Amyl acetate, oxidation

Benzyl alcohol can be smoothly converted to benzaldehyde by electrochemi-cally recycled BrO as an oxidizing catalyst in an emulsion system prepared from a mixture of water, amyl acetate, and 2% BU4NHSO4 [60]. A different hypobromite reagent is provided by an electrochemical oxidation of a cross-linked poly-4-vinylpyridine in an MeCN-H20-HBr-(Pt) system [61]. Secondary alcohols can be oxidized by this method to give ketones in high yields. The electrooxidation of A-monoalkyltosylamides (42) in a two-phase system consisting of cyclohexane... [Pg.499]

Lichenin Pentanitrate is insol in w, eth and benz readily sol in acet, et acet and amyl acet sol in eth-alc mixts. It is an expl compd, decompg at high temps, giving off oxides of nitrogen... [Pg.571]

Apard [27] found that the addition of finely powdered plumbous oxide, calcium oxide or calcium hydroxide to a 1% nitrocellulose solution in acetone, ether-alcohol or amyl acetate initially brought about an increase of the viscosity. Further addition of these substances caused the nitrocellulose to coagulate, together with the added... [Pg.301]

The remaining 30 percent of 1-butene is divided among several uses. About 10-15 percent of the 1-butene is polymerized in the presence of a Ziegler-type catalyst to produce polybutene-1 resin. The markets for this resin are pipe, specialty films, and polymer alloys. Approximately the same volume of 1-butene is reacted with synthesis gas in an oxo reaction to produce valeraldehydes. These C5 aldehydes are then hydrogenated to amyl alcohols or oxidized to valeric acid. Amyl alcohols are consumed in the production of lube oil additives and amyl acetate and in solvent uses. Valeric acid goes into lubricant base stocks and specialty chemicals. [Pg.387]

Gold(III) is usually separated from Pt and Pd by extraction from 4-8 M hydrochloric acid [18-20] or from H2S04-KBr media [21]. Oxygen-containing solvents, such as DIPE, MIBK, mesityl oxide, or amyl acetate have been used as extractants. Iron(III), which interferes, is masked with phosphoric acid before the extraction of gold. The chloride complex of gold can also be extracted with TOPO in MIBK [20], TBP in toluene or xylene [24]. The anionic... [Pg.210]

METHYL ISO AMYL ACETATE (108-84-9) C(Hit02 Forms explosive mixture with air (flash point 113°F/45°C). Violent reaction with strong oxidizers. Inconqjatible with sulfuric acid, nitric acid, caustics, aliphatic amines, isocyanates. Will swell rubber and can dissolve certain coatings. METHYL ISOBUTENYL KETONE (141-79-7) CjHioO (CH3)2C=CHCOCH3 Highly flammable liquid. Forms explosive... [Pg.712]

AMYL ACETATE or sec-AMYL ACETATE (626-38-0) Forms explosive mixture with air (flash point 89°F/32°C). High heat may lead to instability. Reacts with strong oxidizers. Incompatible with strong acids, nitrates, strong alkalis. Attacks many plastics. [Pg.106]

Acetic acid Acetylsalicylic acid Alpha-Tocopherol Aluminum Hydroxide Aluminum Potassium Sulfate Aluminum Oxide Ammonium Hydroxide Ammonium Nitrate Ammonium Sulfate Amoxicillin Amyl Acetate Amyl Nitrite Ascorbic Acid Benzoic Acid Boric Acid Butyl Acetate Butylated Hydroxyanisole and Butylated Hydro-xytoluene Caffeine... [Pg.900]

The isophthalic polyester resins are not resistant to acetone, amyl acetate, benzene, carbon disulfide, solutions of alkaline, salts of potassium and sodium, hot distilled water, or higher concentrations of oxidizing acids. [Pg.161]

Ammonium nitrate Ammonium nitrite Ammonium oxalate Ammonium salicylate Ammonium sulfate Ammonium sulfide Ammonium sulfite Ammonium thiosulfate Amyl acetate Amyl alcohol Amyl chloride Amyl mercaptan Amyl naphthalene Amyl nitrate Amyl nitrite Amyl phenol Aniline hydrdochloride Aniline sulfate Aniline sulfite Animal fats Animal oils Anthraquinone Antimony sulfate Antimony tribromide Antimony trichloride Antimony trioxide Aqua regia Arsenic oxide Arsenic trichloride Arsenic trioxide Arsenic trisulfide Ascorbic acid Barium carbonate Barium chlorate Barium chloride, aqueous Barium cyanide Barium hydroxide Barium iodide Barium nitrate Barium oxide Barium peroxide Barium salts Beet sugar liquors Benzaldehyde Benzene... [Pg.550]

Peanut oil. See Peanut (Arachis hypogaea) oil Peanut oil, sulfated. See Sulfated peanut oil Pearl stearic. See Stearic acid Pearl white. See Bismuth oxychloride Pear oil. See Amyl acetate Pebble lime. See Calcium oxide Pecan shell powder. See Peanut (Arachis hypogaea) oil PEDOT/PSS PEDT. See Poly (3,4-ethylenedioxythiophene)/poly (styrenesulfonic acid)... [Pg.1242]

Secondary Butyl Acetate Methyl Isobutyl Ketone Methyl Isobutyl Ketone (82.5% w)— Methyl Isobutyl Carbinol (17.5% w) Normal Butyl Acetate Mesityl Oxide Secondary Amyl Acetate Amyl Acetate (mixed isomers)... [Pg.358]

Properties YIsh.-wh. amorphous powd. or lumps, rosin odor sol. in acid, amyl acetate, butyl acetate, ether, amyl alcohol insol. in water m.w. 1349.5 soften, pt. 115-165 C Toxicology TSCA listed Precaution Flamm. solid dangerous fire risk spontaneous heating reactive with oxidizing materials... [Pg.707]

Pear oil. See Amyl acetate Isoamyl acetate Pebble lime Pebble Quicklime. See Calcium oxide... [Pg.3053]

Dimethyl, methyl (polyethylene oxide acetate-capped) siloxane finishing compounds, textiles 2-Ethylhexanol finishing emulsions, paper Butyl methacrylate Lauryl methacrylate Stearyl methacrylate finishing fabrics Amyl acetate finishing oil... [Pg.5257]

Hexanone Isoamyl acetate Isoamyl alcohol Isoamyl chloride Isobutyl alcohol Isohexane Isophorone Jsopropyl acetate Isopropyl alcohol dl-Limonene Longifolene Mesityl oxide 3-Methoxybutanol Methoxydiglycol Methoxyethanol Methoxyethanol acetate 2-Methoxy-1-propanol acetate Methyl abietate Methyl acetate Methyl amyl acetate... [Pg.5701]

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