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Ethanol commercial importance

Methanol and ethanol are among the two commercially important alcohols. [Pg.67]

Lavender and lavandin extracts are also commercially important and are produced in southern France by solvent extraction of flowering lavander and lavandin herbs. Production of lavandin concrete is higher than that of lavender. Extraction of the paste-like concretes with ethanol, followed by evaporation, yields absolutes. These extracts differ from the essential oils in being more soluble and in... [Pg.202]

Nonionic surfactants are also used in substantial amounts in laundry detergents and in automatic dishwashing detergents, both applications reflecting in particular their generally lower sudsing characteristics than the anionics. Commercially important examples uf the nonionics include the alkyl ethoxylates, the ethoxylated alkyl phenols, the fatly acid ethanol amides, and complex polymers of ethylene oxide, propylene oxide, and alcohols. [Pg.479]

The mechanisms of these reactions have much in common and have been studied extensively from this point of view. They also have very considerable synthetic utility. The addition of water to alkenes (hydration) is particularly important for the preparation of a number of commercially important alcohols. Thus ethanol and 2-propanol (isopropyl alcohol) are made on a very large scale by the hydration of the corresponding alkenes (ethene and propene) using sulfuric or phosphoric acids as catalysts. The nature of this type of reaction will be described later. [Pg.361]

There are two main process categories for the direct hydration of ethylene to ethanol. Vapor-phase processes contact a solid or liquid catalyst with gaseous reactants. Mixed-phase processes contact a solid or liquid catalyst with liquid and gaseous reactants. Generally, ethanol is produced by a vapor-phase process mixed-phase processes are used for the analogous hydration of propylene to 2-propanol. Important exceptions to these two generalizations exist, but the discussion that follows emphasizes technology associated with the commercially important vapor-phase direct hydration of ethylene. [Pg.404]

Glycols have two or more hydroxyl groups on adjacent carbons. Ethylene glycol, glycerol, and sorbitol are examples of glycols that are commercially important. Three important industrial alcohols are methanol, ethanol, and 2-propanol. [Pg.123]

The catalytic dehydration of ethanol to ethylene in SC water may be commercially important (16). Although high quality commercial alumina catalysts exist for the vapor phase dehydration of ethanol, the commercial processes require the ethanol feedstock to be relatively free of water. Hence the ethanol must be distilled from the ethanol-water mixture which is the product of fermentation processes. By avoiding this distillation step, and securing phase separation of the ethylene product from the ethanol-water reactant, SC dehydration of ethanol could enjoy advantages over existing commercial technologies. [Pg.85]

Commercially important polyesters, e.g. poly[l-(2-ethylenyl)-2,2,6,6-tetramethyl-4-piperidinylbutane dioate] (146) [190] were synthesized from l-(2-hydroxyethyl)-4-hydroxy-2,2,6,6-tetramethylpiperidines and suitable dicarboxylic acids. Another polymeric HALS was prepared by transesterification of oligoesters of tetramethyl-butane-l,2,3,4-tetracarboxylate with 22,6,6-tetramethyl-4-hydroxypiperidine and 1,10-decanediol [191]. Compound 147 is a similar polyester type HALS. An ester-amide chain is created during esterification of 2-(2,2,6,6-tetramethyl-4-piperidinylamino)ethanol and dimethyl adipate [192]. [Pg.108]

Alcohols contain one or more hydroxyl (—OH) functional groups bonded to carbon atoms and are a major class of organic compounds. The importance of methanol, ethanol, and 2-methyl-2-propanol as fuels and fuel additives was described in Sections 12.2 and 12.5. Additional uses of these and other commercially important alcohols are listed in Table 14.3. Alcohols are classified according to the number of carbon atoms bonded directly to the —C—OH carbon as primary (one other G atom), secondary (two other C atoms), or tertiary (three other C atoms). The reactivities of these classes of alcohols are different. [Pg.320]

Camphor a bicyclic monoterpene ketone found widely in plants. Both optical isomers occur naturally (-t)-C. (Japan C), m.p. 180°C, b.p. 204°C, [a] -h43.8° (c = 7.5 in abs. ethanol), and (-)-C. (Matricaria C), m.p. 178.6°C, b.p. 204°C, [o]g -44.2° (ethanol). C. is obtained commercially from camphor trees (Cin-namomum camphora) native to coastal areas of East Asia. Partial synthesis from pinene is also commercially important, the product being a racemic mixture... [Pg.86]

