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Reactions with Organics

The CAMEO system is a remarkable achievement that is able to model the mechanism and course of a wide range of organic reactions with a reasonable success rate. In this sense it is also highly valuable as a tool for teaching mechanistic organic chemistiy... [Pg.549]

One needs to interpret product data from preparative organic reactions with a great deal of reservation (cf. Section III,B,1 and... [Pg.361]

This is the decarboxylation of a (3-keto acid which undergoes smoothly even in the absence of an enzyme. Thus, it can be said that the mother nature utilizes an organic reaction with a low activation energy. The second step of the decarboxylation is the conversion of a-ketoglutaric acid to succinic acid (Fig. 3). This is the same type of reaction as the decarboxylation of pyruvic acid. [Pg.305]

As a kind of specialty solutions for the real hard cases where fouling is intense and unavoidable, IMM first proposed ideas to develop special micro mixers for fouling-intense reactions and conducted feasibility tests, among them very fast organic reactions with spontaneous precipitation such as the amidation of acetyl chloride in THF [134]. The Forschimgszentrum Karlsruhe developed special anti-foul-ing coatings in cooperation with partners [135]. [Pg.49]

A third method of solving the kinetics dilemma is to use organic reactions with functionalized inert coordination compunds. An example of a cobalt(III) polymer which has been prepared in this manner is shown below. [Pg.465]

Biochemical reactions are basically the same as other chemical organic reactions with their thermodynamic and mechanistic characteristics, but they have the enzyme stage. Laws of thermodynamics, standard energy status and standard free energy change, reduction-oxidation (redox) and electrochemical potential equations are applicable to these reactions. Enzymes catalyse reactions and induce them to be much faster . Enzymes are classified by international... [Pg.124]

This section is concerned with the quantitative correlation of reaction rates and equilibria of organic reactions with the structure of the reactants. We will restrict the discussion to benzene derivatives. The focus is on a remarkably simple treatment developed by L. P. Hammett in 1935, which has been tremendously influential. Hammett s correlation covers chemical reactivity, spectroscopy and other physical properties, and even the biological activity of drugs. Virtually all quantitative treatments of reactivity of organic compounds in solution start with the kinds of correlations that are discussed in this section. [Pg.1329]

The theory of chemical reaction rates is still at a much more qualitative level of development than theories of molecular properties, but recent advances have made a considerable impact on organic chemistry. Stone gives a very comprehensive account of theories of organic reactions, with particular emphasis on models which can lead to predictions of relative rates of reactions. [Pg.145]

Brum, J. Dell Orco, P. Lapka, S. etal., Monitoring organic reactions with on-line atmospheric pressure ionization mass spectrometry The hydrolysis of isatin Rapid Commun. Mass Spectrom. 2001, 15, 1548-1553. [Pg.357]

Metal-organic reactions, with sonochemistry, 1, 313 Metal-organometallic coordination networks, and manganese complexes, 5, 803 Metal oxide intercalation... [Pg.143]

In 1930 Watson became head of the Chemistry Department of the Cardiff Technical College. With various collaborators, Watson continued studies of the kinetics and mechanism of organic reactions, with a particular interest in structure-reactivity correlations and wrote the important monograph to which reference has already been made.67 In 1936, Soper went to the Chair of Chemistry at Otago, New Zealand, where studies in physical organic chemistry continued for many years, apart from an interval in World War II. Soper s contributions to physical organic chemistry ceased with his appointment as Vice-Chancellor of Otago University in 1953. [Pg.95]

Chapter 8 begins the treatment of organic reactions with a discussion of nucleophilic substitution reactions. Elimination reactions are treated separately in Chapter 9 to make each chapter more manageable. Chapter 10 discusses synthetic uses of substitution and elimination reactions and introduces retrosynthetic analysis. Although this chapter contains many reactions, students have learned to identify the electrophile, leaving group, and nucleophile or base from Chapters 8 and 9. so they do not have to rely as much on memorization. Chapter 11 covers electrophilic additions to alkenes and alkynes. The behavior of carbocations, presented in Chapter 8, is very useful here. An additional section on synthesis has been added to this chapter as well. [Pg.1326]

This book will serve as a starting point in learning the amazing features of six-membered chairlike transition states in stereoselective organic reactions. With this book, I hope that students and practitioners alike will be able to propose reasonable transition states for the description of newly discovered stereoselective reactions. [Pg.222]

V. BASIC ORGANIC REACTIONS WITH ELECTROPHILIC ACTIVE CENTERS... [Pg.41]

EXAMPLES OF ORGANIC REACTIONS WITH NON-STATISTICAL DYNAMICS... [Pg.514]


See other pages where Reactions with Organics is mentioned: [Pg.200]    [Pg.290]    [Pg.150]    [Pg.379]    [Pg.442]    [Pg.360]    [Pg.225]    [Pg.133]    [Pg.135]    [Pg.2575]    [Pg.199]    [Pg.6]    [Pg.35]    [Pg.98]    [Pg.191]    [Pg.167]    [Pg.174]    [Pg.338]   


