Excess pressure

It is this type of work that is ubiquitous in chemical themiodynamics, principally because of changes of the volume of the system under the external pressure of the atmosphere. The negative sign of the work done on the system is, of course, because the application of excess pressure produces a decrease in volume. (The negative sign in the two-dimensional case is analogous.)... 

All clamps holding glass apparatus should be lined with cork, attached by means of glue or seccotine , or with asbestos paper this will reduce the danger of fracture if excessive pressure is exerted on the clamp. 

Section 3.7, the gas adsorption method breaks down for practical reasons. Since the angle of contact of mercury with solids is 140° (see later), and therefore more than 90°, an excess pressure Ap is required to force liquid mercury into the pores of a soh d. The idea of using mercury intrusion to measure pore size appears to have been first suggested by Washburn who put forward the basic equation... 

Because of its small size and portabiHty, the hot-wire anemometer is ideally suited to measure gas velocities either continuously or on a troubleshooting basis in systems where excess pressure drop cannot be tolerated. Furnaces, smokestacks, electrostatic precipitators, and air ducts are typical areas of appHcation. Its fast response to velocity or temperature fluctuations in the surrounding gas makes it particularly useful in studying the turbulence characteristics and rapidity of mixing in gas streams. The constant current mode of operation has a wide frequency response and relatively lower noise level, provided a sufficiently small wire can be used. Where a more mgged wire is required, the constant temperature mode is employed because of its insensitivity to sensor heat capacity. In Hquids, hot-film sensors are employed instead of wires. The sensor consists of a thin metallic film mounted on the surface of a thermally and electrically insulated probe. 

Fig. 22. Multileaf spiral-wound module, used to avoid excessive pressure drops on the permeate side of the membrane. Large, 30-cm diameter modules may have as many as 30 membrane envelopes, each with a membrane area of about 2 m. ...

Storage and Handling. The acid should never be allowed to stand in a line completely sealed between two closed valves or check valves. Excessive pressure caused by thermal expansion of the Hquid can cause leaks or pipe mptures. AH lubricants and packing materials in contact with chlorosulfuric acid must be chemically resistant to the acid. Elanged connections are recommended over screwed fittings and flange guards should be used. 

Automobile exhaust catalysts have been developed that maximize the catalyst surface area available to the flowing exhaust gas without incurring excessive pressure drop. Two types have been extensively studied the monolithic honeycomb type and the pellet type. 

Line size and length must be small enough to meet transporttime requirements without excessive pressure drop or excessive bypass of sample at the analyzer input. 

Care of Pressure Vessels Protection against excessive pressure is largely taken care of by code requirements for relief devices. Exposure to fire is also covered by the code. The code, however, does not provide for the possibility of local overheating and weakening of a vessel in a fire. Insulation reduces the required relieving capacity and also reduces the possibihty of local overheating. 

Forced-Recirculation Reboilers In forced-recirculation reboilers, a pump is used to ensure circiilation of the liquid past the heattransfer surface. Force-recirculation reboilers may be designed so that boiling occurs inside vertical tubes, inside horizontal tubes, or on the shell side. For forced boihng inside vertical tubes. Fair s method (loc. cit.) may be employed, making only the minor modification that the recirculation rate is fixed and does not need to be balanced against the pressure available in the downcomer. Excess pressure required to circiilate the two-phase fluid through the tubes and back into the column is supphed by the pump, which must develop a positive pressure increase in the hquid. 

The wall thickness selected varies with the service and material. Carbon steel coils are often made from schedule 80 or heavier pipe to allow for corrosion. When stainless-steel or other high-aUoy coils are not subject to corrosion or excessive pressure, they mav be of schedule 5 or 10 pipe to keep costs at a minimum, altliougli high-quahty welding is required for these thin walls to assure trouble-free seiwice. 

Dry filters are usually deeper than viscous filters. The dry filter media use finer fibers and have much smaller pores than the viscous media and need not rely on an oil coating to retain collected dust. Because of their greater resistance to air flow, dry filters must use lower filtration velocities to avoid excessive pressure drops. Hence, dry media must have larger surface areas and are usually pleated or arranged in the form of pockets (Fig. 17-64), generally sheets of cellulose pulp, cotton, felt, or spun glass. 

Excessive pressure drop in the separator and in the inlet piping... 

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