Acrylates ethoxylated

Ethanol, 2,2, 2"-(propylidynetris methyleneoxy))tri-, tri-acrylate. Ethanol, 2, ,2 -(propylidynetris(methyleneoxy))tri-, tri-acrylate Ethoxylated trimethylolpropane triacrylate Trimethylolpropane ethoxylated, triacrylate Trimethyl-olpropane ethoxytriacrylate Trimethylolpropane poly-oxyethylene triacrylate. 

Properties Solid sol. in butyl Cellosolve acetate, 2-phenoxyethyl methacrylate, tetrahydrofurfuryl acrylate, ethoxylateds bisphenol Adiacrylate, propoxylated allyl methacrylate, tetrahydrofurfuryl mefhacrylate, epoxy acrylate oligomer blended with 1,6 hexanediol diacrylate m.p. 78 C ret. index 1.475 0.01% acid C[M06 [Sartomer]... 

Adekacol WS-100 Adekacol WS-110 dispersant, solvent-based acrylics Ethoxylated trimethylol propane dispersant, solvent-based architectural coatings Tenlo 70... 

AquaBead 270E AquaBead 325E BYK -LP N 20094 BYK -LP S 6665 emulsifier, solvent systems Rhodafac RE-410 emulsifier, solvent-aq. systems Foamphos L-3 Laureth-3 phosphate emulsifier, solvent-based acrylics Ethoxylated trimethylol propane Igepal CA 210... 

A modified latex composition contains a phosphorus surface group. Such a latex is formed by emulsion polymerization of unsaturated synthetic monomers in the presence of a phosponate or a phosphate which is intimately bound to the surface of the latex. Thus, a modified latex containing 46% solids was prepared by emulsion polymerization of butadiene, styrene, acrylic acid-styrene seed latex, and a phosphonate comonomer in H20 in the presence of phosphated alkylphenol ethoxylate at 90°C. The modified latex is useful as a coating for substrates and as a binder in aqueous systems containing inorganic fillers employed in paper coatings, carpet backings, and wallboards [119]. 

Manufacture of highly water-absorbent polymers with uniform particle size and good flowability can be carried out by reverse phase suspension polymerization of (meth)acrylic acid monomers in a hydrocarbon solvent containing crosslinker and radical initiator. Phosphoric acid monoester or diester of alka-nole or ethoxylated alkanole is used as surfactant. A polymer with water-absorbent capacity of 78 g/g polymer can be obtained [240]. 

Gilsonite is active as a fluid loss additive because the permeability of cement is reduced. Latex additives also act as fluid loss additives. They also act as bonding aids, gas migration preventers, and matrix intensifiers. They improve the elasticity of the cement and the resistance to corrosive fluids [921]. A styrene-butadiene latex in combination with nonionic and anionic surfactants shows less fluid loss. The styrene-butadiene latex is added in an amount up to 30% by weight of the dry cement. The ratio of styrene to butadiene in the latex is typically 2 1. In addition, a nonionic surfactant (octylphenol ethoxylate and polyethylene oxide) or an anionic surfactant, a copolymer of maleic anhydride, and 2-hydroxypropyl acrylate [719] can be added in amounts up to 2%. 

When scouring synthetic fibres that are to be dyed with disperse dyes, nonionic scouring agents are best avoided unless they are formulated to have a high cloud point and are known not to adversely affect the dispersion properties of the dyes. Conversely, when scouring acrylic fibres, anionic surfactants should be avoided [156] because they are liable to interfere with the subsequent application of basic dyes. These fibres are usually scoured with an ethoxylated alcohol, either alone or with a mild alkali such as sodium carbonate or a phosphate. 

This disadvantage can be ruled out by spacers between the allylic and the acrylic group [15], but the selectivity in favor of the allylic group is not improved. An acetylenic triple bond instead helps to clarify the situation. 2-Propynoxyethyl acrylate, available in 90 % yield from ethoxylated propargylic alcohol by esterification, is hydrosilylated very smoothly only at the triple bond, leaving the acrylic side virtually untouched (Eq. 5). 

Films of 7 3 mixtures of 1-naphthyl acrylate and ethoxylated bisphenol-A dimethacrylate had better planarizing properties than any of the resins that were examined and may be useful as layers for etchback processing. For use as bottom layers in multilayer-resist structures it will be necessary to bake the films after uv hardening to increase the Tg, and if the exposure wavelength is above 300 nm, an appropriate dye must be added to eliminate substrate reflections that degrade resolution. 

Non-ionic Alkylphenol ethoxylates, long chain alkanol ethoxylates, long chain alkylamine ethoxylates, sorbitan esters and ethoxylates, castor oil ethoxylates, EO/PO copolymers, acrylic copolymers, polysiloxane-polyether copolymers, fluorosilicones... 

Sarac, A. Yildirim, H., 2003, Effect of Initiators and Ethoxylation Degree of Non-Ionic Emulsifiers on Vinyl Acetate and Butyl Acrylate Emulsion Copolymerization in the Loop Reactor. J. Appl. Polym. Sci., 90(2), 537-543. 

Ethoxylated and propoxylated acrylates are highly reactive, yet exhibit less skin irritation. ... 

