Detail filter

Add 25 g. of finely-powdered, dry acetanilide to 25 ml. of glacial acetic acid contained in a 500 ml. beaker introduce into the well-stirred mixture 92 g. (50 ml.) of concentrated sulphuric acid. The mixture becomes warm and a clear solution results. Surround the beaker with a freezing mixture of ice and salt, and stir the solution mechanically. Support a separatory funnel, containing a cold mixture of 15 -5 g. (11 ml.) of concentrated nitric acid and 12 -5 g. (7 ml.) of concentrated sulphuric acid, over the beaker. When the temperature of the solution falls to 0-2°, run in the acid mixture gradually while the temperature is maintained below 10°. After all the mixed acid has been added, remove the beaker from the freezing mixture, and allow it to stand at room temperature for 1 hour. Pour the reaction mixture on to 250 g. of crushed ice (or into 500 ml. of cold water), whereby the crude nitroacetanilide is at once precipitated. Allow to stand for 15 minutes, filter with suction on a Buchner funnel, wash it thoroughly with cold water until free from acids (test the wash water), and drain well. Recrystallise the pale yellow product from alcohol or methylated spirit (see Section IV,12 for experimental details), filter at the pump, wash with a httle cold alcohol, and dry in the air upon filter paper. [The yellow o-nitroacetanihde remains in the filtrate.] The yield of p-nitroacetanihde, a colourless crystalline sohd of m.p. 214°, is 20 g. 

Key service buildings - basic structures and m or contents, layout elevations and floor plans, ventilation details (filters), design limits, etc. 

Rows 1-8 are the approximation filter coefficients and rows 9-16 represent the detail filter coefficients. At each next row the two coefficients are moved two positions (shift b equal to 2). This procedure is schematically shown in Fig. 40.43 for a signal consisting of 8 data points. Once W has been defined, the a wavelet transform coefficients are found by solving eq. (40.16), which gives ... 

In the simplest (and most localized) member of the Daubechies family, the four coefficients [Cq, Cj, C2, C3] represent the low-pass filter H that is applied to the odd rows of the transformation matrix. The even rows perform a different convolution by the coefficients [C3, -C2, Cj, -Cq] that represent the high-pass filter G. H acts as a coarse filter (or approximation filter) emphasizing the slowly changing (low-frequency) features, and G is the detail filter that extracts the rapidly changing (high-frequency) part of the data vector. The combination of the two filters H and G is referred to as a filter bank. 

Detail-Filtered One-Level Decomposition The detail-filtered (high-pass) coefficients of the first resolution level represent a new type of descriptor that reveals special aspects of data, like trends, breakdown points, and discontinuities in higher derivatives. It is useful as alternative molecular representation for neural networks in classification and prediction tasks (Figure 5.20). 

Combining coarse- and detail-filtered complete decomposition results in a combination of the coarse coefficients of the last resolution level and all the detail coefficients D - ... 

FIGURE 5.20 Detail-filtered D20 transformed RDF at resolution level j= 1. 

FIGURE 5.21 Combination coarse- and detail-filtered transformed RDF descriptor performed at the highest resolution level (J = 6). The transform is an alternative representation of an RDF in the wavelet domain. This signal consists of the coefficients G ) + D -1- 0(S)... 

The coarse- or detail-filtered wavelet transform or a combination of the coefficients for an RDF descriptor at a certain resolution level is done right before any postprocessing, like normalization. 

Detail-filtered WLT at resolution level j = 1 (one-level decomposition)... 

Detail-filtered (high-pass) wavelet coefficients D(l) of die first resolution level. 

Coarse- and detail-filtered WLT at the highest Combination of die coarse wavelet coefficients... 

At this time the NICMOS schedule calls for launch and insertion into HST in May of 1997. Decisions on which of the current axial HST instruments NICMOS will replace will be based on the status and utilization of the current instruments approximately 1 to 2 years before launch. NICMOS is currently under construction at Ball Aerospace, with several of the key dewar components already completed. The design and developmoit of NICMOS is complete although the detailed filter compliment and grism parameters are stiU under evaluation. All NICMOS flight detector arrays are due for delivery by the end of 1994. There will be a total of three primary and six spare arrays. All nine arrays will meet flight specifications, but the three primary arrays will be chosen based on the qualification data and further... 

