Allyl propoxylate

Allyl propoxylate monomer can be prepared by reacting allyl alcohol with propylene oxide in the presence of a basic catalyst. The reaction yields a mixture of... [Pg.149]

Table 1 Physical Properties of Allyl Alcohol and Allyl Propoxylate...

Allyl Propoxylate With Average 1.6 Oxypropylene Units... [Pg.150]

Allyl Alcohol And Allyl Propoxylate Homopolymers and Copolymers [9] Homopolymers of allyl alcohol and allyl propoxylate have been prepared by free radical polymerization. It has been found that allyl propoxylate is considerably more reactive than allyl alcx)hol. As showed in Table 2, the homoix)lymerization of allyl propoxylate yields 75% of polymer, while allyl alcohol gives only 28% of polymer under similar polymerization conditions. In the copolymerization of allyl alcohol and allyl propoxylate, the polymer yield increases with the decrease of the ratio of allyl alcohol to allyl propoxylate. [Pg.150]

Poly(allyl propoxylate) is soluble in all of the commonly used solvents listed in the Table 3. Poly(allyl alcohol) is insoluble in most solvents but alcohols. The solubility of the copolymers of allyl alcohol and allyl propoxylate increases with increase of the allyl propoxylate units. The difficulty of preparation of poly(allyl alcohol) and its poor solubility have limited its application, however, poly(allyl propoxylate) has showed increased potential as a highly hydroxyl-fimetionalized polymer. [Pg.150]

Table 2 Allyl Alcohol and Allyl Propoxylate Homopolymers and Copolymers...

Like SAA resins, the water-soluble or water-dispersible terpolymer of allyl propoxylate, styrene and methacrylic acid can be used in water borne polyurethan, melamine, polyester, and many other water borne coatings and thermoset polymers to improve performance. [Pg.152]

Fraction Mass of Fraction, g Mn, By GPC Mole % of Methyl Methacrylate Monomeric Unit Mole % of Allyl Propoxylate Monomeric Unit... [Pg.155]

Safety Allyl alcohol is highly toxic and flammable liquid. It is corrosive to skin and is a severe eye irritant. It is also a high inhalation, skin absorption, and ingestion hazard. It can cause damage to the liver and kidneys, cause lacrimation, tremors, excitability, convulsion, and even coma. Allyl propoxylate has... [Pg.155]

Materials Allyl monopropoxylate and allyl propoxylate with 1.6 of an average oxypropylene unit are development products from Lyondell Chemical Company. Other materials are available from Aldrich. They are used as received. [Pg.156]

Homopolymerization of Allyl Propoxylate The procedure is the same as the Homopolymerization of Allyl Alcohol except allyl propoxylate instead of allyl alcohol is used. [Pg.156]

Copolymerization of Allyl Alcohol and Allyl Propoxylate The procedure is the same as the Homopolymerization of Allyl Alcohol except a mixture of allyl alcohol and allyl propoxylate is used. The comonomer feed composition of allyl alcohol and allyl propoxylate is varied to achieve copolymers of different compositions. [Pg.156]

Copolymerization of Styrene and Allyl Propoxylate The procedure is the same as in Copolymerization of Allyl Alcohol and Styrene except allyl propoxylate instead of allyl alcohol is used. Various styrene and allyl propoxylate copolymers can be made by changing the ratio of styrene to allyl propoxylate. [Pg.157]

Copolymerization of Allyl Propoxylate with Methyl Methacrylate The... [Pg.157]

Copolymerization of Allyl propoxylate, Styrene and Methacrylic Acid 500... [Pg.157]

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