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Synthesis carbonyl

The stoichiometric and the catalytic reactions occur simultaneously, but the catalytic reaction predominates. The process is started with stoichiometric amounts, but afterward, carbon monoxide, acetylene, and excess alcohol give most of the acrylate ester by the catalytic reaction. The nickel chloride is recovered and recycled to the nickel carbonyl synthesis step. The main by-product is ethyl propionate, which is difficult to separate from ethyl acrylate. However, by proper control of the feeds and reaction conditions, it is possible to keep the ethyl propionate content below 1%. Even so, this is significantly higher than the propionate content of the esters from the propylene oxidation route. [Pg.155]

Furoxans, bis[(acetoxyalkyl)carbonyl]-synthesis, 6, 421 Furoxans, bisarylsulfonyl-synthesis, 6, 423 Furoxans, bis(dialkylamino)-synthesis, 6, 414 Furoxans, butylhexynyl-synthesis, 6, 423 Furoxans, decamethylenering cleavage, 6, 405 Furoxans, diacyl-thermolysis, 6, 81 synthesis, 6, 442 Furoxans, diadamant-1-yl-ring cleavage, 6, 404 Furoxans, dialkoxycarbonyl-synthesis, 6, 423 Furoxans, dialkyl-synthesis, 6, 423 Furoxans, diaryl-ozonolysis, 6, 405 Furoxans, diaroyl-isoxazoles from, 6, 82 Furoxans, dibenzoyl-synthesis, 6, 423 Furoxans, diethoxycarbonyl-synthesis, 6, 423... [Pg.639]

Equation 11.16 Carbonylative synthesis of benzoic acid in the presence... [Pg.388]

Heterojunction with intrinsic thin layer (HIT) photovoltaic cell, 23 46-47 Heteroleptic uranium complexes, 25 441 Heterologous promoters, 22 453 Heteronano interface (HNI), 23 838 Heteronium bromide, 4 359t Heteronuclear metal carbonyls, synthesis of, 26 69-71... [Pg.430]

High molecular weight synthetic alkylated aromatic feedstocks, 23 533 High nuclearity carbonyl clusters, 16 64-66 High nuclearity metal carbonyl synthesis, 16 66-69 from salts, 16 68 from smaller carbonyls, 16 68-69 High ortho novolacs... [Pg.436]

Torrence P (2002) Carbonylations synthesis of acetic acid and acetic acid anhydride from methanol. In Cornils B, Herrmann WA (eds) Applied homogeneous catalysis with organometallic compounds, vol 1, 2nd edn. Wiley, Weinheim, p 104... [Pg.210]

FT-ICR, see Fourier-transform ion cyclotron resonance Fullerene[60], germanium-germanium addition, 10, 748 Fullerenes with cobalt, 7, 51 on cobalt Cp rings, 7, 73 inside metallodendrimers, 12, 401 microwave applications, 1, 334 Pd rc-complexes, 8, 348 Ru—Os complexes, 6, 830 with tungsten carbonyls, 5, 687 )2-Fullerenes, with platinum, 8, 634 Fulvalene actinide complex, synthesis, 4, 232 Fulvalene chromium carbonyls, synthesis and characteristics, 5, 264... [Pg.107]

Fulvalene zirconium(III) compounds, reactions, 4, 751 Fulvene chromium carbonyls, synthesis and characteristics,... [Pg.107]

H. Podall J. Chem. Educ. 38 187 (1961) Recent developments in metal carbonyl synthesis 5 (40) ... [Pg.307]

The chemistry of transition metal carbonyls synthesis and reactivity... [Pg.468]

Eschenmoser, A., Eelix, D., Ohioff, G. New fragmentation reaction of a,P-unsaturated carbonyls. Synthesis of exaltone and rac-muscone from cyclododecanone. Helv. Chim. Acta 1967, 50, 708-713. [Pg.582]

On the other hand, although the formation of carbonyls with Fe, Ni and Co is very common, it does not occur when PFSA films exchanged with their aquated Fe+, Ni, Co+, Co+, or Cu+2 ions are reacted, either hydrated or dehydrated, with CO in the 0.1 to 1.0 atm and 25°C to 220°C range (15). It seems clear that reduction of these ions is required prior to carbonyl formation. While that fact is well known in metal carbonyl synthesis, it isn t entirely clear why such reduction is necessary in this ionomer since a wide range of other metal ions in PFSA do form carbonyls. In some of these cases it may be that the hydration of the ions is too strong for the CO to displace H2O to form a relatively weak association. In other cases the reduction may simply require more of a driving force than can be provided by the H2, which is formally or actually formed in the films through reaction of CO and H2O. [Pg.68]

