Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

And ethyl alcohol

Some liquids are practically immiscible e.g., water and mercury), whilst others e.g., water and ethyl alcohol or acetone) mix with one another in all proportions. Many examples are known, however, in which the liquids are partially miscible with one another. If, for example, water be added to ether or if ether be added to water and the mixture shaken, solution will take place up to a certain point beyond this point further addition of water on the one hand, or of ether on the other, will result in the formation of two liquid layers, one consisting of a saturated solution of water in ether and the other a saturated solution of ether in water. Two such mutually saturated solutions in equilibrium at a particular temperature are called conjugate solutions. It must be mentioned that there is no essential theoretical difference between liquids of partial and complete miscibility for, as wdll be shown below, the one may pass into the other with change of experimental conditions, such as temperature and, less frequently, of pressure. [Pg.17]

An important application of the critical solution temperature is to the determination of the water content in such substances as methyl and ethyl alcohols. Here the system is usually the alcohol and a hydro carbon, such as -hexane or dicyclohexyl the water is, of course, insoluble in the hydrocarbon. Thus, the methyl alcohol - cyclohexane system has a C.S.T. of 45 -5° and even 0 01 per cent, of water produces a rise of 0-15° in the C.S.T. The experimental details are given below. [Pg.20]

The inflammable solvents most frequently used for reaction media, extraction or recrystallisation are diethyl ether, petroleum ether (b.p. 40-60° and higher ranges), carbon disulphide, acetone, methyl and ethyl alcohols, di-Mo-propyl ether, benzene, and toluene. Special precautions must be taken in handling these (and other equivalent) solvents if the danger of Are is to be more or less completely eliminated. It is advisable to have, if possible, a special bench in the laboratory devoted entirely to the recovery or distillation of these solvents no flames are permitted on this bench. [Pg.90]

Extremely dry (or super-dry ) ethyl alcohol. The yields in several organic preparations e.g., malonic ester syntheses, reduction with sodium and ethyl alcohol, veronal synthesis) are considerably improved by the use of alcohol of 99-8 per cent, purity or higher. This very high grade ethyl alcohol may be prepared in several ways from commercial absolute alcohol or from the product of dehydration of rectified spirit with quicklime (see under 4). [Pg.167]

Method 2 (E. L. Smith, 1927). Sodium alone cannot be used for the complete removal of water in ethyl alcohol owing to the equilibrium between the resulting sodium hydroxide and ethyl alcohol ... [Pg.168]

Shake 1 ml. of anhydrous methyl alcohol with 1 ml. of paraffin oil. Repeat the experiment with 1 ml. of n butyl alcohol. From your results state which is the better solvent for paraffin oil (a mixture of higher hydrocarbons) and thus explain why n-butanol and higher alcohols are incorporated in pyroxylin lacquers in preference to methyl and ethyl alcohols. [Pg.261]

Mercaptals, CH2CH(SR)2, are formed in a like manner by the addition of mercaptans. The formation of acetals by noncatalytic vapor-phase reactions of acetaldehyde and various alcohols at 35°C has been reported (67). Butadiene [106-99-0] can be made by the reaction of acetaldehyde and ethyl alcohol at temperatures above 300°C over a tantala—siUca catalyst (68). Aldol and crotonaldehyde are beheved to be intermediates. Butyl acetate [123-86-4] has been prepared by the catalytic reaction of acetaldehyde with 1-butanol [71-36-3] at 300°C (69). [Pg.51]

Dibromoacetic acid [631-64-1] (Br2CHCOOH), mol wt 217.8, C2H2Br202, mp 48°C, bp 232—234°C (decomposition), is soluble in water and ethyl alcohol. It is prepared by adding bromine to boiling acetic acid, or by oxidi2ing tribromoethene [598-16-3] with peracetic acid. [Pg.90]

Many other recovery alternatives have been proposed that iaclude ion exchange (qv), pyrolysis, and wet combustion. However, these have not gained general acceptance. A limited number of calcium-based mills are able to utilize their spent pulpiag liquors to produce by-products such as lignosulfates for oil-weU drilling muds, vanillin, yeast, and ethyl alcohol (see PETROLEUM Vanillin). [Pg.274]

Poly(vinyl acetate) and its copolymers with ethylene are available as spray-dried emulsion soHds with average particle sizes of 2—20 p.m the product can be reconstituted to an emulsion by addition of water or it can be added directly to formulations, eg, concrete. The powders may be used to raise soHds of a lower soHds latex. Solutions of resin in methyl and ethyl alcohol at 2—50 wt % soHds are also available. [Pg.468]

