Reactions of Inorganic Radicals with Organic Substrates

Reactions of Inorganic Radicals with Organic Substrates 

The -N02 radical (and also the C03 radical) are of some biological interest (Augusto et al. 2002) because they play some role in the reactions of peroxyni-trite (Chap. 2.4). For example, N02 oxidizes tyrosine to nitrotyrosine (Prutz et al. 1985b), and the latter has been considered a promoter of free-radical damage in DNA model systems (Prutz 1986). In this context, it may be of interest that CCV reacts with a self-complementary ODN (k = 1.9 x 107 dm3 mol-1 s 1) exclusively at G (by ET) (Chap. 11.2). 

Alegre ML, Gerones M, Rosso JA, Bertolotti SG, Braun AM, Martiere DO, Gonzales MC (2000) Kinetic study of the reactions of chlorine atoms and Cl2 radical anions in agueous solutions. I. Reaction with benzene. J Phys Chem A 104 3117-3125 

Alfassi ZB, Prutz WA, Schuler RH (1986) Intermediates in the oxidation of azide ion in acidic solutions. Phys Chem 90 1198-1203 

Alfassi ZB, Huie RE, Neta P, Shoute LCT (1990) Temperature dependence of the rate constants for reaction of inorganic radicals with organic reductants. J Phys Chem 94 8800-8805 

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Reactions of Inorganic Radicals with Organic Substrates 94... 

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