In the course of studying the stoichiometric, carbonylative synthesis of y-buty-rolactones from enones and a titanocene complex [37], it was observed that certain aryl enones could be cyclocarbonylated in a catalytic manner, Eq. (12) [38]. This success in effecting a titanocene-catalyzed cyclocarbonylation led to an examination of the analogous reaction with enyne substrates. Indeed, it was found that under similar conditions, a titanocene-catalyzed Pauson-Khand type cyclization was possible, Eq. (13) [36]. [Pg.475]

Chapter 23 Metal carbonyls synthesis, physical properties and structure 709... [Pg.709]


See other pages where Synthesis carbonyl is mentioned: [Pg.127]    [Pg.714]    [Pg.906]    [Pg.158]    [Pg.9]    [Pg.57]    [Pg.817]    [Pg.714]    [Pg.906]    [Pg.127]    [Pg.150]    [Pg.124]    [Pg.714]    [Pg.906]    [Pg.127]    [Pg.149]    [Pg.358]    [Pg.33]   
See also in sourсe #XX -- [ Pg.53 ]




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0-Silyl carbonyl compounds, synthesis

ATTEMPTED SYNTHESES OF CARBONYL DIIODIDE

Acetic Acid Synthesis via Methanol Carbonylation

Acetic acid synthesis, carbonylation

Acetic acid synthesis, carbonylation methanol

Alcohols, synthesis carbonyl compounds

Amines asymmetric synthesis from carbonyl

Amino-acids, synthesis from carbonylation

Asymmetric synthesis carbonyl compounds

Benzothiazole, vinylin synthesis masked carbonyl derivative

Carbonate synthesis, alcohol oxidative carbonylations, palladium

Carbonyl Condensation Reactions in Synthesis The Robinson Annulation Reaction

Carbonyl bromide chloride synthesis

Carbonyl bromide fluoride synthesis

Carbonyl chloride iodide synthesis

Carbonyl chloride isocyanate synthesis

Carbonyl colorants synthesis

Carbonyl complexes syntheses

Carbonyl compounds acetoacetic ester synthesis

Carbonyl compounds alkene synthesis from

Carbonyl compounds asymmetric synthesis, enantioselectivity

Carbonyl compounds chain-elongating synthesis

Carbonyl compounds diastereoselective synthesis

Carbonyl compounds enamines, synthesis

Carbonyl compounds fragmentation synthesis

Carbonyl compounds heterocyclic synthesis

Carbonyl compounds heterocyclic synthesis, intramolecular

Carbonyl compounds malonic ester synthesis

Carbonyl compounds natural products synthesis

Carbonyl compounds ortho acid synthesis

Carbonyl compounds oxime synthesis

Carbonyl compounds substituted acetic acids, synthesis

Carbonyl compounds synthesis

Carbonyl compounds synthesis by alkene oxidation

Carbonyl compounds synthesis from

Carbonyl compounds synthesis from nitriles

Carbonyl compounds synthesis, Knoevenagel reaction

Carbonyl compounds synthesis, palladium catalysis

Carbonyl compounds, allenic synthesis

Carbonyl derivatives, synthesis using

Carbonyl dibromide synthesis

Carbonyl difluoride synthesis

Carbonyl diisocyanate synthesis

Carbonyl fluoride iodide synthesis

Carbonyl halides laboratory syntheses

Carbonyl reduction chiral compound stereoselective synthesis

Carbonyl selenide synthesis

Carbonyl sulfide synthesis

Carbonyl syntheses with

Carbonyl ylide, metal carbene synthesis

Carbonyl ylides directed syntheses

Carbonyl ylides enantioselective syntheses

Carbonyl ylides synthesis

Carbonylation hydroxamic acid synthesis

Carbonylation natural product synthesis

Carbonylation, synthesis with

Carbonylative Coupling Reactions Synthesis of Carbonyl Derivatives

Carbonylative Coupling Reactions Synthesis of Carboxylic Acid Derivatives

Carbonylative ketone synthesis

Carbonyls inorganic syntheses

Cationic metal carbonyls synthesis

Chain-Elongating Syntheses of Carbonyl Compounds