The physical properties of methylene chloride are Hsted in Table 1 and the binary a2eotropes in Table 2. Methylene chloride is a volatile Hquid. Although methylene chloride is only slightly soluble in water, it is completely miscible with other grades of chlorinated solvents, diethyl ether, and ethyl alcohol. It dissolves in most other common organic solvents. Methylene chloride is also an excellent solvent for many resins, waxes, and fats, and hence is well suited to a wide variety of industrial uses. Methylene chloride alone exhibits no dash or fire point. However, as Htde as 10 vol % acetone or methyl alcohol is capable of producing a dash point. [Pg.518]

The physical piopeities of ethyl chloiide aie hsted in Table 1. At 0°C, 100 g ethyl chloride dissolve 0.07 g water and 100 g water dissolve 0.447 g ethyl chloride. The solubihty of water in ethyl chloride increases sharply with temperature to 0.36 g/100 g at 50°C. Ethyl chloride dissolves many organic substances, such as fats, oils, resins, and waxes, and it is also a solvent for sulfur and phosphoms. It is miscible with methyl and ethyl alcohols, diethyl ether, ethyl acetate, methylene chloride, chloroform, carbon tetrachloride, and benzene. Butane, ethyl nitrite, and 2-methylbutane each have been reported to form a binary azeotrope with ethyl chloride, but the accuracy of this data is uncertain (1). [Pg.1]

WeU-cleaned aluminum filings react at room temperature in the presence of mercuric chloride (20,21). In an autoclave, metallic aluminum and ethyl alcohol react without a catalyst at 120°C (22). The reaction can also be promoted by the addition of sodium ethoxide (23). Aluminum should be avoided as a material of constmction for ethanol service. [Pg.402]

FIG. 2-10 Enthalpy-concentration diagram for aqueous ethyl alcohol. Reference states Enthalpies of hquid water and ethyl alcohol at 0 C are zero. NOTE In order to interpolate equilihrium compositions, a vertical may he erected from any liquid composition on the hoihug hue and its intersection with the auxihary hue determined. A horizontal from this intersection will estahhsh the equihhrium vapor composition on the dew hue. (Bosnjakovic, Techuische Thermo-dynamik, T. Steinkopff, Leipzig, 1935. )... [Pg.279]

Decamethylene glycol has been prepared by the reduction of dimethyl sebacate and diethyl sebacate with sodium and ethyl alcohol by the reduction of sebacamide with sodium and amyl alcohol and by the reduction of dimethyl sebacate with sodium and liquid ammonia in absolute alcohol. The reduction of esters with sodium and alcohol has also been applied to the preparation of many other glycols. ... [Pg.22]

Ethyl ether and ethyl alcohol which are formed as by-products are removed by distillation and the ethyl cellulose is precipitated by hot water. The polymer is then carefully washed to remove sodium hydroxide and sodium chloride and dried. [Pg.630]

Compounds Affecting Rq>roduction Compounds that can affect reproductive function include several drugs and occupationally important chemicals such as solvents and pesticides as well as a number of environmentally relevant com-fxrunds. A group of chemical compounds that has received much attention recently is endocrine disrupters, many of which are halogenated hydrocarbons, e.g., PCBs. These are known to induce feminization in fish and other animal species.1.5/ There is intense debate about the significance of these compounds to human health. Tobacco smoke and ethyl alcohol also have major effects on human reproduction, the effects of alcohol being especially important. Table 5.17 lists compounds that may disturb the functions of female and male reproductive functions. [Pg.304]

Bodies of an alcholic nature play a very important part in both natural and synthetic perfumery. They are found to a very large extent in essential oils, both in the free state and also in the form of esters. Some that have not so far been recognised as constituents of essential oils, have been found to be so highly odorous, and so useful as perfume materials, that they are prepared artificially, and enter largely into the composition of the synthetic perfumes which to-day are indispensable to the manufacturer of perfumes. It is obvious that those alcohols which are soluble in water, such as methyl and ethyl alcohols, although they may be original constituents of some essential oils, are removed by the ordinary distillation processes, so that they do not, in fact, appear in the essential oil as found in commerce. [Pg.104]

Ethyl Cinnamate.—The cinnamic ester of ethyl alcohol is a natural constituent of a few essential oils, including camphor oil and storax. It is formed synthetically by condensing cinnamic acid and ethyl alcohol by dry hydrochloric acid gas. It has a soft and sweet odour, and is particularly suitable for blending in soap perfumes. It is an oil at ordinary temperatures, melting at 12°, and boiling at 271°. Its specific gravity is 1 0546, and its refractive index 1 5590. [Pg.166]

