Soils analysis

FIGURE 7.34 Theraiogravimetric (a, c) and derivative (b, d) curves for the AC horizon of a Houston clay soil (a, b) and the A horizon of a Houston black clay soil (c, d) the heating was conducted in N2 atmosphere by heating at 10°C/min. (Reprinted from Tan et al, Methods of Soil Analysis. Part 1. Physical and Mineralogical Methods, American Society of Agronomy-Soil Science Society of America, Madison, Wisconsin, 2010. With permission from the Soil Science Society of America.) 

The chemical characterization of soils and soil components include a number of methods, ranging from simple measurements such as pH or electrical conductivity to elemental analysis after total dissolution by digestion with HNO3/HCI/HF (Sparks 1996). Table 7.8 summarizes the most important analysis methods for elements of interest in soils. Many of these methods have been covered in previous sections. Some of them (e.g., chromatography, colorimetry) are common, well-known analytical techniques (Skoog et al. 2004 Harris 2010). 

Most of the methods described so far are immediately applicable to separated soil components however, in the analysis of a whole soil sample, matters are obvionsly more complicated because of the high number of components. There are several 

Commonly Employed Methods of Chemical Analysis for Elements in Soil 

Note AE = atomic emission AAS = atomic absorption IC = ionic chromatography Color = colorimetry. 

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Analysis of soils is an important task in the environmental researches. Reliability of ICP-MS results of soil analysis mainly depends on chemical sampling. Recently microwave systems are widely used for preparation of different samples. Influence of microwave radiation on sample ensures a complete decomposition of sample, greatly increases the mineralization, and allows possible losses of volatile elements to be minimized. In the given study to intensify decomposition of soils we applied the microwave sample preparation system MULTIWAVE (Anton Paar, Austria and Perkin-Elmer, USA) equipped with rotor from 6 autoclaves with TEM reaction chambers of 50 ml volume. 

Site preparation and soil analysis are very important for grassroots plant estimating. If the stage of the project is such that no site has been selected, a generous allowance for site preparation should be included. Once the site has been selected, this phase of the estimate should be firmed at once. If soil conditions are less than ideal, an estimate of the added cost for piling, compacting, or whatever the soil conditions require must be included. 

Table 10.10 Common instrumental techniques for soil analysis ...

Boden, m. soil earth, ground, land bottom base floor plate, tray (in a distilling column) (Dyeing) blotch loft, garret, -analyst /. soil analysis, -anspruch, m. soil... 

There is an opinion in literature that SAH are able to form an additional volume of pores, that is, to provide expansion of soil. Analysis of the tc(w) curves shows... 

The soil analysis is presented in Table II. Small amounts of 2,4-D and 2,4,5-T were detected in soil samples receiving these herbicides. Background values from the control soils were subtracted from the observed values in treated soils. The samples were not corrected for recovery since it was better than 80% for the method. Residues decreased with time after application. Leaching and microbial decomposition could account for this observation. 

Soil Analysis Modem Instrumental Techniques, Second Edition, edited by Keith A. Smith... 

For studies involving test substance application to soil, there may be a requirement for more soil information than for studies where applications are made to foliage of established crops. The study protocol should describe any specific requirements relative to soil type selection and how to confirm the soil characteristics for the study. Most studies simply require that the soil be identified by its name (e.g., Keystone silt loam) and composition (e.g., percent sand, silt, and clay). This information can typically be acquired from farm records, a soil survey of the local area, or a typical soil analysis by a local soil analysis laboratory. In some instances, a GLP compliant soil analysis must be completed. The study protocol must clearly define what is needed and how it is to be obtained. Unless specified in the protocol, non-GLP sources are adequate to identify the soil and its characteristics. The source of the soil information should be identified in the field trial record. 

Sulfonylureas are not directly amenable to gas chromatography (GC) because of their extremely low volatility and thermal instability. GC has been used in conjunction with diazomethane derivatization, pentafluorobenzyl bromide derivatization, and hydrolysis followed by analysis of the aryl sulfonamides. These approaches have not become widely accepted, owing to poor performance for the entire family of sulfonylureas. Capillary electrophoresis (CE) has been evaluated for water analysis and soil analysis. The low injection volumes required in CE may not yield the required sensitivity for certain applications. Enzyme immunoassay has been reported for chlorsulfuron and triasulfuron, with a limit of detection (LOD) ranging from 20 to 100 ng kg (ppt) in soil and water. 

