Mbber

Figure C2.1.16. Tensile stress as a Hmction of the extension ratio registered for a sample of natural mbber (circles). The broken curve is calculated from equation (C2.1.20). (Data from [79].)...

In section C2.6.4.3 it was shown how tlie addition of non-adsorbing polymer chains induces a depletion attraction between colloidal particles. If sufficient polymer is added, tliese attractions can be strong enough to induce a phase separation of tire colloidal particles. An early application of tliis was tire creaming of mbber latex [93]. 

Everything in Sections 9 and 10 on physiochemical relationships, and on polymers, mbbers, fats, oils, and waxes, respectively, has been retained. 

The principal direct appHcation of furfural is as a selective solvent. It is used for separating saturated from unsaturated compounds in petroleum refining, for the extractive distillation of butadiene and other hydrocarbons in the manufacture of synthetic mbber and for the production of... 

Tetrahydrofurfuryl alcohol is used in elastomer production. As a solvent for the polymerization initiator, it finds appHcation in the manufacture of chlorohydrin mbber. Additionally, tetrahydrofurfuryl alcohol is used as a catalyst solvent-activator and reactive diluent in epoxy formulations for a variety of apphcations. Where exceptional moisture resistance is needed, as for outdoor appHcations, furfuryl alcohol is used jointly with tetrahydrofurfuryl alcohol in epoxy adhesive formulations. 

Other furan compounds, best derived from furfural, are of interest although commercial volumes are considerably less than those of furfural, furfuryl alcohol, furan, or tetrahydrofurfuryl alcohol. Some of these compounds are stiU in developmental stages. Apphcations include solvents, resin intermediates, synthetic mbber modifiers, therapeutic uses, as well as general chemical intermediates. 

Rubber Modifiers. Derivatives of furan and tetrahydrofurfuryl alcohol are used in the polymerization of synthetic mbber to control stereoregularity and otherproperti.es (149,150). 

Fig. 5. Chemistry of cyclized mbbei—bis-a2ide negative acting resist, (a) Preparation of cyclized mbber resin from polyisoprene (b) photochemistry of aromatic bis-a2ide sensiti2ers. The primary photoproduct is a highly reactive nitrene which may combine with molecular oxygen to form oxygenated products, or may react with the resin matrix by addition or insertion to form polymer—polymer linkages.

Positive-Tone Photoresists based on Dissolution Inhibition by Diazonaphthoquinones. The intrinsic limitations of bis-azide—cycHzed mbber resist systems led the semiconductor industry to shift to a class of imaging materials based on diazonaphthoquinone (DNQ) photosensitizers. Both the chemistry and the imaging mechanism of these resists (Fig. 10) differ in fundamental ways from those described thus far (23). The DNQ acts as a dissolution inhibitor for the matrix resin, a low molecular weight condensation product of formaldehyde and cresol isomers known as novolac (24). The phenoHc stmcture renders the novolac polymer weakly acidic, and readily soluble in aqueous alkaline solutions. In admixture with an appropriate DNQ the polymer s dissolution rate is sharply decreased. Photolysis causes the DNQ to undergo a multistep reaction sequence, ultimately forming a base-soluble carboxyHc acid which does not inhibit film dissolution. Immersion of a pattemwise-exposed film of the resist in an aqueous solution of hydroxide ion leads to rapid dissolution of the exposed areas and only very slow dissolution of unexposed regions. In contrast with crosslinking resists, the film solubiHty is controUed by chemical and polarity differences rather than molecular size. 

As a vessel is loaded, it moves downward because of deflection of the load cells and support stmcture. Pipes rigidly attached to a vessel restrict its free movement and assume some portion of the load that cannot be measured by the load cells. This is very detrimental to scale accuracy. Deflection of the load cell is unavoidable deflection of the vessel support stmcture should be minimized. Anything which increases vessel deflection, eg, mbber pads used for shock protection, must be avoided. The total number of pipes should be minimized and be of the smallest diameter, thinnest wall possible. Pipe mns to weigh vessels must be horizontal and the first pipe support should be as far as possible from the vessel. Alternatively, a section of mbber hose or flexible bellows should be used to make the final connection to the vessel. The scale should be caUbrated using weights, not by means of an electrical simulation method, which cannot account for the effects of the piping or test the correct functioning of the scale. 

Another widely used overlay adhesive is the contact type. These specialized adhesives, in the same group as mbber cement, may be of the solvent-base or water-base types. They are often used to bond overlays such as wood veneer, vinyl (poly(vinyl chloride)) films, or high pressure laminates such as countertop overlays. 

Lay-up proceeds by laying down the veneer which is to be the back surface of the panel. Then a sufficient number of pieces of core veneer are passed through the glue spreader to form the next layer of cross-oriented veneer. The glue spreader commonly used in hardwood plywood manufacture is a roU coater in which a pair of opposing mbber roUs are coated with a thin layer of adhesive. As the veneer is passed between the roUs, the adhesive is transferred to the surfaces of the veneer. Adhesive is appHed only to the cross-pfles and in sufficient quantity to provide a continuous layer on both opposing faces of veneer. Thus, in the case of a three-ply panel, only the core layer is spread with adhesive and in that of a five-ply panel, the second and fourth layers both of which are cross-pfles, are spread with adhesive. Then the top surface veneer, which is normally the decorative surface, is placed on the assembly. 

