Nylons insulation

CATHODE ASSEMBLY CATHODE TOP PLATE GAS DISTRIBUTOR PLATE CATHODE BUS BAR CATHODE BUS BAR STUD GAS ENTRY EXTENSION NIPPLE GAS TUBE ANODE ASSEMBLY ANODE ASSEMBLY COVER COPPER ANODE NOZZLE NYLON INSULATOR CATHODE... 

TW - moisture resistance THW - resistant to hot water THHN-THWM - a hybrid construction having a layer of primary vinyl insulation covered with a thin layer of secondary nylon insulation. 

Nylon A class of synthetic fibres and plastics, polyamides. Manufactured by condensation polymerization of ct, oj-aminomonocarboxylic acids or of aliphatic diamines with aliphatic dicarboxylic acids. Also rormed specifically, e.g. from caprolactam. The different Nylons are identified by reference to the carbon numbers of the diacid and diamine (e.g. Nylon 66 is from hexamethylene diamine and adipic acid). Thermoplastic materials with high m.p., insolubility, toughness, impact resistance, low friction. Used in monofilaments, textiles, cables, insulation and in packing materials. U.S. production 1983 11 megatonnes. 

The Fe, Co, and Ni deposits are extremely fine grained at high current density and pH. Electroless nickel, cobalt, and nickel—cobalt alloy plating from fluoroborate-containing baths yields a deposit of superior corrosion resistance, low stress, and excellent hardenabiUty (114). Lead is plated alone or ia combination with tin, iadium, and antimony (115). Sound iasulators are made as lead—plastic laminates by electrolyticaHy coating Pb from a fluoroborate bath to 0.5 mm on a copper-coated nylon or polypropylene film (116) (see Insulation, acoustic). Steel plates can be simultaneously electrocoated with lead and poly(tetrafluoroethylene) (117). Solder is plated ia solutioas containing Pb(Bp4)2 and Sn(Bp4)2 thus the lustrous solder-plated object is coated with a Pb—Sn alloy (118). 

Nylon-11. Nylon-11 [25035-04-5] made by the polycondensation of 11-aminoundecanoic acid [2432-99-7] was first prepared by Carothers in 1935 but was first produced commercially in 1955 in France under the trade name Kilsan (167) Kilsan is a registered trademark of Elf Atochem Company. The polymer is prepared in a continuous process using phosphoric or hypophosphoric acid as a catalyst under inert atmosphere at ambient pressure. The total extractable content is low (0.5%) compared to nylon-6 (168). The polymer is hydrophobic, with a low melt point (T = 190° C), and has excellent electrical insulating properties. The effect of formic acid on the swelling behavior of nylon-11 has been studied (169), and such a treatment is claimed to produce a hard elastic fiber (170). 

Electrical Properties. Nylon has low electrical conductivity (high electrical resistivity) and behaves like an insulator. Nylon-6 has a resistivity of 6 X lO " Hem when dry and a resistivity of 2 x lO " Hem when conditioned at 100% rh at 20°C (44) nylon-6,6 responds similarly. 

Electrical Applications. Plastics are used for electrical insulation, conduit and enclosures, lighting fixtures, and mechanical devices. The most widely used plastic for wire and cable insulation is flexible, plasticized PVC, which constitutes well over half the market in insulating wires for buildings, automobiles, appHances, and power and control lines. Polyethylene is also a factor. Higher performance plastics such as nylon and fluoropolymers also play a smaller role in this area. 

Fig. 11. Crimp terminal contigurations (a) straight battel, 90° tongue, where wine without insulation is crimped in the battel, (b) Open battel having insulation-piercing lances, (c) Nylon or poly(vinyl chloride) preinsulated terminal accommodating and supporting wine insulation. Wine without end insulation is insetted in the terminal and is crimped. The terminal sleeve is not broken but conforms to the shape of the crimp indent, (d) Quick disconnect...

Nylon and poly(vinyl chloride) sleevings ate used for preinsulated terminals. Ceramics (qv) ate employed in some high voltage power connectors. Hard mbbet shells insulate connectors that serve underground power distribution cables. 