Another approach to mass analysis is based on stable ion trajectories in quadnipole fields. The two most prominent members of this family of mass spectrometers are the quadnipole mass filter and the quadnipole ion trap. Quadnipole mass filters are one of the most connnon mass spectrometers, being extensively used as detectors in analytical instnunents, especially gas clnomatographs. The quadnipole ion trap (which also goes by the name quadnipole ion store, QUISTOR , Paul trap, or just ion trap) is fairly new to the physical chemistry laboratory. Its early development was due to its use as an inexpensive alternative to tandem magnetic sector and quadnipole filter instnunents for analytical analysis. It has, however, staned to be used more in die chemical physics and physical chemistry domains, and so it will be described in some detail in this section. 

At ach scale a signal is filtered into a course and a detailed comp. 

The explorative analysis of data sets by visual data mining applications takes place in a three-step process During the first step (overview), the user can obtain an overview of the data and maybe can identify some basic relationships between specific data points. In the second step (filtering), dynamic and interactive navigation, selection, and query tools will be used to reorganize and filter the data set. Each interaction by the user will lead to an immediate update of the data scene and will reveal the hidden patterns and relationships. Finally, the patterns or data points can be analyzed in detail with specific detail tools. 

The ethereal extracts are then united, dried with a suitable drying agent and filtered. The filtrate is then cautiously distilled, the ether being first distilled and finally the organic compound if volatile if the compound is solid, the crude residue is purified by recrystallisation. Very great care must be taken on all occasions when ether is distilled because of the risk of fire or of an explosion full experimental details for this operation are given, both on p. 8o (Preparation of Ether) and on p. 164 (Pre-... 

If crystallisation commences as soon as the solvent cools or if large quantities of hot solution are to be filtered, the funnel (and fluted filter paper) should be warmed externally during the filtration (hot water funnel). Three types of hot water funnel are illustrated in Fig. 11,1, 6 no flames should be present whilst inflammable solvents are being filtered through the funnel of Fig. 11, 1, 6, a. Alternatively, the funnel may be surrounded by an electric heating mantle (see Section 11,57) the heat input may be controlled by a variable transformer. When dealing with considerable volumes of aqueous or other solutions which do not deposit crystals rapidly on cooling, a Buchner funnel may be used for filtration (see detailed account in Section 11,1 and Fig. 11 1, 7, c). The filter paper... 

Benzene. The analytical reagent grade benzene is satisfactory for most purposes if required dry, it is first treated with anhydrous calcium chloride, filtered, and then placed over sodium wire (for experimental details, see under Diethyl ether, 1). 

Drop 1 g. of sodium into 10 ml. of ethyl alcohol in a small flask provided with a small water condenser heat the mixture until all the sodium has dissolved. Cool, and add 1 g. of the ester and 0-5 ml. of water. Frequently the sodium salt of the acid will be deposited either at once or after boiling for a few minutes. If this occurs, filter oflF the solid at once, wash it with a little absolute ethyl alcohol (or absolute methylated spirit), and convert it into the p-bromophenacyl ester, p-nitro-benzyl ester or S-benzyl-tso-thiuronium salt (for experimental details, see Section 111,85). If no solid separates, continue the boiling for 30-60 minutes, boil oflF the alcohol, allow to cool, render the product just neutral to phenolphthalein with dilute sulphuric or hydrochloric acid, convert the sodium salt present in solution into a crystalline derivative (Section 111,85), and determine its melting point. 

Place 18 g. (12 ml.) of fuming nitric acid, sp. gr. 1 5, and 30 g. (16-5 ml.) of concentrated sulphuric acid and a few fragments of broken glass in a 250 or 500 ml. round-bottomed flask. Add gradually, in small portions, 14 g. of p-nitrotoluene do not allow the temperature to rise above 50 and cool the flask, if necessary, by immersion in cold water. Place a small funnel in the mouth of the flask and heat on a water bath at 90-95° for 30 minutes. Allow to cool almost to the laboratory temperature and pour the reaction mixture slowly into about 500 ml. of ice water containing a few small pieces of ice. Filter the crude dinitrotoluene through a Buchner funnel at the pump, wash it thoroughly with cold water, and drain as completely as possible. RecrystalUse from the minimum volume of hot methyl alcohol (flask, reflux condenser, and water bath experimental details as in Section IV,12). The yield of pure 2 4-dinitrotoluene, m.p. 71°, is 12 -5 g. 