Sample preparation consists of homogenization, extraction, and cleanup steps. In the case of multiresidue pesticide analysis, different approaches can have substantially different sample preparation procedures but may employ the same determinative steps. For example, in the case of soil analysis, the imidazolinone herbicides require extraction of the soil in 0.5 M NaQH solution, whereas for the sulfonylurea herbicides, 0.5M NaOH solution would completely decompose the compounds. However, these two classes of compounds have the same determinative procedure. Some detection methods may permit fewer sample preparation steps, but in some cases the quality of the results or ruggedness of the method suffers when short cuts are attempted. For example, when MS is used, one pitfall is that one may automatically assume that all matrix effects are eliminated because of the specificity and selectivity of MS. 

HPLC-UV, GC-ECD, GC-MS, LC-MS Figure 8 Schematic of general analytical method for soil analysis... 

R.G. Petersen and L.D. Calvin, Sampling, in Methods of Soil Analysis, Part I. Physical and Mineralogical Methods, Agronomy Monograph No. 9, second edition, American Society for Agronomy, Madison, WI, Chapter 2, pp. 33-51 (1986). 

The article on soil analysis has an extensive discussion of the kinetics on the dissipation rate. This article includes a recommendation on the data that should be reported. 

G.R. Blake and K.H. Hartge, Bulk density, in Methods of Soil Analysis Part 1 Physical and Mineralogical Methods, ed. A. Klute, Second edition, American Society of Agronomy and Soil Science Society of America, Madison, Wl, pp. 363-375 (1986). 

Regular soil analysis is also important for checking the levels of the important nutrients - phosphorus, potassium, calcium and magnesium. Care should be taken to confirm the method of analysis, because the Scottish system and that carried out by organic laboratories and by Agricultural Development and Advisory Service (ADAS) laboratories have different standards. For instance, on the Scottish system, very low for potassium (the lowest level) is less than 40, whereas the... 

Biological and Analytical Applications. - Phosphorus-31 n.m.r. continues to expand its application in the medical and biological fields20 and is now being applied to soil analysis.21 The problems involved in the use of FT 31P n.m.r. for quantitative determinations have been discussed.22 Samples of phosphinic carboxylic acids were cooled to -40°Cfor quantitative estimations.23... 

Gee, G.W. and Or, D., Particle size analysis, in Methods of Soil Analysis, Part 4, Physical Methods, Dane, J.H. and Topp, G.C., Eds, Soil Science Society of America, Madison, WI, 2002. 

Burnham, A. J. and R. I. Macphail (1995), Archaeological Sediments and Soils Analysis, Interpretation and Management, Institute of Archaeology, London Univ., London. 

Heidenreich, C. E. and V. A. Konrad (1973), Soil analysis at the Robataille site Part II A method useful in determining the location of Longhouse patterns, Ontario Archaeol. 21, 33-62. 

Patrick WH, Gambrell RP, Faulkner SP. Redox measurements of soil. In Sparks DL, editor. Methods of Soil Analysis, Part 3 Chemical Methods, 3rd Ed. Madison SSSA 1996. pp. 1255-1273. 

Saline soils are often recognized in the field by the presence of a white surface crust, by damp oily-looking surfaces devoid of vegetation, stunted plant growth, and sometimes by tipbum and firing of leaf margins. Soil analysis rather than visual observations are nevertheless needed to properly assess salinity. 

Reed S.T., Martens D.C. Copper and zinc . In Methods of soil analysis. Part 3. Chemical methods. Sparks D.L., ed. Madison, WI SSSA Book Ser. 5, 1996. 

Keeney DR (1982) Nitrogen-availability indices. In Page AL, Miller RH, Keeney DR (eds) Methods of soil analysis. Part 2 Chemical and microbiological properties. Am Soc Agron, Madison, Wisconsin, pp 711-733... 

Tabatabai MA (1994) Soil enzymes. In Weaver RW (ed) Methods of Soil Analysis. Part 2 Microbiological and biochemical properties. Soil Sci Soc Am, Madison, WI, pp 775-833... 

Numerical Evaluation of Partial Digestions for Soil Analysis, Talbot VMS Cu-Zn Prospect, Manitoba, Canada... 

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