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Additives, whether hydrophobic solutes, other surfactants or polymers, tend to nucleate micelles at concentrations lower than in the absence of additive. Due to this nucleating effect of polymers on micellization there is often a measurable erne, usually called a critical aggregation concentration or cac, below the regular erne observed in the absence of added polymer. This cac is usually independent of polymer concentration. The size of these aggregates is usually smaller than that of free micelles, and this size tends to be small even in the presence of added salt (conditions where free micelles tend to grow in size). [Pg.2603]

Starch solution (other than soluble) make a thin paste of the starch with cold water, then stir in 200 times its weight of boiling water and boil for a few minutes. A few drops of chloroform added to the solution acts as a preservative. [Pg.1197]

Year Solid Fertilizer Solution Other Total... [Pg.309]

Sulfides. The main sulfide of indium is I1I2S2 [12030-24-9], which can be prepared by heating the metal with sulfur or by precipitation from weak acid solutions of indium salts by H2S. Precipitated I1I2S2 varies in color from yellow to red-brown, and in crystal size depending on formation conditions. It dissolves in acids and sodium sulfide solution. Other reported sulfides of indium ate InS [12030-14-7], a red-brown soHd In2S [12196-52-0], and In S [12142-00-5]. [Pg.81]

When strong acid cation exchangers are used in the Na" form and strong base anion exchangers are used in the CL form, they are regenerated with a 10% sodium chloride [7647-14-5], NaCl, solution. Other concentrations may be used, perhaps with some adjustment in flow rate. [Pg.384]

Zirconium hydroxy oxychloride [18428-88-17, nominally ZrO(OH)Cl, is produced by dissolving hydrous zirconia in hydrochloric acid in an equal molar proportion, and is available only in solution. Other oxychlorides with Cl Zr ratios <2 are discussed in Reference 199. [Pg.437]

Arsenic may be detected quaUtatively as a yellow sulfide, AS2S2, by precipitation from a strongly acidic HQ solution. Other members of this group... [Pg.326]

The hydrolysis equilibria for H2Cr04 given in Table 3 are only valid in HNO or HCIO solutions. Other acids yield complexes such as those shown for chloride and bisulfate ions. The exact composition of chromate(VI) anion(s) present in aqueous solution is a function of both pH and hexavalent chromium concentration (68). However, at pH values above 8, virtually all the Cr(VI) is present as the CrO anion. When the pH is between 2 and 6, an equilibrium mixture of HCrO and Ci2 is present when the pH is below 1, the principal species is H2Cr04 (68,69). At very high Cr(VI) concentrations... [Pg.136]

Powerful solvents such as dimethyl sulfoxide (common laser dye solvent) and solubilizing substituents (K" and R " = sulfoalkyl in stmcture 32) may enhance the transport of dyes in solution through skin and other membranes. Reference 88 (on laser dye solutions and toxicity) is recommended to researchers working with dye solutions. Other dyes, such as Indocyanine Green, attain useful properties (blood tracer dye) as a result of having solubilizing substituents in their stmcture. [Pg.401]

This reaction occurs with overall cathodic currents, i.e., with cathodic polarization. It can be practically ignored in the case of free corrosion of steel in a neutral solution. Other oxidizing media are of interest only in special cases. [Pg.36]

One way to remove the lower half of the liner, when hoisting facilities are not available or operational, Is to float the drum by filling the tank with a sufficiently concentrated solution. Other components that should be periodically checked are ... [Pg.351]

The dipping solution can also be used as a spray solution other concentrations are also reported in the literature [1 — 3],... [Pg.396]

The reactive species for the transfer of the nitrosyl cation NO+ is not the nitrous acid 2 but rather N2O3 4 which is formed in weakly acidic solution. Other possible nitrosating agents are NOCl or H2N02 ", or even free NO+ in strong acidic solution. The initially formed N2O3 4 reacts with the free amine 1 ... [Pg.87]

