Polymer substrates terephthalate

Friedrich et al. also used XPS to investigate the mechanisms responsible for adhesion between evaporated metal films and polymer substrates [28]. They suggested that the products formed at the metal/polymer interface were determined by redox reactions occurring between the metal and polymer. In particular, it was shown that carbonyl groups in polymers could react with chromium. Thus, a layer of chromium that was 0.4 nm in thickness decreased the carbonyl content on the surface of polyethylene terephthalate (PET) or polymethylmethacrylate (PMMA) by about 8% but decreased the carbonyl content on the surface of polycarbonate (PC) by 77%. The C(ls) and 0(ls) spectra of PC before and after evaporation of chromium onto the surface are shown in Fig. 22. Before evaporation of chromium, the C(ls) spectra consisted of two components near 284.6 eV that were assigned to carbon atoms in the benzene rings and in the methyl groups. Two additional... 

For polymer materials, the relatively poor temperatme tolerance is a severe problem that hinders their applications. Common polymer substrates, such as polyethylene and polyethylene terephthalate can only withstand a maximal temperature of 80 and 150"C, respectively. They are obviously too low for high-temperature fabrication methods, such as chemical vapor deposition and thermal annealing. This dilemma is currently compromised by conducting a transfer process where the devices are first fabricated at high... 

The surface characteristics of a microfluidic channel are very important in determining the flow in electrokinetically driven systems. In electrokinetically driven systems, the bulk flow is created by movement of the mobile diffuse layer near the channel wall/solution interface that is termed electroosmotic flow (EOF). The EOF is dependent on the surface of the microchannel walls. Roberts et al. demonstrated the generation of EOF on laser-ablated polymer substrates for the first time, using the parallel processing mode with a photomask and an ArF excimer laser at 193 nm [17]. A variety of polymer substrates such as polystyrene, polycarbonate, cellulose acetate, and poly(ethylene terephthalate) (PET) were ablated to fabricate microfluidic channels. The laser ablation process alters the surface chemistry of the machined regions and produced negatively charged. 

In terms of cost and manufacturing technologies for scalable devices, because the functional materials of OPVs are likely to dissolve in common organic solvents, they can be easily printed or coated onto the flexible polymer substrates such as polyethylene terephthalate (PET) and polyethylene... 

Polymer Substrate The substrate was Melinex 516 polyethylene terephthalate (PET, DuPont Corp.), which has a melting point of 250°C and a highly crystalline structure. 

Other Polymers. Besides polycarbonates, poly(methyl methacrylate)s, cycfic polyolefins, and uv-curable cross-linked polymers, a host of other polymers have been examined for their suitabiUty as substrate materials for optical data storage, preferably compact disks, in the last years. These polymers have not gained commercial importance polystyrene (PS), poly(vinyl chloride) (PVC), cellulose acetobutyrate (CAB), bis(diallylpolycarbonate) (BDPC), poly(ethylene terephthalate) (PET), styrene—acrylonitrile copolymers (SAN), poly(vinyl acetate) (PVAC), and for substrates with high resistance to heat softening, polysulfones (PSU) and polyimides (PI). 

The primary substrates or support iaclude many types of paper and paperboard, polymer films such as polyethylene terephthalate, metal foils, woven and nonwoven fabrics, fibers, and metal cods. Although the coating process is better suited to continuous webs than to short iadividual sheets, it does work very well for intermittent coating, such as ia the printing process. In general, there is an ideal coater arrangement for any given product. 

Polymer coatings on stiffer substrates can be measured by time-resolved techniques (Sinton et al. 1989). Often in these cases it is not convenient to measure a direct reflection from an uncoated part of the substrate at more or less the same time, and anyway the substrate may not be flat, but this may not matter if it can be assumed that either the thickness or the longitudinal velocity of the coating does not vary. The time interval between the echoes from the top and bottom surfaces of the coating can then be used to determine the unknown quantity. An example of the kind of signal that can be obtained is shown in Fig. 10.5. The specimen was a coating of PET (polyethylene terephthalate) 15 m thick on a stone-finish rolled steel substrate. Although there is some overlap of the two echoes, there is no difficulty in... 

Fig. 10.5. Signals reflected from the top and bottom surfaces of a 15 ym thick coating of polyethylene terephthalate on a stone-finish rolled steel substrate, using a short pulse of centre frequency 230 MHz and half-power bandwidth 110 MHz z = +40 (with the top surface of the polymer as datum) (Sinton etal. 1989).

Quantitative characterization of plasma-polymer films, especially of ultrathin fluorinated carbon plasma polymer films, has been performed by ToF-SIMS to study changes in the surface composition and molecular distribution. CFX films on silicon and polyethylene terephthalate (PET) substrates were exposed to a pulsed Ar/CHF3 plasma by varying the deposition time from 10-90 s.111-113 The results show differences in film growth and CFX cross linking for the silicon and PET substrates.111... 

When a polymer film is used as a substrate, aqueous Ti02 paste without organic surfactants is sintered at relatively low temperatures, with approximately 150°C being sufficient to produce mechanically stable 2 films. Sommeling et al. at ECN used an ITO-coated polyethylene terephthalate) (PET) film as a substrate and prepared a plastic DSSC [164-167]. A cell performance with a 7 of 15 pA/cm2, Voc of 0.48 V, and ff of 0.67 was obtained at an illumination intensity of 250 lux. This performance is sufficient for a power supply for indoor applications such as watches and calculators. Under AM 1.5 irradiation, a Vtx of 0.7 V and /sc of 2 mA/cm2 were obtained. 

PBDEs are used in different resins, polymers, and substrates at levels ranging from 5 to 30% by weight (EU 2001). Plastic materials that utilize PBDEs as flame retardants include ABS polyacrylonitrile (PAN) polyamide(PA) polybutylene terephthalate (PBT) polyethylene (PE) cross-linked polyethylene (XPE) polyethylene terephthalate (PET) polypropylene (PP) polystyrene (PS) high-impact polystyrene (HIPS) polyvinyl chloride (PVC) polyurethane (PUR) and unsaturated polyester (UPE). These polymers and examples of their final products are summarized inTable 5-2 (Hardy 2002 WHO 1994a). 

T50I(NPG)/PMDA was of particular interest because of its adhesive characteristics, oxidative stability, and polymer cost. Table III shows the improvement in adhesion obtained when various substrates were coated with blends containing this polyester (acid number 39). As indicated in the table, the ease of obtaining adhesion on the different substrates decreased approximately in the following order brass > steel > copper > chrome-coated steel > aluminum > nylon 66 > poly (ethylene terephthalate). In spite of the wide differences in structure and polarity of the various polymers, the carboxylated polyester significantly improved the adhesion of the coatings. 

One of the main drivers in moving to plastic substrates is that it opens up the possibility of roll-to-roll processing and the process and economic advantages that this brings. Under these conditions a winding tension will clearly be present and polymer film substrates with low moduli will be susceptible to internal deformation, particularly at elevated process temperatures. Figure 7.8 shows a comparison between poly(ethylene terephthalate) and poly(ethylene naphthalate) films. 

Substrates used included fiber-reinforced epoxy base polymer [FRP], nylon 66, polytetrafluoroethylene [Teflon], poly(ethylene terephthalate) [PET], phenolic resin, and thermoplastic polyimide [ULTEM, GE]. FRPs were the primary substrates used. Initially, they were cleaned with detergent in an ultrasonic bath followed by rinsing with deionized water and alcohol. For further cleaning, they were treated with oxygen plasma (1.33 seem, 60 W, 5 min) followed by a hydrogen plasma treatment (3 seem, 60 W, 5 min). 

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