Reactions with organic compounds

The halogen fluorides are binary compounds of bromine, chlorine, and iodine with fluorine. Of the eight known compounds, only bromine trifluoride, chlorine trifluoride, and iodine pentafluoride have been of commercial importance. Properties and appHcations have been reviewed (1 7) as have the reactions with organic compounds (8). Reviews covering the methods of preparation, properties, and analytical chemistry of the halogen fluorides are also available (9). 

Reactions With Organic Compounds. Most organic compounds react vigorously exhibiting incandescence or even explosively with CIF3... 

Reactions with Organic Compounds. Tetrafluoroethylene and OF2 react spontaneously to form C2F and COF2. Ethylene and OF2 may react explosively, but under controlled conditions monofluoroethane and 1,2-difluoroethane can be recovered (33). Benzene is oxidized to quinone and hydroquinone by OF2. Methanol and ethanol are oxidized at room temperature (4). Organic amines are extensively degraded by OF2 at room temperature, but primary aHphatic amines in a fluorocarbon solvent at —42°C are smoothly oxidized to the corresponding nitroso compounds (34). 

Thus, for a successful fluorination process involving elemental fluorine, the number of coUisions must be drasticaUy reduced in the initial stages the rate of fluorination must be slow enough to aUow relaxation processes to occur and a heat sink must be provided to remove the reaction heat. Most direct fluorination reactions with organic compounds are performed at or near room temperature unless reaction rates are so fast that excessive fragmentation, charring, or decomposition occurs and a much lower temperature is desirable. 

Reaction with Organic Compounds. Many organic reactions are catalyzed by acids such as HCl. Typical examples of the use of HCl in these processes include conversion of HgnoceUulose to hexose and pentose, sucrose to inverted sugar, esterification of aromatic acids, transformation of acetaminochlorobenzene to chloroaruHdes, and inversion of methone [1074-95-9]. 

Reaction with Organic Compounds. Aluminum is not attacked by saturated or unsaturated, aUphatic or aromatic hydrocarbons. Halogenated derivatives of hydrocarbons do not generally react with aluminum except in the presence of water, which leads to the forma tion of halogen acids. The chemical stabiUty of aluminum in the presence of alcohols is very good and stabiUty is excellent in the presence of aldehydes, ketones, and quinones. 

Sulfur dichloride undergoes many of the same reactions with organic compounds as described for sulfur monochloride. Addition to olefins affords a route to bis(2-chloroalkyl) sulfides and, ia certain cases, heterocycHc sulfides (159,160). 

Reactions with Organic Compounds. The addition of biomine to unsatuiated carbon compounds occurs readily. 

An alternative oxidizing agent, similar to chromic acid in its reactions with organic compounds, is potassium permanganate (KMn04). 

Solutions of alkali metals in liquid ammonia have been developed as versatile reducing agents which effect reactions with organic compounds that are otherwise difficult or impossible/ Aromatic systems are reduced smoothly to cyclic mono- or di-olefins and alkynes are reduced stereospecifically to frani-alkenes (in contrast to Pd/H2 which gives cA-alkenes). 

P. S. Bailey, Ozonation in Organic Chemistry, Vol. 1, Olefinic Compounds, Academic Press, New York, 1978, 272 pp. Vol. 2, Nonolefinic Compounds, 1982, 496 pp. S. D. Razumovski and G. E. Zaikov, Ozone and Its Reactions with Organic Compounds, Elsevier, Amsterdam, 1984, 404 pp. 

B. Ranby and J. F. Rabek (eds.) Singlet Oxygen Reactions with Organic Compounds and Polymers, Wiley, Chichester, 1978, 331 pp. 

In reactions with organic compounds FCIO3 acts either as an oxidant or as a 1- or 2-centre electrophile which can therefore be used to introduce either F, a -CIO3 group, or both F and O into the molecule. As FCIO3 is highly susceptible to nucleophilic attack at Cl it reacts readily with organic anions ... 

Nitric acid also undergoes reactions with organic compounds wherein the acid serves neither as an oxidizing agent nor as a source of hydrogen ions. The formation of organic nitrates by esterification (O-nitration) involves reaction with the hydroxyl group ... 

Organotin Hydrides, Reactions with Organic Compounds, 1, 47... 

Razumovskii, S.D., and Zaikov, G.E., "Ozone and Its Reactions with Organic Compounds".Elsevier. 1984. 

Ozone Reactions with Organic Compounds, ACS 112, Washington, ACS, 1972... 

Carbon atoms, energetic, reactions with organic compounds, 3,201... 

Atkinson, R., Carter, W.P.L. (1984) Kinetics and mechanisms of gas-phase ozone reaction with organic compounds under atmospheric conditions. Chem. Rev. 84, 437 470. 

Rate Constants of Ozone Reaction with Organic Compounds (Experimental Data)... 

The nitroso compounds can be formed by reaction with organic compounds present in the atmosphere and include two categories namely N-nitroso and C-nitroso compounds. 

Ozone and its Reactions with Organic Compounds by S.D. Razumovskii and G.E. Zaikov... 

Gould, R. F., Ed. Ozone Reactions with Organic Compounds. Advances in Chem-btry Series 112. Washington, D.C. American Chemical Society, 1972. 129 pp. 

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