Tripoli. TripoH [1317-95-9] is a fine grained, porous, decomposed siHceous rock produced mainly in Arkansas, Illinois, and Oklahoma. It is widely used for polishing and buffing metals, lacquer finishing, and plated products. Since tripoH particles are rounded, not sharp, it has a mild abrasive action particularly suited for polishing. TripoH is also used in toothpastes, in jewelry polishing, and as filler in paints, plastics, and mbber. Rottenstone and amorphous siHca are similar to tripoH and find the same uses. In 1987 the abrasive use of tripoH in the United States totaled 26.6 million tons and was valued at about 3.1 million however, the portion used as a filler totaled 71.1 million tons and had a value of almost 10 million (4). 

Bond Type. Most bonded abrasive products are produced with either a vitreous (glass or ceramic) or a resinoid (usually phenoHc resin) bond. Bonding agents such as mbber, shellac, sodium siHcate, magnesium oxychloride, or metal are used for special appHcations. 

In manufacture, the abrasive grain is mixed with cmde mbber, sulfur, and other ingredients for curing, then passed through calender roUs to produce a sheet of desired thickness. The wheels are stamped from this sheet and heated under pressure to vulcanise the mbber. 

The abrasive industry is highly competitive and many small companies worldwide successfully compete by specializing in a particular segment of the business, eg, disk wheels, mounted points, and mbber wheels. Costs in the fused abrasive industry are primarily in materials and electric power. Thus manufacturers seek out plant sites having the lowest power costs. Costs for coated abrasive manufacturers are capital and labor intensive and they seek out sources of low cost labor. 

Acetic anhydride is a useful solvent in certain nitrations, acetylation of amines and organosulfur compounds for mbber processing, and in pesticides. Though acetic acid is unexceptional as a fungicide, small percentages of anhydride in acetic acid, or in cold water solutions are powerful fungicides and bactericides. There are no reports of this appHcation in commerce. It is possible that anhydride may replace formaldehyde for certain mycocidal apphcations. 

Acetic anhydride penetrates the skin quickly and painfully forming bums and bUsters that are slow to heal. Anhydride is especially dangerous to the deUcate tissues of the eyes, ears, nose, and mouth. The odor threshold is 0.49 mg/m, but the eyes are affected by as Httie as 0.36 mg/m and electroencephalogram patterns are altered by only 0.18 mg/m. When handling acetic anhydride, mbber gloves that are free of pinholes are recommended for the hands, as well as plastic goggles for the eyes, and face-masks to cover the face and ears. 

Historically, the use of acetylene as raw material for chemical synthesis has depended strongly upon the avadabihty of alternative raw materials. The United States, which until recendy appeared to have limitless stocks of hydrocarbon feeds, has never depended upon acetylene to the same extent as Germany, which had more limited access to hydrocarbons (1). During Wodd War 1 the first manufacture of a synthetic mbber was undertaken ia Germany to replace imported natural mbber, which was no longer accessible. Acetylene derived from calcium carbide was used for preparation of... 

Methyl mbber, obtained by polymerization of this monomer, was expensive and had inferior properties, and its manufacture was discontinued at the end of Wodd War 1. By the time Wodd War 11 again shut off access to natural mbber, Germany had developed better synthetic mbbers based upon butadiene... 

Using cuprous chloride as catalyst, hydrogen chloride adds to acetylene, giving 2-chloro-1,3-butadiene [126-99-8], chloroprene, C H Cl, the monomer for neoprene mbber. 

Shipment, Stora.ge, ndPrice. Butyrolactone is shipped in unlined steel tank cars and plain steel dmms. Plain steel, stainless steel, aluminum, and nickel are suitable for storage and handling mbber, phenoHcs, and epoxy resins are not suitable. Butyrolactone is hygroscopic and should be protected from moisture. Because of its low free2ing point (—44° C), no provision for heating storage vessels is needed. 

The combination of durability and clarity and the ability to tailor molecules relatively easily to specific applications have made acryflc esters prime candidates for numerous and diverse applications. At normal temperatures the polyacrylates are soft polymers and therefore tend to find use in applications that require flexibility or extensibility. However, the ease of copolymerizing the softer acrylates with the harder methacrylates, styrene, acrylonitrile, and vinyl acetate, allows the manufacture of products that range from soft mbbers to hard nonfilm-forming polymers. 

Polyacrylate elastomers find limited use in hydrauhc systems and gasket apphcations because of their superior heat resistance compared to the nitrile mbbers (219,220). Ethylene—acrylate copolymers were introduced in 1975. The apphcations include transmission seals, vibration dampers, dust boots, and steering and suspension seals. Further details and performance comparisons with other elastomers are given in reference 221 (see also Elastomers, SYNTHETIC-ACRYLIC ELASTOTffiRS). 

The reaction proceeds until aU. available monomer has reacted or until it is terminated by an acidic species. The gel point in these m situ polymerizations, as represented by the time of fixture, occurs within several seconds on strongly catalytic surfaces such as thermoset mbbers to several minutes on noncatalytic surfaces. 

The cured polymers are hard, clear, and glassy thermoplastic resins with high tensile strengths. The polymers, because of their highly polar stmcture, exhibit excellent adhesion to a wide variety of substrate combinations. They tend to be somewhat britde and have only low to moderate impact and peel strengths. The addition of fillers such as poly (methyl methacrylate) (PMMA) reduces the brittleness somewhat. Newer formulations are now available that contain dissolved elastomeric materials of various types. These mbber-modifted products have been found to offer adhesive bonds of considerably improved toughness (3,4). 

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