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With Organometallic Compounds

Organohthium and organomagnesium compounds find their chief use m the prepa ration of alcohols by reaction with aldehydes and ketones Before discussing these reac tions let us first examine the reactions of these organometallic compounds with proton donors... [Pg.592]

T. G. Brihnka and V. A. Shushunov, Reactions of Organometallic Compounds with Ouygen and Peroxide, CRC Press, Inc., Cleveland, Ohio, 1969, pp. 184-185. [Pg.360]

Azolium rings react readily with organometallic compounds. With a Grignard reagent, conversion (193) -> (194) is known in the benzothiazolium series, and 1,3-benzodithioly-liums give products of type (195). [Pg.66]

Reaction of organometallic compounds with enamine salts have been successfully used for the synthesis of some natural products (256). Thus reaction of the immonium salt of 0-alkylated enamino ketone 122 with isobutyllithium affords the compound 169. [Pg.290]

Examples of the Activity of the Catalyst Formed by the Reaction of Transition Metal Organometallic Compounds with Oxide Supports during Ethylene Polymerisation... [Pg.188]

The Reaction of Organometallic Compounds with the Support as a Stage... [Pg.189]

The availability of organic ligands in the surface complexes obtained by the reaction of organometallic compounds with supports allows us to consider two possibilities of the initiation process (1) the monomer insertion into the organic ligand-metal bond (bensyl, allyl, etc.) (9a) ... [Pg.190]

The data obtained up to the present time show that the method of catalyst preparation by the reaction of organometallic compounds with surface reactive groups may be applied to generate both isolated ions of transition metals (in various valent states) or superfine metal particles on the surface of the support. [Pg.192]

C. Reaction of Organometallic Compounds with Sulphurous Add Derivatives 257... [Pg.233]

Aylett, B. J., and Tannahill, A. A., Chemical Vapour Deposition of Metal Silicides from Organometallic Compounds with Silicon-Metal Bonds, SIRA Int. Seminar on Thin Film Preparation and Processing Technolgy, Brighton, UK (March 1985)... [Pg.341]

It might be mentioned that matters are much simpler for organometallic compounds with less-polar bonds. Thus Et2Hg and EtHgCl are both definite compounds, the former is a liquid and the latter is a solid. Organocalcium reagents are also known, and they are formed from alkyl halides via a single electron transfer (SET) mechanism with free-radical intermediates. "... [Pg.237]

For a list of preparations of ketones by the reaction of organometallic compounds with carboxylic esters, salts, anhydyrides, or amides, with references, see Ref. 568, pp. 685, 693. [Pg.670]

Coupling of Organometallic Compounds with Aryl Halides, Ethers, and Carboxylic Esters... [Pg.868]

Reaction of organometallic compounds with aziridines 10-103 Reaction of organometallics with aziridines... [Pg.1654]

Coupling of organometallic compounds with aryl halides, ethers, and... [Pg.1657]

Reaction of aryl organometallic compounds with halogens Aryl halide exchange halo-denitration halo-dehydroxylation Reaction between diazonium salts and iodide ion Heating of diazonium fluoroborates (Schiemann)... [Pg.1658]

Organometallic compounds with metal-metal bonds... [Pg.254]

The most widely used route to organoboranes is hydroboration, introduced in Section 4.5.1, which provides access to both alkyl- and alkenylboranes. Aryl-, methyl-, allylic, and benzylboranes cannot be prepared by hydroboration, and the most general route to these organoboranes is by reaction of an organometallic compound with a halo- or alkoxyboron derivative.1... [Pg.784]

Seifert, D. Organometallic Compounds with a Vinyl Group, Moscow, Mir Publishers 1964, (Russ. Transl.)... [Pg.137]

Zinc forms numerous organometallic compounds, with the dialkyls being the most important. Although these compounds do not associate to give aggregates, they are spontaneously flammable. The reaction of a zinc halide with a Grignard reagent can be used to prepare the compounds. [Pg.411]

In some reactions of carbanions or organometallic compounds with very weak acids the base has a choice of protons and can give more than one salt. An example is the nuclear metallation of a substituted benzene in which the product may be oriented ortho, meta, or para. The actual results of a few such reactions are shown in Table XII. [Pg.203]

Photoelectron spectroscopy (PES) of organometallic compounds with C-M (M = Ge, Sn, Pb) bonds... [Pg.291]


See other pages where With Organometallic Compounds is mentioned: [Pg.82]    [Pg.259]    [Pg.189]    [Pg.203]    [Pg.235]    [Pg.173]    [Pg.836]    [Pg.836]    [Pg.837]    [Pg.1617]    [Pg.118]    [Pg.767]    [Pg.769]    [Pg.387]    [Pg.227]    [Pg.1]    [Pg.528]    [Pg.21]    [Pg.200]    [Pg.293]   


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1-Naphthy limine reactions with organometallic compounds