Chromium carbonyl asymmetric synthesis

Chromium carbonyl synthesis

Chromium trioxide synthesis of carbonyl compounds

Chromone-2-carbonyl chlorides synthesis

Cobalt carbonyl hydride synthesis

Cobalt carbonyls synthesis

Cyclopentenone synthesis carbonylation

Enamine carbonyls synthesis methods

Enolates synthesis from carbonyl compounds

Enone , conjugate carbonyl synthesis

Enone, conjugate carbonyl addition synthesis

Free Radical Methods for the Synthesis of Carbonyl Compounds

Furan, 2,5-bis reaction with carbonyl compounds synthesis

Halo carbonyl compounds 390 Synthesis

High nuclearity metal carbonyl clusters synthesis

High-Nuclearity Carbonyl Clusters: Their Synthesis and Reactivity

High-nuclearity carbonyl clusters syntheses

High-pressure synthesis carbonyl complexes

In the synthesis of, carbonyl difluoride

Iridium carbonyls synthesis

Iron carbonyl complexes carboxylic acid synthesis

Iron carbonyl complexes ketone synthesis

Iron carbonyls synthesis

Lactam synthesis carbonylation

Lactam synthesis carbonylation, intramolecular cyclization

Lactone synthesis carbonylation

Lactones synthesis, carbonylation of allylic alcohols

Metal carbonyl cations synthesis

Metal carbonyl clusters synthesis

Metal carbonyl fluorides, synthesis

Metal carbonyls high-pressure synthesis

Metal carbonyls synthesis

Metal carbonyls synthesis, physical properties and structure

Molybdenum carbonyl synthesis

Nickel carbonyl synthesis

Osmium carbonyl clusters synthesis

Osmium carbonyls synthesis

Osmium tetroxide synthesis of carbonyl compounds

Oxirane synthesis from carbonyl compounds

Ozone synthesis of carbonyl compounds

Palladium-catalyzed carbonylative domino synthesis

Palladium®) complexes carbonylation, natural products synthesis

Peptide synthesis carbonyl chemistry in action

Phase transfer catalysis synthesis of carbonyl compounds

Poly in the synthesis of, carbonyl difluoride

Potassium permanganate synthesis of carbonyl compounds

Rf-block metal carbonyl cations, synthesis physical properties

Rf-block metal carbonyl cations, synthesis reactions

Rhodium carbonyls synthesis

Ruthenium carbonyls synthesis

Ruthenium tetroxide synthesis of carbonyl compounds

Ruthenium, high nuclearity carbonyl synthesis

STILLE Carbonyl Synthesis

SYNTHESIS OF PHOSGENE FROM OTHER CARBONYL HALIDES

Selenides carbonyl compound synthesis from

Sodium periodate synthesis of carbonyl compounds

Sulfides carbonyl compound synthesis from

Syntheses of Carbonyl Compounds by Ring-Enlargement Reactions

Synthesis carbonylation

Synthesis carbonylation

Synthesis of Carbonyl Colorants

Synthesis of Carbonyl Compounds

Synthesis of Carbonyl Compounds From Nitriles

Synthesis of Heterocyclic Compounds Containing a Carbonyl Moiety by Radical Carbonylations

Synthesis of Metal Carbonyls

Synthesis of anionic osmium carbonyl clusters

Synthesis of carbonyl difluoride from carbon

Synthesis of carbonyl difluoride from methane

Synthesis of carbonyl difluoride from tetrafluoroethene

Synthesis of epoxides from carbonyl compounds and sulfonium salts

Synthesis of high-nuclearity carbonyl clusters

Synthesis of perfluoroalkyl heterocycles from carbonyl

Synthesis reductive carbonylation

Titanocene, crotylreaction with carbonyl compounds synthesis

Transition metal carbonyl, synthesis

Tungsten carbonyl complexes synthesis

Tungsten carbonyl complexes synthesis, structure, properties

Tungsten carbonyl synthesis

Unsaturated carbonyl compounds) 394 Synthesis

Unsaturated carbonyl derivative synthesis

Zirconocene, crotylreaction with carbonyl compounds synthesis

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