Prepared saltwater completion fluids are made of fresh surface water, with sufficient salts added to produce the proper salt concentration. Usually, the addition of 5 to 10% NaCl, 2% CaClj, or 2% KCl is considered satisfactory for clay inhibition in most formations. Sodium chloride solutions have been extensively used for many years as completion fluids these brines have densities up to 10 Ib/gal. Calcium chloride solutions may have densities up to 11.7 lb/ gal. The limitations of CaClj solutions are (1) flocculation of certain clays, causing permeability reduction, and (2) high pH (10 to 10.5) that may accelerate formation clays dispersion. In such cases, CaC12-based completion fluids should be replaced with potassium chloride solutions. Other clear brines can be formulated using various salts over wide range of densities, as shown in Figure 4-123 [28]. [Pg.708]

Oxygen Dissolved oxygen is probably the most significant constituent affecting corrosion, its importance lying in the fact that it is the most important cathodic depolariser in neutral solutions. Other depolarisers also occur, but as oxygen is an almost universal constituent of natural waters its importance will readily be understood. [Pg.349]

Other electroplating solutions Other solutions, which are more rarely used for plating copper, include the fluoborate bath, the amine bath, the sulphamate bath and the alkane sulphonate bath. [Pg.519]

The absolute value of a proportional error depends upon the amount of the constituent. Thus a proportional error may arise from an impurity in a standard substance, which leads to an incorrect value for the molarity of a standard solution. Other proportional errors may not vary linearly with the amount of the constituent, but will at least exhibit an increase with the amount of constituent present. One example is the ignition of aluminium oxide at 1200°C the aluminium oxide is anhydrous and virtually non-hygroscopic ignition of various weights at an appreciably lower temperature will show a proportional type of error. [Pg.128]

L-alanine can be prepared from aspartic acid (Figure A8.13). L-Aspartate-(5-decarboxylase produced by Xanthomonas oryzae No 531 has been used to prepared L-alanine in 95% yield from 15% L-aspartic add solution. Other strains, ie Pseudomonas dacunhae or Achromobacter pestifer, give comparable yields of L-alanine. The process has been commercialised by Tanabe. [Pg.286]

The complexes are 1 1 electrolytes in solution. Other such complexes can be made by a similar route or by halide (or carboxylate) exchange. The first monomeric system Ru2C1(02C.C4H4N)4 (thf), where the ruthenium at one end of the lantern is bound to a thf and the other to a chloride, has recently been made [97], [Ru2Cl(02CBut)4(H20)] and [R Cl CPr thf)] are also monomeric [98],... [Pg.35]

Another factor that can influence the environmental distribution of a chemical is the presence of charged groups. Some pollutants, such as the sodium or potassium salts of phenoxyalkanoic herbicides, dinitrophenols, and tetra- or penta-chlo-rophenol, exist as anions in solution. Others, such as the bipyridyl herbicides diquat and paraquat, are present as cations. In either case, the ions may become bound to organic macromolecules or minerals of soils or sediments that bear the opposite... [Pg.69]

In general, the Lewis-Matheson method has not been found to be an efficient procedure for computer solutions, other than for relatively straightforward problems. It is not suitable for problems involving multiple feeds, and side-streams, or where more than one column is needed. [Pg.544]

However, in pentane-dichloromethane solution other products are produced,<30,3l)... [Pg.82]

The acidity of a solution is determined by the hydronium ion concentration of the solution. The greater [H,0+], the more acidic the solution the lower [H,0+], the more basic the solution. Other substances, for example, OH, affect the acidity of a solution by affecting the concentration of H, 0+. The presence of OH in water in greater concentration than H30+ makes the solution basic. If the relative concentrations are reversed, the solution is acidic. [Pg.303]

In principle, any physical property that varies during the course of the reaction can be used to follow the course of the reaction. In practice one chooses methods that use physical properties that are simple exact functions of the system composition. The most useful relationship is that the property is an additive function of the contributions of the different species and that each of these contributions is a linear function of the concentration of the species involved. This physical situation implies that there will be a linear dependence of the property on the extent of reaction. As examples of physical properties that obey this relationship, one may cite electrical conductivity of dilute solutions, optical density, the total pressure of gaseous systems under nearly ideal conditions, and rotation of polarized light. In sufficiently dilute solutions, other physical properties behave in this manner to a fairly good degree of approximation. More complex relationships than the linear one can be utilized but, in such cases, it is all the more imperative that the experimentalist prepare care-... [Pg.39]


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See also in sourсe #XX -- [ Pg.397 , Pg.398 , Pg.399 ]




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