Metal carbonyls synthesis

Heterojunction with intrinsic thin layer (HIT) photovoltaic cell, 23 46-47 Heteroleptic uranium complexes, 25 441 Heterologous promoters, 22 453 Heteronano interface (HNI), 23 838 Heteronium bromide, 4 359t Heteronuclear metal carbonyls, synthesis of, 26 69-71... 

High molecular weight synthetic alkylated aromatic feedstocks, 23 533 High nuclearity carbonyl clusters, 16 64-66 High nuclearity metal carbonyl synthesis, 16 66-69 from salts, 16 68 from smaller carbonyls, 16 68-69 High ortho novolacs... 

H. Podall J. Chem. Educ. 38 187 (1961) Recent developments in metal carbonyl synthesis 5 (40) ... 

The chemistry of transition metal carbonyls synthesis and reactivity... 

On the other hand, although the formation of carbonyls with Fe, Ni and Co is very common, it does not occur when PFSA films exchanged with their aquated Fe+, Ni, Co+, Co+, or Cu+2 ions are reacted, either hydrated or dehydrated, with CO in the 0.1 to 1.0 atm and 25°C to 220°C range (15). It seems clear that reduction of these ions is required prior to carbonyl formation. While that fact is well known in metal carbonyl synthesis, it isn t entirely clear why such reduction is necessary in this ionomer since a wide range of other metal ions in PFSA do form carbonyls. In some of these cases it may be that the hydration of the ions is too strong for the CO to displace H2O to form a relatively weak association. In other cases the reduction may simply require more of a driving force than can be provided by the H2, which is formally or actually formed in the films through reaction of CO and H2O. 

Chapter 23 Metal carbonyls synthesis, physical properties and structure 709... 

M. Denk, R. K. Hayashi, and R. West,/. Chem. Soc., Chem. Commun., 33 (1994). Silylene Complexes from a Stable Silylene and Metal Carbonyls Synthesis and Structure of [Ni(t-Bu—N—CH=CH—N—f-Bu)2(CO)2), a Donor-Free Bis-Silylene Complex. 

Metal carbonyls synthesis, physical properties and structure 899 Table 24.3 Neutral, low-nuclearity (metal carbonyls of the (f-block metals (dec. = decomposes). 

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