Multilayer Insulation Miiltilayer insulation consists of alternating layers of highly reflec ting material, such as aluminum foil or aluminized Mylar, and a low-conduc tivity spacer material or insulator, such as fiberglass mat or paper, glass fabric, or nylon net, all under high vacuum. When properly applied at the optimum density, this type of insulation can have an apparent thermal conduc tivity as low as 10 to 50 jlW/m-K between 20 and 300 K. 

Industrial equipment is a continuing area of development for plastics. Pipes, pumps, valves and sight glasses, made from such materials as PVC, PTFE and poly-4-methylpent-l-ene, have become well established on account of their corrosion resistance. The nylons are used for such diverse applications as mine conveyor belts and main drive gears for knitting machines and paper-making equipment. These and other materials are widely used where such features as toughness, abrasion resistance, corrosion resistance, non-stick properties, electrical insulation capability and transparency are of importance. 

Copolymers of chlorotrifluoroethylene and ethylene were introduced by Allied Chemicals under the trade name Halar in the early 1970s. This is essentially a 1 1 alternating copolymer compounded with stabilising additives. The polymer has mechanical properties more like those of nylon than of typical fluoroplastic, with low creep and very good impact strength. Furthermore the polymers have very good chemical resistance and electrical insulation properties and are resistant to burning. They may be injection moulded or formed into fibres. 

The nylons are reasonably good electrical insulators at low temperatures and under conditions of low humidity but the insulation properties deteriorate as humidity and temperature increase. The effects of the amount of absorbed water on the volume resistivity of nylon 66 is shown in Figure 18.15. This effect is even greater with nylon 6 but markedly less with nylon 11. Some typical electrical properties of the nylons are given in Table 18.5. 

Although the nylons are not generally considered as outstanding electrical insulators, their toughness and, to some extent, their temperature resistance, have led to applications in coil formers and terminal blocks. Indeed, the new nylon 46 materials would appear to be of particular interest here. Acetal resins, polysulphones, modified PPO and polycarbonates, however, present a challenge to applications in this sphere. 

Compared with aliphatic nylons it also shows greater rigidity and hardness, lower water absorption, low temperature coefficient of expansion, good resistance to heat and moisture, better electrical insulation properties, particularly under hot and damp condition, and of course transparency. 

The properties of the polyurethane moulding compositions are also very similar to nylon 66. The greatest difference in properties is in water absorption, the 6,4-polyurethane absorbing only about of that of nylon 66 under comparable conditions. This results in better dimensional stability and a good retention of electrical insulation properties in conditions of high humidity. Resistance to sulphuric acid is somewhat bettter than with nylon 66 but both types of polymer are dissolved by phenols and formic acid. 

In terms of environmental exposure, water and humidity must be carefully evaluated in electrical applications. In general, if a plastic absorbs a significant amount of water, the electrical resistivity drops. As examples this is the case for nylons and phenolic. Care must be used in selecting a dielectric to insure that the electrical properties such as the insulation resistance and dielectric strength, as well as other electrical properties are adequate under the conditions of field use, particularly if this involves exposure to high humidity conditions. Temperature also causes changes in most electrical products. 

In America there are promising signs for certain polymers. For example, poly(ethylene terephthalate) drinks bottles can be cleaned and recycled to give an acceptable grade of PET resin in a process that is economically viable. The recycled polymer is used as carpet fibre, furniture stuffing, or insulation. Waste nylon can also be recycled profitably. 

As nylons absorb water, their electrical properties deteriorate. Their performance as insulators declines and they become more susceptible to energy dissipation in alternating fields. 

The synthesis and properties of heat-resistant polyazomethines containing 2,5-disubstituted oxadiazole fragments, being insulators convertible into semiconductors by doping with iodine, have been described. The radical copolymerization of alkenes with the fluorescent co-monomer 2-/-butyl-5-(4 -vinyl-4-biphenylyl)-l,3,4-oxadiazole has resulted in useful macromolecular scintillators. Anionic polymerization of 2-phenyl-l,3,4-oxadiazolin-5-one has produced a nylon-type product <1996CHEC-II(4)268>. 

Quartz batting sandwiched between AFRSI quartz and fibrous glass fabric Nylon felt with a silicone rubber FRSI coating Silica tiles, borosilicate glass coating insulation HRSI with silicon boride added... 

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