Bonding agents

About 80% of the vanadium now produced is used as ferrovanadium or as a steel additive. Vanadium foil is used as a bonding agent in cladding htanium to steel. Vanadium pentoxide is used in ceramics and as a catalyst. 

Bond Type. Most bonded abrasive products are produced with either a vitreous (glass or ceramic) or a resinoid (usually phenoHc resin) bond. Bonding agents such as mbber, shellac, sodium siHcate, magnesium oxychloride, or metal are used for special appHcations. 

Rubber. Both natural and synthetic rubber are used as bonding agents for abrasive wheels. Rubber-bond wheels are ideal for thin cut-off and slicing wheels and centerless grinding feed wheels. They are more flexible and more water-resistant than resinoid wheels. 

Polymer-based rocket propellants are generally referred to as composite propellants, and often identified by the elastomer used, eg, urethane propellants or carboxy- (CTPB) or hydroxy- (HTPB) terrninated polybutadiene propellants. The cross-linked polymers act as a viscoelastic matrix to provide mechanical strength, and as a fuel to react with the oxidizers present. Ammonium perchlorate and ammonium nitrate are the most common oxidizers used nitramines such as HMX or RDX may be added to react with the fuels and increase the impulse produced. Many other substances may be added including metallic fuels, plasticizers, stabilizers, catalysts, ballistic modifiers, and bonding agents. Typical components are Hsted in Table 1. 

Constrained-Layer Treatments. Constrained-layer damping treatments consist of a thin layer (/ m) of viscoelastic material sandwiched between a base material and an outer constraining layer of sheet metal or other stmctural material. Some of these treatments are available with self-adhesives on both sides of the viscoelastic material and act as a bonding agent between the base and constraining layers others have the constraining layer already bonded to the inner layer so they need only be appHed to the base material. 

Foundry Resins. In the foundry industry, phenoHc resins are used as the binder for sand in the manufacture of sheU molds and cores. The two mating halves are joined by clamps or a bonding agent to form a sheU mold into which the molten metal is poured for castings. The sheU is formed by depositing a resin—sand mix on a hot metal pattern plate. After a certain period the pattern is inverted and the excess resin sand is removed. The sand particles are bonded by an oven cure, and the sheU is ejected from the pattern plate. 

Chemically bonded basic bricks are blended much the same as burned brick mixes except that a bonding agent, eg, magnesium sulfate or magnesium chloride, is added to the mix as well as tempering water to form oxysulfates or oxychlorides. 

High Alumina Refractories. The desired alumina content, from 100% to just above 45%, is obtained by adding bauxites, synthetic aluminosihcates, and synthetic aluminas to clay and other bonding agents. These refractories are used in kilns, ladles, and furnaces that operate at temperatures or under conditions for which fireclay refractories are not suited. Phosphate-bonded alumina bricks have exceptionally high strength at low to intermediate temperatures and are employed in aluminum furnaces. High alumina and mullite are used in furnace roofs and petrochemical apphcations. 

Bonding Agents. These materials are generally only used in wire cable coat compounds. They are basically organic complexes of cobalt and cobalt—boron. In wire coat compounds they are used at very low levels of active cobalt to aid in the copper sulfide complex formation that is the primary adherance stmcture. The copper sulfide stmcture builds up at the brass mbber interface through copper in the brass and sulfur from the compound. The dendrites of copper sulfide formed entrap the polymer chains before the compound is vulcanized thus hoi ding the mbber firmly to the wire. 

Rubber. The mbber industry consumes finely ground metallic selenium and Selenac (selenium diethyl dithiocarbamate, R. T. Vanderbilt). Both are used with natural mbber and styrene—butadiene mbber (SBR) to increase the rate of vulcanization and improve the aging and mechanical properties of sulfudess and low sulfur stocks. Selenac is also used as an accelerator in butyl mbber and as an activator for other types of accelerators, eg, thiazoles (see Rubber chemicals). Selenium compounds are useflil as antioxidants (qv), uv stabilizers, (qv), bonding agents, carbon black activators, and polymerization additives. Selenac improves the adhesion of polyester fibers to mbber. 

Cellulose. Cellulose or starch xanthate cross-linked by titanates can adsorb uranium from seawater (536). CarboxymethylceUulose cross-linked with TYZOR ISTT is the bonding agent for clay, talc, wax, and pigments to make colored pencil leads of unusual strength (537). 

The hydrohalide is liable to dehydrochlorination, particularly when moist acid is used in its preparation, so that hydrochloric acid acceptors such as lead carbonate are useful stabilisers. Dibutyl phthalate and tritolyl phosphate are effective plasticisers. Rubber hydrochloride is used as a packaging film (Pliofilm) and as a rubber-to-metal bonding agent (e.g. Typly). 

Hoetjer, J.J., European patent EP 0062389, Bl. Manufacture of chipboard and a novel suitable bonding agent. Assigned to Methanol Chemie Nederland, 1982. 

Composite materials typically have a low matrix Young s modulus in comparison to the fiber modulus and even in comparison to the overall laminae moduli. Because the matrix material is the bonding agent between laminae, the shearing effect on the entire laminate is built up by summation of the contributions of each interlaminar zone of matrix material. This summation effect cannot be ignored because laminates can have 100 or more layersi The point is that the composite material shear moduli and G are much lower relative to the direct modulus than for isotropic materials. Thus, the effect of transverse shearing stresses. 

The bonding agent technique is usually not applicable to the metal particles in the composite. However, the surface of the metal is almost invariably covered by a thin (40-80 A) oxide layer [50]. The free energy of oxide surfaces is normally quite large (10 mJ/m ) to allow quick wetting by most organic polymers (40-60 mJ/m ). Additionally, the metal surface may provide two... 

Figure 14 Instron tensile data for a urethane composite using several bonding agents. Source Ref. 47.

Bonding Agents and Processing Aids for HTPB Propellants , Rept No S-205, Contract DAAH01-68-C-0632, Rohm Haas Co, Huntsville (1969) 6) A.M. Bedard, Evaluation of... 

Michigian, Selection and Evaluation of Bonding Agents for HTPB Propellants , Rept No ASPC-1085-26F, RKCR-75-18, Aerojet Solid Proplsn Co, Sacramento (1974) 15) G,... 

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