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Iron carbonyl complexes carboxylic acid synthesis

The synthesis of (+)-pisiferic acid (1) presents many important aspects (i) functionalization of the angular methyl group to lactone, (ii) cleavage of lactone ring to carboxylic acid, and (iii) conversion of (78) to allylic alcohol (81) via iron carbonyl complex... [Pg.188]

The mechanism of CO substitution with phosphines in the 19-e complex Cp Mn(CO)2NO is dissociative, followed by spontaneous oxidation of the product. Trinuclear clusters containing CpRe(CO)-fiagments in combination with iron carbonyl sulfido dimers have been reported. The synthesis of CpMn(CO)2(n -cyclooctyne) and the ligand rearrangement to an allene complex within the metal coordination sphere has been investigated by NMR spectroscopy. Tc labelled esters of cytectrene carboxylic acid have been prepared by exchange with ferrocenylcarboxylic acids in the presence of carbonyl donors. ... [Pg.387]


See other pages where Iron carbonyl complexes carboxylic acid synthesis is mentioned: [Pg.385]    [Pg.1087]    [Pg.2022]    [Pg.223]    [Pg.2021]    [Pg.81]    [Pg.3]    [Pg.426]    [Pg.147]    [Pg.308]   
See also in sourсe #XX -- [ Pg.371 , Pg.372 , Pg.374 , Pg.374 ]




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Acidic carbonyl

Carbonyl carboxylate

Carbonyl complexes syntheses

Carbonylation Iron carbonyl

Carbonyls synthesis

Carboxylate complexes

Carboxylate, synthesis

Carboxylic acid complexes

Carboxylic acids iron complexes

Carboxylic synthesis

Iron 4] synthesis

Iron carbonyl complexes

Iron carboxylates

Iron complex synthesis

Iron complexes carbonylation

Iron complexes carboxylates

Iron complexes complex synthesis

Irones synthesis

Synthesis carbonylation

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