1.2.3- Triazine with organometallic compounds

1.3- Oxazines, 4,4,6-trimethyl-5,6-dihydromethiodide salt reactions with organometallic compounds

2- Hexenal reaction with organometallic compounds

2-Oxazolines, 4,4-dimethylmethiodide salt reactions with organometallic compounds

A -Piperidine reactions with organometallic compounds

A-Alkoxyaldimines reaction with allyl organometallic compounds

Acetals reactions with organometallic compounds

Acetophenone reaction with allylic organometallic compounds

Acids reaction with organometallic compounds

Acyl with organometallic compounds

Aldehydes, a-alkoxy reactions with organometallic compounds

Aldehydes, p-alkoxy reaction with allyl organometallic compounds

Aldimines reactions with organometallic compounds

Aldimines, N-isopropylreaction with crotyl organometallic compounds

Aldimines, N-isopropylreaction with crotyl organometallic compounds syn-anti selectivity

Aldimines, N-propylreaction with allyl organometallic compounds

Aldimines, a-alkoxyreaction with allyl organometallic compounds

Aldoxime ethers reactions with organometallic compounds

Alkenyl halides, coupling with metals organometallic compounds from

Allenic organometallic compounds reactions with aldimines

Allenic organometallic compounds reactions with imines

Allyl organometallic compounds reactions with 8-phenylmenthylA-methoxyiminoacetate

Allyl organometallic compounds reactions with a-phenylaldimine

Allyl organometallic compounds reactions with aldimines

Allyl organometallic compounds reactions with chiral C=N electrophiles

Allyl organometallic compounds reactions with gem-amino ethers

Allyl organometallic compounds reactions with glyoxylate aldimines

Allyl organometallic compounds reactions with imines

Amines, organometallic compounds with imines

Aniline, N-benzylidinereactions with organometallic compounds

Aniline, benzylidenereaction with crotyl organometallic compounds

Aniline, benzylidenereaction with crotyl organometallic compounds stereoselectivity

Aniline, benzylidenereaction with crotyl organometallic compounds syn-anti selectivity

Boranes, alkoxyreaction with organometallic compounds

Boranes, alkoxyreaction with organometallic compounds formation of aldehydes

Boranes, vinylreactions with organometallic compounds

Boranes, vinylreactions with organometallic compounds synthesis

Boranes, vinylreactions with organometallic compounds via hydroboration of 1-alkynes

Butanal, 2-ethylreaction with organometallic compounds

Butanal, 2-ethylreaction with organometallic compounds chemoselectivity

Butyraldehyde, 3-methoxy a-alkoxyaldimines derived from reaction with allyl organometallic compounds

By Reaction with Other Organometallic Compounds

Carbonyl compounds acid derivatives reactions with organometallic reagents

Carbonyl compounds reactions with crotyl organometallics

Carbonyl compounds reactions with organometallic reagents

Carbonyl compounds reactions with organometallics

Carbonyl compounds with organometallic reagents

Chloromethyl with organometallic compounds

Coupling of alkyl halides with organometallic compounds

Cross-coupling halides with organometallic compounds

Cross-coupling of haloalkynes with organometallic compounds

Crotyl organometallic compounds reactions with achiral ketones

Crotyl organometallic compounds reactions with aldehydes

Crotyl organometallic compounds reactions with aldimines

Crotyl organometallic compounds reactions with gem-amino ethers

Crotyl organometallic compounds reactions with imines

Crown ethers reactions with organometallic compounds

Cumulative Subject reactions with organometallic compounds

Cyclohexylamine, V-methyl-4-z-butylreaction with allyl organometallic compounds

Cyclopentanone, 2-phenylreaction with organometallic compounds

Diborane reaction with organometallic compounds

Electrophilic cyclopropanes reaction with organometallic compound

Ethylamine, cyclohexylsynthesis reaction with allyl organometallic compounds

Ethylamine, phenylaldimines derived from reaction with allyl organometallic compounds

Fluorine 18 atom reactions with organometallic compounds

Formaldoxime ethers reactions with organometallic compounds

From organometallics with fluoro compounds

Gem-Amino ethers, N- reactions with allyl organometallic compounds

Glyoxylates reaction with allyl organometallic compounds

Heptan-2-one reaction with allylic organometallic compounds

Hydrazones reactions with organometallic compounds

Hydroxylamine, V- reaction with allyl organometallic compounds

Hydroxylamines reactions with organometallic compounds

Imidazoles, l-benzyl-2-alkyl-4,5-dihydromethiodide salt reactions with organometallic compounds

Imines, N-trimethylsilylin situ synthesis reactions with organometallic compounds