The noncatalytic oxidation of propane in the vapor phase is nonselec-tive and produces a mixture of oxygenated products. Oxidation at temperatures below 400°C produces a mixture of aldehydes (acetaldehyde and formaldehyde) and alcohols (methyl and ethyl alcohols). At higher temperatures, propylene and ethylene are obtained in addition to hydrogen peroxide. Due to the nonselectivity of this reaction, separation of the products is complex, and the process is not industrially attractive. [Pg.171]

The reaction between isobutylene and methyl and ethyl alcohols is an addition reaction catalyzed by a heterogeneous sulfonated polystyrene resin. When methanol is used a 98% yield of methyl-ter-butyl ether MTBE is obtained ... [Pg.252]

The standard etch primer (WP-1, DEF-1408) consists of two solutions, one containing polyvinyl butyral resin and zinc tetroxychromate in ethyl alcohol with n-butanol, and the second containing phosphoric acid and ethyl alcohol. It is essential that a small critical amount of water be present in the latter. The two solutions are mixed in appropriate ratio for use the mixture deteriorates and should be discarded when more than 8 h old. Single-pack etch primers of reasonable shelf life are available but contain less phosphoric acid than the above and are not considered to be so effective. [Pg.730]

Tlie numerical values in (20) and (24) refer to water. After cheeking these values, obtain the corresponding expressions for methyl and ethyl alcohols, taking the necessary quantities from Table 1. [Pg.20]

Table 23. Viscosity B-Coefficients in Dilute Methyl and Ethyl Alcohols at... Table 23. Viscosity B-Coefficients in Dilute Methyl and Ethyl Alcohols at...
If, then, values of w/(A0 — A ) obtained from experiment are plotted against the molarity of the water n, a straight line should be obtained, of which the slope is (X+ — X +) and the intercept — r. The results1 in methyl and ethyl alcohol are shown in Fig. 62. It will be seen that from the intercept the value r = 0.25 is obtained in methyl, and r = 0.06 in ethyl. In each solvent the mobility of the (HaO)+ ion is found to be not very different from that of the Na+ ion. [Pg.226]

Nonconductors of electricity when pure. Molecules are uncharged, so they cannot carry an electric current. In most cases (e.g., iodine, I2, and ethyl alcohol, C2H5OH), water solutions of molecular substances are also nonconductors. A few polar molecules, including HC1, react with water to form ions ... [Pg.235]

This mercury safety valve avoids all dangers which might result from the development of excess pressure within the system (Note 3). The temperature of the esterification mixture is kept at 105-110° and ethyl alcohol vapor is passed through until 500 cc. of distillate has been collected. This requires about three hours. The distillate consists of alcohol, water, and a little ether. [Pg.70]

First we can investigate, qualitatively, the extent to which the solids dissolve in the liquids. By adding a small piece of each solid to a milliliter of liquid, we easily discover that sugar dissolves both in water and ethyl alcohol, sodium chloride dissolves readily in water but not in ethyl alcohol, and iodine does not dissolve much... [Pg.73]

N -Ethyl-jK-toluidine has been obtained by passing m-toluidine and ethyl alcohol over a catalyst at high temperatures,1 and by the use of ethyl />-toluenesulfonate 2 as an alkylating agent. The present method of purification is a modification of a general procedure for secondary amines developed by Diepolder.3... [Pg.42]

Soluble in Methyl and ethyl alcohols, acetone, ether, ethylene- Most organic solvents... [Pg.485]

Compounds containing oxygen linked to a carbon and a hydrogen atom are termed alcohols. Simple examples are methyl and ethyl alcohol, CH3OH and C2H5OH, respectively. Reactions of alcohols are characterized by the replacement of either the OH hydrogen atom or the entire OH group ... [Pg.37]


See other pages where And ethyl alcohol is mentioned: [Pg.43]    [Pg.104]    [Pg.29]    [Pg.389]    [Pg.380]    [Pg.239]    [Pg.240]    [Pg.52]    [Pg.29]    [Pg.165]    [Pg.793]    [Pg.245]    [Pg.40]    [Pg.21]    [Pg.874]    [Pg.42]    [Pg.53]   
See also in sourсe #XX -- [ Pg.4 ]




SEARCH



Alcohol Ethylic

Ethyl alcohol

© 2024 chempedia.info