To isolate pure p-dibromobenzene, filter the second portion of the steam distillate through a small Buchner funnel with suction press the crystals as dry as possible. Combine these crystals with the residue (R) and recrystaliise from hot ethyl alcohol (for experimental details, see Section IV,12) with the addition of 1-2 g. of decolourising charcoal use about 4 ml. of alcohol (methylated spirit) for each gram of material. Filter the hot solution through a fluted filter paper, cool in ice, and filter the crystals at the pump. The yield of p-dibromobenzene, m.p. 89°, is about 12 g. 

The experimental details for mono-M-propylanillne are as follows. Reflux a mixture of 230 g. of aniline and 123 g. of n-propyl bromide for 8-10 hours. Allow to cool, render the mixture alkafine, and add a solution of 150 g. of zinc chloride in 150 g. of water. Cool the mixture and stir after 12 hours, filter at the pump and drain well. Extract the thick paste several times with boiling light petroleum, b.p. 60-80° (it is best to use a Soxhlet apparatus), wash the combined extracts successively with water and dilute ammonia solution, and then dry over anhydrous potassium carbonate or anhydrous magnesium sulphate. Remove the solvent on a water bath, and distil the residue from a Claisen flask with fractionating side arm (well lagged). Collect the n-propyl-aniline at 218-220° the yield is 80 g. Treat the pasty solid zincichloride with an excess of. sodium hydroxide solution and steam distil 130 g. of pure aniline are recovered. 

Diphenyinitrosamine. Dissolve 8-5 g. of pure diphenylamine in 70 ml. of warm alcohol also 4 g. of sodium nitrite in 6 ml. of water. Cool each solution in ice until the temperature falls to 5°. Add 6 ml. of concentrated hydrochloric acid slowly and with stirring to the diphenylamine solution, and immediately (otherwise diphenylamine hydrochloride may crystallise out) pour the sodium nitrite solution rapidly into the well-stirred mixture. The temperature soon rises to 20-25° and the diphenyinitrosamine crystallises out. Cool the mixture in ice water for 15-20 minutes, filter with suction on a Buchner funnel, wash with water to remove sodium chloride, and press well with a wide glass stopper. Re-crystaUise from methylated spirit (for details, see Section IV,12). The yield of pure diphenyinitrosamine (pale yellow crystals), m.p. 68°, is 8- 5 g. 

In a 1 5 or 2-Utre rovmd-bottomed flask, prepare cuprous chloride from 105 g. of crystallised copper sulphate as detailed in Section 11,50,1. Either wash the precipitate once by decantation or filter it at the pump and wash it with water containing a httle sulphurous acid dissolve it in 170 ml. of concentrated hydrochloric acid. Stopper the flask loosely (to prevent oxidation) and cool it in an ice - salt mixture whilst the diazo-tisation is being carried out. 

Place a solution of 10 -4 g. of benzalacetophenone, m.p. 57° (Section IV,130) in 75 ml. of pure ethyl acetate (Section 11,47,15) in the reaction bottle of the catalytic hydrogenation apparatus and add 0 2 g. of Adams platinum oxide catalyst (for full experimental details, see Section 111,150). Displace the air with hydrogen, and shake the mixture with hydrogen until 0 05 mol is absorbed (10-25 minutes). Filter oflF the platinum, and remove the ethyl acetate by distillation. RecrystaUise the residual benzylacetophenone from about 12 ml. of alcohol. The yield of pure product, m.p. 73°, is 9 g. 

Prepare a solution containing about 100 g, of potassium hypochlorite from commercial calcium hypochlorite ( H.T.H. ) as detailed under -Dimethylacrylic Acid, Section 111,142, Note 1, and place it in a 1500 ml. three-necked flask provided with a thermometer, a mechanical stirrer and a reflux condenser. Warm the solution to 55° and add through the condenser 85 g, of p-acetonaphthalene (methyl p-naphthyl ketone) (1). Stir the mixture vigorously and, after the exothermic reaction commences, maintain the temperature at 60-70° by frequent cooling in an ice bath until the temperature no longer tends to rise (ca. 30 minutes). Stir the mixture for a further 30 minutes, and destroy the excess of hypochlorite completely by adding a solution of 25 g. of sodium bisulphite in 100 ml. of water make sure that no hypochlorite remains by testing the solution with acidified potassium iodide solution. Cool the solution, transfer the reaction mixture to a 2-litre beaker and cautiously acidify with 100 ml. of concentrated hydrochloric acid. Filter the crude acid at the pump. 

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