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Abstraction reaction with organic molecules

Acetylene reaction with organic halides

Addition reaction with organic molecules

Alcohol with organic acids, reaction

Alkynes reactions with organic halides

Ammonia reactions with organic matter

Anion radical reactions with organic

Anion reactions with organic halides

Antimony fluorides, reaction with organic

Antimony fluorides, reaction with organic halides

Basic Organic Reactions with Electrophilic Active Centers

By reaction of organic halides with magnesium

Carbon atoms, energetic, reactions with organic compounds

Carbon monoxide, reaction with organic

Carbon monoxide, reaction with organic halides

Chlorine reactions with organics

Copper reactions with organic matter

Coupling reactions alkenes with organic halides (Heck

Cross-coupling Reactions of Terminal Alkynes with Organic Halides

Cross-coupling reactions with organic halides

Cycloaddition Reactions with Diazoalkanes in Organic Synthesis

Disilanes, reaction with organic halides

Elimination reactions organic synthesis with

Energetic tritium and carbon atoms reactions of,with organic

Energetic tritium and carbon atoms, reactions of, with organic compounds

Examples of Organic Reactions With Non-Statistical Dynamics

Fluorin , reaction with organic compounds

Hydrated electrons, reactions of, with organic compounds

Hydrides reaction with organic halides

Hydrides reactions, with unsaturated organic compounds

Hydroxyl reaction with organic molecules

Inorganic Ion-Radicals in Reactions with Organic Substrates

Iron chloride, radical reactions with organic

Lithium aluminum hydride reaction with organic halides

Metal atoms reactions with small-molecule organic

Metallo-organic compounds, reaction with

Nitrate radical reaction with organic compound

Nitric reaction with organic compound

Nitrite, reaction with organic matter

Nitrogen reaction with organics

Nonpolar organic compounds, reaction with

Nucleophile organic compound reactions with

OZONE REACTIONS WITH ORGANIC COMPOUNDS

Olefin reaction with organic halides

Organic acids reaction with vegetable oils

Organic functional groups, reaction with

Organic functional groups, reaction with aniline

Organic halides coupling reaction with organoboron

Organic halides coupling reaction with organocuprates

Organic halides reaction with alkene

Organic halides reaction with metals

Organic peroxides, chemical reaction with

Organic peroxy radical reaction with

Organic reaction with nitrite

Organic reactions regioselective bromination with bromine

Organic reactions with diazomethane

Organoboron compounds metal-catalyzed cross-coupling reactions, with organic

Organotin Hydrides, Reactions with Organic Compounds

Palladium, allylchlorocatalyst TASF reaction with organic halides

Peroxides, organic reaction with sulfides

Peroxy radicals reactions with organic compounds

Preparation of Active Copper and Reaction with Organic Halides to Yield Organocopper Reagents

Preparation reaction with organic halide (Suzuki

Radical Reactions of Organic Azides with Tributyltin Hydride

Radical reactions with organic halides

Reaction addition with organic compounds

Reaction of Alkynes with Organic Halides

Reaction of NO with Organic Compounds

Reaction of metal atoms with organic compounds

Reaction of organic halides with magnesium

Reaction of organic halides with magnesium metal

Reaction with organic compounds

Reaction with organic halide

Reaction with organic halide (Heck

Reaction with organic matter

Reaction with sedimentary organic

Reaction with sedimentary organic matter

Reactions of Anionic Complexes with Organic Halides

Reactions of Inorganic Radicals with Organic Substrates

Reactions of Nitrogen Dioxide with Organic Compounds

Reactions of Organic Compounds with Transients from Water

Reactions of Organic Free Radicals with Metal Complexes

Reactions of Superoxide Ion with Organic Electrophiles

Reactions of Superoxide Ion with Organic H Acids

Reactions of Tetrahydroborates with Organic Compounds

Reactions with Aryl Chlorides and Other Organic Electrophiles

Reactions with Diazonium Salts, Organic Halides, and Carboxylic Acids

Reactions with Halogens and Organic Halides

Reactions with Organic Fluorides

Reactions with Organic Substances

Reactions with Organic Substrates

Reactions with organic molecules

Subject reaction with organics

Sulfides, organic reaction with iron

Superoxide reactions with organic compounds

Survey on Reactions with Organic Compounds

Thayer, John S., Not for Synthesis Only The Reactions of Organic Halides with etal Surfaces

The Reaction of Stannylmetallic Compounds with Organic Electrophiles

Through Reactions with Organic Tellurium Compounds

Transition metal atoms reactions with organic substrates

Triphenylphosphine, reaction with organic

Triphenylphosphine, reaction with organic azides

Tritium atoms, energetic reactions with organic compounds

Tunneling reactions of biphenyl anion radical with electron acceptor organic molecules

Unsaturated organic molecules, coupling reactions with

With rhodium organic substrate reactions

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