenolic acid production must include considerations of the nature of the residue, soil properties, nutrient status of the system, microbial biomass interrelationships, temperature, moisture, residue placement in or on the soil, and other factors that relate to the field. Soil properties in the field are especially important when organic residues are incorporated. When soils are wet, such as those with more than -0.02 MPa water potential, oxygen diffusion is impeded and anaerobic conditions prevail, especially in soils that are high in clay content. Under these circumstances, microbial byproducts change dramatically and one result, for example, is an increase in the production of phenolic acids. Phenolic acid production is also affected by temperature (22) and soil fertility status (23). While the C H ratio of an organic residue may influence the rate of its decomposition and, hence, the rate of phenolic acid production, the... 

Nickel is strongly adsorbed by soil, although to a lesser degree than lead, copper, and zinc (Rai and Zachara 1984). There are many adsorbing species in soil, and many factors affect the extent to which nickel is adsorbed, so the adsorption of nickel by soil is site specific. Soil properties such as texture, bulk density, pH, organic matter, the type and amount of clay minerals, and certain hydroxides influence the retention and release of metals by soil (Richter and Theis 1980). 

The major limitations of this technology are those factors that limit bacterial growth, such as temperature extremes, pH (below 3 or above 10), and presence of other contaminants detrimental to bacteria life. Remediation of petroleum contaminants using FyreZyme can be accomplished under both aerobic and anaerobic conditions however, remediation under aerobic conditions is faster and more complete. Other factors that may affect speed and completion of contaminant breakdown include moisture level, soil properties, and microbe mobility. In addition, the shelf life of FyreZyme is reduced from 5 to 2 years at temperatures above 100°F. 

Many site-specific factors can infiuence the cost of VESTRIP treatment. Soil properties that can influence the cost of any SVE system include permeability, porosity, depth and stratigraphy of the contamination, site heterogeneity, and seasonal water table fiuctuations. In general, the more permeable and homogenous the soil, the more efficiently any SVE will operate, and the lower treatment costs will be (D22449H, p. 4-4). 

Vacuum extraction alone is limited to treating unsaturated soils, and successful remediation is contingent upon factors such as soil properties and the volatility of the contaminants. Ideally, measured soil permeabilities should range between 10 " and 10 cm/sec, and contaminants should have a Henry s constant of 0.001 or higher. Also, sites with complex stratigraphy or contaminant distributions may require pilot demonstrations prior to the full implementation of a vacuum extraction system. 

The cost of operating a BCD system will vary from site to site, depending on factors such as soil properties and the type and volume of treated material. High clay or moisture content in soils, for example, can increase treatment costs (D20225V, p. 4). 

Although the majority of an applied triazine herbicide remains in the surface soil where it controls weeds while degrading, soil movement and persistence has been well studied and documented. A variety of factors affect triazine runoff, including method of application, soil properties, type of tillage, and environmental conditions. Estimates of triazine amounts in runoff from agricultural fields vary widely, with the highest concentrations occurring in the first 2 months after application. 

Thus, triazine movement and persistence are influenced by many factors, the interactions of which are not always easy to predict. Several models have been used as tools to estimate losses and to identify variables that will impact the rate and magnitude of loss. Considering the broad range in soil properties and climatic conditions used, some models performed well. However, modeling results and predictions are only estimates, and the fate and transport of triazines in the soil environment has been shown to be affected by many factors, including concentration, soil texture, variation in climate, and differences in tillage practices. 

Specific management practices influence triazine runoff and leaching, including fertilizer type, tillage crop residues, and previous crop history, as well as triazine application, formulation, and placement (Baker and Mickelson, 1994). Tillage systems affect various soil properties, such as soil moisture, temperature, pH, organic matter, water flow, and microbial populations, especially at and near the soil surface. These factors can affect transformation, retention, and transport of herbicides in soil. Interactions of and compensations between these processes can influence our prediction of triazine transport in soil. Therefore, triazine movement is usually studied under one management practice at a time. 

Contaminant distribution in soil and water depends on such factors as soil properties the physical and chemical properties of the contaminant contaminant fate and transport in soil, groundwater or surface water and even the manner in which the contaminant was introduced into the environment. The knowledge of these issues coupled with available information on site history and background allows us to make valid assumptions in the planning phase on contaminant distribution and variability at the site. 

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