Ether petroleum

Petroleum is the mixture of gaseous, liquid, and solid hydrocarbons (although the term is often restricted to the non-gases) derived from chemical reactions on prehistoric animal and vegetable matter which occurs as reservoirs in sedimentary rocks from which it is extracted. Petroleum (8002-05-9) syn. crude oil or petroleum oil also contains inorganics such as compounds of sulphur, nitrogen, oxygen, metals, etc. 

Natural gas (8006-14-2) is the gaseous component of petroleum. It is mostly methane with some ethane and smaller quantities of propane, butane, carbon dioxide, hydrogen sulphide, nitrogen, helium, and other gases. It is distributed in commerce as compressed or liquefied natural gas (LNG) for fuel and other purposes. 

Crude oil is processed in refineries by distillation, cracking, reforming, alkylation, polymerization, and other methods to generate gases, distillates, residuum, and sludges from which an enormous number of petroleum products 

The author was unable to find a reference for why an oil well sampling device might be charged with a compressed or liquefied gas. 

In addition to natural gas a number of gases are associated with petroleum  

Uses Petroleum ether is a flammable liquid used as a universal solvent and extractant during the processing of different chemicals like fats, waxes, paints, 

Toxicity Acute, prolonged exposure in workplaces has caused a variety of health disorders in workers (e.g., erythema, edema, skin peeling, loss of appetite, muscle weakness, paresthesia, CNS depression, peripheral nerve disorders, skin and respiratory irritation, chemical pneumonia in children).7 In addition, rubber solvents, varnish, thinners, and petroleum spirits cause skin irritation, respiratory problems, and hematologic effects in workers all demand proper handling and chemical safety. 

Water Less than 0.01% by Karl Fischer titration 

Ultraviolet absorbance Optical transparency is not controlled. Typical ultraviolet absorption spectrum is shown for information only. 

Refractive index 1.3650 + 0.0050 at 20 C Boiling range 30-60 C Residue Less than one mg/1 

Purity Greater than 99% total pentane and hexane Isomers by gc analysis Electron capture gc No residue peaks greater than 10 ng/1 as heptachlor epoxide. 

SPECIFICATIONS Packed under nitrogen Ultraviolet absorbance  

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Spirit G (petroleum ether) 0.645 30-75 (approx.) Petroleum gas equipment, perfume extraction... 

The inflammable solvents most frequently used for reaction media, extraction or recrystallisation are diethyl ether, petroleum ether (b.p. 40-60° and higher ranges), carbon disulphide, acetone, methyl and ethyl alcohols, di-Mo-propyl ether, benzene, and toluene. Special precautions must be taken in handling these (and other equivalent) solvents if the danger of Are is to be more or less completely eliminated. It is advisable to have, if possible, a special bench in the laboratory devoted entirely to the recovery or distillation of these solvents no flames are permitted on this bench. 

If the substance is found to be far too soluble in one solvent and much too insoluble in another solvent to allow of satisfactory recrystallisation, mixed solvents or solvent pairs may frequently be used with excellent results. The two solvents must, of course, be completely miscible. Recrystallisation from mixed solvents is carried out near the boiling point of the solvent. The compound is dissolved in the solvent in which it is very soluble, and the hot solvent, in which the substance is only sparingly soluble, is added cautiously until a slight turbidity is produced. The turbidity is then just cleared by the addition of a small quantity of the first solvent and the mixture is allowed to cool to room temperature crystals will separate. Pairs of liquids which may be used include alcohol and water alcohol and benzene benzene and petroleum ether acetone and petroleum ether glacial acetic acid and water. 

Another procedure, which is sometimes adopted, consists in adding a susi)eiisioii of the adsorbent in petroleum ether (b.p. ca. 60-80°) in small... 

Reference has already been made to the choice of solvent for introducing the mixture to the column. Generally speaking, adsorption takes place most readily from non-polar solvents, such as petroleum ether or benzene, and least from highly polar solvents such as alcohols, esters and pyridine. Frequently the solvent for introducing the mixture to the column and the developer are so chosen that the same solvent serves the dual purpose. 

The value of a graded series of eluents is that if one member of the series succeeds in desorbing a portion of an adsorbate, then another more power ful eluent should remove a further portion of the adsorbate. By mixing the eluents in various proportions, a finer gradation may be obtained, e.g., petroleum ether benzene and petroleum ether benzene and ether ether and acetone, etc. 

Petroleum ether fractions free from aromatic hydrocarbons are marketed, as are also n-hexane and n-heptane from petroleum. 

The alcohol may be purified by conversion into the calcium chloride addition compound. Treat it with anhydrous calcium chloride much heat is evolved and the addition compound is formed. After several hours, remove any oil which has not reacted by washing with petroleum ether (b.p. 60-80°). Decompose the solid with ice water, separate the alcohol, dry and distil. 

Petroleum ether is preferable to diethyl ether because it removes very little acetic acid from the aqueous phase. 

Cool the flask in ice, acidify with 10 ml. of cold 1 1-hydro-chloric acid and distil under reduced pressure (water pump) until most of the alcohol is removed. Add water to the residue, extract several times with ether, wash the combined ethereal extracts with N ammonia solution until a test portion gives no precipitate upon acidification. Extract the combined alkahne solutions once with a fresh portion of ether, and add the aqueous solution to an excess of dilute hydrochloric acid the final mixture should still be acidic to Congo red. Collect the crystalhne half-ester by filtration at the pump, wash it with water and dry at 100°. The yield is 14-5 g., m.p. 122-125°. Recrystallise by dissolving in about 40 ml. of warm benzene and adding an equal volume of petroleum ether (b.p. 40- 60°) 13 -5 g. of the colourless half-ester, m.p. 125-126°, are obtained. 

Alkvl Azides from Alkyl Bromides and Sodium Azide General procedure for the synthesis of alkyl azides. In a typical experiment, benzyl bromide (360 mg, 2.1 mmol) in petroleum ether (3 mL) and sodium azide (180 mg, 2.76 mmol) in water (3 mL) are admixed in a round-bottomed flask. To this stirred solution, pillared clay (100 mg) is added and the reaction mixture is refluxed with constant stirring at 90-100 C until all the starting material is consumed, as obsen/ed by thin layer chromatographv using pure hexane as solvent. The reaction is quenched with water and the product extracted into ether. The ether extracts are washed with water and the organic layer dried over sodium sulfate. The removal of solvent under reduced pressure affords the pure alkyl azides as confirmed by the spectral analysis. ... 

Sodium hydride (9.3 g, 0.22 mol) was washed with petroleum ether and DMSO (200 ml) was added and the mixture was heated to 100°C. A solution of diethyl malonate (35.2 g, 0.22mol) in DMSO (50 ml) was then added and stirred for 10 min to give a clear solution. A solution of 4-bromo-3-nitrobenzophenone (30.6 g, 0.10 mol) in DMSO (100 ml) was added and the resulting dark solution kept at 100 C for 1 h. The solution was poured into water (3 1) and extracted (2x) with ether. The extract was washed with water, dried (NajSOj and concentrated in vacuo to give an oil which crystallized. The solid was recrystallized from isopropyl alcohol to give 35.4 g (92% yield) of the product. 

Acetyl chlotide reacts with aromatic hydrocarbons and olefins in suitably inert solvents, such as carbon disulfide or petroleum ether, to furnish ketones (16). These reactions ate catalyzed by anhydrous aluminum chlotide and by other inorganic chlotides (17). The order of catalytic activity increases in the order... 

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