Cast iron, 228 table

Bruhtoh s calciner is shown in. Fig. 602, It is a circular cast-iron table fixed on a stout central shaft,... 

As it is also known from other fields of working metals, the different forms of the chips from machining cast iron and steel cause a much more intense interaction with the cutting plate for the latter material. Therefore, the demands concerning the chemical and oxidation stability are more stringent on working hardened steel than on machining hard cast iron (Table 2). 

The materials are austenitic stainless steel (Hereafter,it is said SUS304), ductile cast iron (Hereafter, it is said FCD500), and pure Ni. The composition of the materials is shown in Table. 1. Moreover, the sound characteristic of the materials and air as the defect are shown in Table.2. 

Silicon [7440-21-3] Si, from the Latin silex, silicis for flint, is the fourteenth element of the Periodic Table, has atomic wt 28.083, and a room temperature density of 2.3 gm /cm. SiUcon is britde, has a gray, metallic luster, and melts at 1412°C. In 1787 Lavoisier suggested that siUca (qv), of which flint is one form, was the oxide of an unknown element. Gay-Lussac and Thenard apparently produced elemental siUcon in 1811 by reducing siUcon tetrafluoride with potassium but did not recognize it as an element. In 1817 BerzeHus reported evidence of siUcon occurring as a precipitate in cast iron. Elemental siUcon does not occur in nature. As a constituent of various minerals, eg, siUca and siUcates such as the feldspars and kaolins, however, siUcon comprises about 28% of the earth s cmst. There are three stable isotopes that occur naturally and several that can be prepared artificially and are radioactive (Table 1) (1). 

The reaction vessel (nitrator) is constructed of cast iron, mild carbon steel, stainless steel, or glass-lined steel depending on the reaction environment. It is designed to maintain the required operating temperature with heat-removal capabiUty to cope with this strongly exothermic and potentially ha2ardous reaction. Secondary problems are the containment of nitric oxide fumes and disposal or reuse of the dilute spent acid. Examples of important intermediates resulting from nitration are summarized in Table 3. 

Y = coefficient naving value in Table 10-50 for ductile ferrous materials, 0.4 for ductile nonferrous materials, and zero for brittle materials such as cast iron t,n = minimum required thickness, in, to which manufacturing tolerance must be added when specifying pipe thickness on purchase orders. [Most ASTM specifications to which mill pipe is normally obtained permit minimum wall to be 12V percent less than nominal. ASTM A155 for fusion-welded pipe permits minimum wall 0.25 mm (0.01 in) less than nominal plate thickness.] Pipe with t equal to or greater than D/6 or P/SE greater than 0.385 reqmres special consideration. 

Table 2.1 ranks materials by their cost per unit weight UK per tonne (i.e. 1000 kg) in the second column, US per tonne in the third. The most expensive materials - diamond, platinum, gold - are at the top. The cheapest - cast iron, wood, cement - are at the bottom. Such data are obviously important in choosing a material. How do we keep informed about materials prices change and what controls them ... 

Carbon is the cheapest and most effective alloying element for hardening iron. We have already seen in Chapter 1 (Table 1.1) that carbon is added to iron in quantities ranging from 0.04 to 4 wt% to make low, medium and high carbon steels, and cast iron. The mechanical properties are strongly dependent on both the carbon content and on the type of heat treatment. Steels and cast iron can therefore be used in a very wide range of applications (see Table 1.1). 

Galvanic anodes of cast iron were already in use in 1824 for protecting the copper cladding on wooden ships (see Section 1.3). Even today iron anodes are still used for objects with a relatively positive protection potential, especially if only a small reduction in potential is desired, e.g., by the presence of limiting values U" (see Section 2.4). In such cases, anodes of pure iron (Armco iron) are mostly used. The most important data are shown in Table 6-1. 

The cast irons do not possess ductility. They cannot be pressed or forged even while heated however, their machining properties are considered good. Typical mechanical properties of various types of cast iron are given in Table 3.1. 

Table 3.1. Typical Mechanical Properties of Various Types of Cast Iron [1]...

White cast iron is very hard (from 400 to 600 DPN) and brittle. All white cast irons are very difficult to machine and usually are finished by grinding. Table 3.3 gives properties of the four principal types of white cast irons. 

This type of cast iron is made by high-temperature heat treatment of white iron castings. The mechanical properties of malleable cast irons are given in Table 3.1 usually they are applied to the fabrication of conveyor chain links, pipe fittings and gears. 

The main advantages of austenitic cast irons are corrosion and heat resistance. For corrosion resistance, the flake and nodular are similar, but the mechanical properties of nodular cast irons are superior. Some of the commercially available austenitic cast irons are given in the Tables 3.4 and 3.5. 

Table 3.6 gives commonly used maximum working stresses for various grades of cast irons up to 600°C. 

Table 3.7. Rods and Electrodes for Fusion-Welding Cast Iron...

Addition of nickel improves the resistance of iron and steel to corrosion by alkaline solutions. The beneficial effect is most pronounced in hot, strong caustic solutions as illustrated by the results on nickel cast irons in Table 3.37. 

Table 3.37 Resistance of nickel cast irons to corrosion by hot caustic soda ...

Table 3.41 Composition ranges of cast iron alloys...

The figures quoted in Table 3.41, while not authoritative in indicating upper and lower limits, give some idea of the range of analysis to be expected for each type of iron. Because of this variation in composition, cast irons are usually specified in terms of their mechanical properties rather than on an analytical basis. 

Because cast iron components are normally very heavy in section, the relatively low rates of attack associated with atmospheric corrosion do not constitute a problem and little work has been carried out on the phenomenon. A summary of some of the data available is given in Table 3.42. The most extensive work in this field was initiated by the A.S.T.M. in 1958 and some of the results produced by these studies are quoted in Table 3.43. It will be noted that there is a marked fall in corrosion rate with time for all the metals tested. 

The austenitic irons are superior to ordinary cast iron in their resistance to corrosion by a wide range of concentrations of hydrochloric acid at room temperature (Table 3.50). However, for practical uses where such factors as velocity, aeration and elevated temperatures have to be considered, the austenitic irons are mostly used in environments where the hydrochloric acid concentration is less than 0- 5%. Such environments occur in process streams encountered in the production and handling of chlorinated hydrocarbons, organic chlorides and chlorinated rubbers. 

The austenitic irons are also useful in some circumstances for handling organic acids such as dilute acetic, formic and oxalic acids, fatty acids and tar acids. They are more resistant to organic acids than unalloyed cast irons, e.g. in acetic acid the austenitic irons show corrosion rates 20-40 times lower than the ferritic iron (Table 3.51). 

Table 3.51 Corrosion of Type I Ni-Resist and ferritic cast iron in acetic acid in laboratory tests at 15°C...

Table 3.52 Corrosion of Ni-Resist irons, cast iron and carbon steel in caustic soda solutions...

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