Acetaldehyde, first used extensively during World War I as a starting material for making acetone [67-64-1] from acetic acid [64-19-7] is currendy an important intermediate in the production of acetic acid, acetic anhydride [108-24-7] ethyl acetate [141-78-6] peracetic acid [79-21 -0] pentaerythritol [115-77-5] chloral [302-17-0], glyoxal [107-22-2], aLkylamines, and pyridines. Commercial processes for acetaldehyde production include the oxidation or dehydrogenation of ethanol, the addition of water to acetylene, the partial oxidation of hydrocarbons, and the direct oxidation of ethylene [74-85-1]. In 1989, it was estimated that 28 companies having more than 98% of the wodd s 2.5 megaton per year plant capacity used the Wacker-Hoechst processes for the direct oxidation of ethylene. [Pg.48]

Supercritical Extraction. The use of a supercritical fluid such as carbon dioxide as extractant is growing in industrial importance, particularly in the food-related industries. The advantages of supercritical fluids (qv) as extractants include favorable solubiHty and transport properties, and the abiHty to complete an extraction rapidly at moderate temperature. Whereas most of the supercritical extraction processes are soHd—Hquid extractions, some Hquid—Hquid extractions are of commercial interest also. For example, the removal of ethanol from dilute aqueous solutions using Hquid carbon dioxide... [Pg.70]

Styrene is a colorless Hquid with an aromatic odor. Important physical properties of styrene are shown in Table 1 (1). Styrene is infinitely soluble in acetone, carbon tetrachloride, benzene, ether, / -heptane, and ethanol. Nearly all of the commercial styrene is consumed in polymerization and copolymerization processes. Common methods in plastics technology such as mass, suspension, solution, and emulsion polymerization can be used to manufacture polystyrene and styrene copolymers with different physical characteristics, but processes relating to the first two methods account for most of the styrene polymers currendy (ca 1996) being manufactured (2—8). Polymerization generally takes place by free-radical reactions initiated thermally or catalyticaHy. Polymerization occurs slowly even at ambient temperatures. It can be retarded by inhibitors. [Pg.476]

Disperse reds are second only to blues as the most important disperse color manufactured. AU. commercial disperse reds are monoazo dyes. In 1988, Disperse Red 73 (98, R = CN) had production of 270 tons valued at nearly 1.6 million. Disperse Violet 24 (99) is produced from diazotized 2-hromo-4,6-dinitroani1ine by coupling with 2-(A/-butyl-y -toluidine)ethanol. [Pg.449]

The pattern of commercial production of 1,3-butadiene parallels the overall development of the petrochemical industry. Since its discovery via pyrolysis of various organic materials, butadiene has been manufactured from acetylene as weU as ethanol, both via butanediols (1,3- and 1,4-) as intermediates (see Acetylene-DERIVED chemicals). On a global basis, the importance of these processes has decreased substantially because of the increasing production of butadiene from petroleum sources. China and India stiU convert ethanol to butadiene using the two-step process while Poland and the former USSR use a one-step process (229,230). In the past butadiene also was produced by the dehydrogenation of / -butane and oxydehydrogenation of / -butenes. However, butadiene is now primarily produced as a by-product in the steam cracking of hydrocarbon streams to produce ethylene. Except under market dislocation situations, butadiene is almost exclusively manufactured by this process in the United States, Western Europe, and Japan. [Pg.347]

The following azeotropes are important commercially for drying ethanol ... [Pg.13]


See other pages where Ethanol commercial importance is mentioned: [Pg.21]    [Pg.400]    [Pg.445]    [Pg.299]    [Pg.330]    [Pg.45]    [Pg.404]    [Pg.80]    [Pg.328]    [Pg.400]    [Pg.270]    [Pg.501]    [Pg.545]    [Pg.400]    [Pg.13]    [Pg.14]    [Pg.404]    [Pg.347]    [Pg.445]    [Pg.214]    [Pg.621]    [Pg.576]    [Pg.1032]    [Pg.569]    [Pg.245]    [Pg.1097]    [Pg.945]    [Pg.42]    [Pg.27]    [Pg.39]    [Pg.198]    [Pg.394]    [Pg.125]    [Pg.458]   
See also in sourсe #XX -- [ Pg.569 ]




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Commercial importance

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