Ethoxylated Dodecanol Ethoxylated Dodecyl Alcohol Ethoxylated Myristyl Alcohol Ethoxylated Nonylphenol Ethoxylated Pentadecanol Ethoxylated Pentadecyl Alcohol Ethoxylated Tetradecanol Ethoxylated Tetradecyl Alcohol Ethoxylated Tridecanol Ethoxylated Tridecyl Alcohol Ethoxytriethylene Glycol Ethoxy Triglycol Ethyl Acetate Ethylacetic Acid Ethyl Acetoacetate Ethyl Acrylate Ethyl Alcohol Ethyl Aldehyde Ethylaluminum Dichloride Ediylaluminum Sesquichloride Ethylamine Ethylbenzene Ethyl Butanoate Ethyl Butanol 2-Ethyl-1 -Butanol 2-Ethylbutyl Alcohol Ethyl Butyrate... 

Triethylsilyl acrylate can be induced lo undergo hydrolysis of the ethoxyl radicals to a desired extent forming linear or cross linked polymers. Addition polymerization will also lake place on the double bond of the acrylate radical. More stable monomers result from the use of allyl or vinyl groups instead of acrylates. The latter contain a silicon-oxygen-carhon linkage which is always more or less susceptible to hydrolysis. 

Polyalkoxycarboxylales surfaclanls are produced either by Ibe reaction of sodium chloroacetate with an alcohol ethoxylate or from an acrylic ester and an alcohol alkoxylatc. Because of the presence of the ethylene oxide linkages, these products possess a higher aqueous solubility which manifests itself in greater compatibility with cationic surfactants and polyvalent cations. 

Fig. 5. Dependence of the rate of polymerization [Rp/%Conv./min)] in the free-radical emulsion polymerization of butyl acrylate in the presence of PEO-MA macromonomer on emulsifier (E, p-nonyl phenol ethoxylate) concentration [100]. Temp. 50 °C...

Ferguson et al. [52] compared the behavior of a range of conventional alkyl ethoxylate surfactants in emulsion polymerizations with their acrylated analogues. This has allowed a direct comparison of identical surfactant structures, one of which remains kinetically mobile in the resultant lattices, while the other becomes chemically bound to the latex particles. The surfactants chosen for this study were C12 i4-(EO)30 with C12 14-(EO)30-A and C12 14-(EO)12 with C12 14-... 

Ferguson, R, Sherrington, D.C. and Gough, A. (1993) Preparation, characterization and use in emulsion polymerization of acrylated alkyl ethoxylate surface-active monomers. Polymer, 34, 3281-92. 

Preparation of poly(Ethoxylated Fluoroalkyl Acrylate)-Z>/ocA -Polystyrene... 

A reactor containing acrylic acid (305 g), 37.3wt % aqueous sodium acrylate (3204 g), and water (1465g) was treated with ethoxylated (15 EO) trimethylolpropane triacrylate (12.2g), 2,2 -azobisamidinopropane dihydrochloride (0.61 g), and sodium persulfate (3.05 g). The mixture was purged for 30 minutes and further treated with hydrogen peroxide (0.244 g) dissolved in water (5g) and ascorbic acid (0.244 g) also dissolved in water (5g). The mixture was then heated in a thermally insulated mb for about 30 minutes the temperature at the start of the reaction was 113 C. The reaction started after a few minutes and proceeded under adiabatic conditions until the product was isolated and comminuted through a meat grinder equipped with a 6 mm breaker plate. The residue was dried at 80°C under reduced pressure and the produce, was isolated having a sieve fraction of 300 to 600 pm. 

The electrolyte effect of some water-soluble monomers on the cloud point of ethoxylated surfactants is illustrated in Figure 4. In the absence of salt, the cloud point of the emulsifier blend (6 1086 Arlacel 83, HLB = 9.3) is equal to 64°7 ( ). Three monomers-sodium acrylate, MADQUAT - ADQUAT (acryloxyethyltrimethylammonium chloride) - salt the surfactant blend out, the strongest effect being observed with ADQUAT ( 9). 

Alkyl phenol ethoxylates can also react with P4O10 yielding alkyl phenol etherphosphates as a mixture of mono-/diesters or with maleic anhydride to yield maleic acid monoesters, which then react with NaHS03 to yield sulphosuccinate monoesters. Alkylphenolpolyglycolether sulphates, phosphates or sulphosuccinates are mainly used as primary anionic emulsifiers for the manufacturing of acrylic, styrene/acrylic or vinyl acetate co-polymer dispersions. Another type of non-ionic emulsifier is block copolymers of ethylene oxide with propylene oxide. 

CLEAR (Cross-linked ethoxylate acrylate resin) [30]... 

Glycidyl ally ether has been treacted with nonylphenol in the presence of triethylamine at 80°C to give a ring-opened intermediate which after ethoxylation was employed in a polymerisation reaction, assisted by ammonium persulphate, with excess ethyl acrylate at 70°C. The emulsion when coated on glass, dried and briefly cured at 160°C gave a water-resistant film (ref. 26). 

Cross-Linked Ethoxylate Acrylate Resin (CLEAR)... 

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