Iminium salts reactions with organometallic compounds

Isoquinoline, 3,4-dihydro-6,7-dialkoxyreactions with organometallic compounds

Ketones reactions with organometallic compounds

Lewis acids reactions with organometallic compounds

Lithium with organometallic compounds

Malonic esters, acyliminoreactions with organometallic compounds

Methyl iodide with organometallic compounds

Nitroarenes reaction with organometallic compound

Nitrones reactions with organometallic compounds

Olefinic esters reaction with organometallic compounds

Opening reactions with organometallic compounds

Organometallic Compounds with -n-Bonding

Organometallic Compounds with 7r-Bonding

Organometallic Compounds with Perfluorinated Ligands

Organometallic Compounds with ir-Bonding

Organometallic Compounds with tt Bonding

Organometallic compound, coupling with

Organometallic compound, coupling with alkyl halide

Organometallic compounds acetylene, reactions with

Organometallic compounds allene, reactions with

Organometallic compounds carbene, reactions with

Organometallic compounds carbenes, reactions with

Organometallic compounds carbyne, reactions with

Organometallic compounds coupling with active

Organometallic compounds coupling with alcohols

Organometallic compounds coupling with alkyl

Organometallic compounds dithioacetals, reactions with

Organometallic compounds interactions with biological

Organometallic compounds photochemistry with

Organometallic compounds reaction with 1 -alkynyl halides

Organometallic compounds reaction with alkyl halides

Organometallic compounds reactions with aldehydes

Organometallic compounds reactions with aldimines, regiochemistry

Organometallic compounds reactions with amides

Organometallic compounds reactions with cyclic ketones

Organometallic compounds reactions with electrophiles

Organometallic compounds reactions with epoxides

Organometallic compounds reactions with nitriles

Organometallic compounds reactions with selenides

Organometallic compounds reduction with sodium

Organometallic compounds thiophene, reactions with

Organometallic compounds various, with acid

Organometallic compounds with acid derivatives

Organometallic compounds with acids

Organometallic compounds with acyl halides

Organometallic compounds with alkyl halides

Organometallic compounds with amides

Organometallic compounds with anhydrides

Organometallic compounds with aryl halides

Organometallic compounds with aziridines

Organometallic compounds with bridging ligands

Organometallic compounds with carbon dioxide

Organometallic compounds with carboxylic acids

Organometallic compounds with conjugated carbonyl

Organometallic compounds with copper

Organometallic compounds with disulfides

Organometallic compounds with epoxides

Organometallic compounds with esters

Organometallic compounds with halides

Organometallic compounds with imines

Organometallic compounds with isocyanides

Organometallic compounds with metal sulfonates

Organometallic compounds with metal-carbon multiple bonds

Organometallic compounds with metals

Organometallic compounds with nitriles

Organometallic compounds with oxygen

Organometallic compounds with peroxides

Organometallic compounds with unsaturated halides

Organometallic compounds with zinc

Organometallic compounds, 1,4-addition metals with halides

Organometallic compounds, 1,4-addition with alkyl-metal bonds

Organometallic compounds, also from metallation with metals

Organometallic compounds, reactions with alkenes

Organometallic compounds, reactions with carbonyls

Organometallic compounds, reactions with imines

Organometallic compounds, reactions with triflates

Oximes reactions with allyl organometallic compounds

Oximes reactions with organometallic compounds

Oxirane reactions with organometallic compounds

Oxygen reaction with organometallic compounds

Peroxides reaction with organometallic compounds

Phosphonates, acyliminoreactions with organometallic compounds

Propargyl organometallic compounds reactions with gem-amino ethers

Propargyl organometallic compounds reactions with imines

Propionaldehyde, 2- methoxyaldimine derivatives reaction with allyl organometallic compounds

Pyridinium salts, 5,6-dihydroreactions with organometallic compounds

Reaction of Organometallic Reagents with Other Compounds

Reaction with other Organometallic Compounds

Reactions of organometallic compounds with metal halides

Reactions with organometallic compounds

Reactions with organometallic compounds Lewis acid promotion

Reactions with organometallic compounds alcohol synthesis

Reactions with organometallic compounds chemoselectivity

Reactions with organometallic compounds stereoselectivity

Reactivity of Organometallic Compounds with Metallic Surfaces

Rhodium with organometallic compounds

Selenones, vinyl reactions with organometallic compounds

Selenoxides, vinyl reactions with organometallic compounds

Silylimines, N-trimethylreaction with allyl organometallic compounds

Stannane, -tri-n-butylreactions with crotyl organometallic compounds

Stannanes reactions with organometallic compounds

Subject reactions with organometallic compounds

Sulfamides, diaryl reactions with organometallic compounds

Sulfenimines, S-arylreactions with organometallic compounds

Sulfonimines reactions with organometallic compounds

Supramolecular Host Recognition Processes with Biological Compounds, Organometallic Pharmaceuticals, and Alkali-metal Ions as Guests

The interaction of carbonyl-containing compounds with organometallic reagents

Through Reactions with Organometallic Compounds

Water reactions with organometallic compound

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