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Water total density

In the CHS model only nearest neighbors interact, and the interactions between amphiphiles in the simplest version of the model are neglected. In the case of the oil-water symmetry only two parameters characterize the interactions b is the strength of the water-water (oil-oil) interaction, and c describes the interaction between water (oil) and an amphiphile. The interaction between amphiphiles and ordinary molecules is proportional to a scalar product between the orientation of the amphiphile and the distance between the particles. In Ref. 15 the CHS model is generalized, and M orientations of amphiphiles uniformly distributed over the sphere are considered, with M oo. Every lattice site is occupied either by an oil, water, or surfactant particle in an orientation ujf, there are thus 2 + M microscopic states at every lattice site. The microscopic density of the state i is p.(r) = 1(0) if the site r is (is not) occupied by the state i. We denote the sum and the difference of microscopic oil and water densities by and 2 respectively and the density of surfactant at a point r and an orientation by p (r) = p r,U(). The microscopic densities assume the values = 1,0, = 1,0 and 2 = ill 0- In close-packing case the total density of surfactant ps(r) is related to by p = Ylf Pi = 1 - i i. The Hamiltonian of this model has the following form [15]... [Pg.721]

Owing to their strong bond on Ru(OOOl), mixed COa 0.55 V, the shift of the equilibrium between water and adsorbed OHad/Oad towards the latter increases the density of the respective species in the intermixed adlayer, which increases the repulsions between the adsorbed species and hence leads to more weakly bound OHad/Oad and COad species. These latter species are less stable against COOHad or CO2 formation, because of the reduced reaction barrier ( Brpnsted-Polanyi-Evans relation [Bronstedt, 1928]), and can support a reaction via (14.9) or (14.12), respectively, at low rates. (Note that the total density of the adlayer does not need to remain constant, although also this is possible.)... [Pg.488]

Figure 2. (a) Density of water oxygens and hydrogens, (b) The water dipole density profile and the associated potential drop, (c) The total charge density profile and the potential drop, as a function of the distance between two parallel slabs of the Pt( 100) surface at T = 300 K. [Pg.129]

A more complex case is the serum lipoprotein (74), shown in Figure 13. When sonicated into water, total lipids from both the low density (/ ) and high density (a) lipoproteins give rise to the high resolution spectra expected of molecules which have a high degree of motion. The spectra of the native lipoproteins show line widths nearly identical to those of the lipids alone, so that no additional motional constraints of the apolar portions of the phospholipids occur when the lipids are bound to the apoproteins of the blood lipoproteins. All the obvious peaks observed in the native lipoproteins can be accounted for by lipid protons, and no upheld shift of the methylene protons occurs. We can conclude that unlike the case of the lysolecithin-serum albumin system, the bonding of lipids to proteins is not apolar. In the serum lipoproteins the NMR results are consistent with a micellar structure and not with extensive apolar association of lipid with protein. [Pg.296]

MW OAREA PTB Q Qa QAO Qo Qw RHOG RHOL RHOW S molecular weight oil cross-section area, ft2 salt in oil at outlet of desalter unit, lb/1000 bbl total flow of emulsified water and oil actual gas flow rate, ft3/s liquid rate, ft3/s crude oil flow rate, dry basis, bpd production water rate, bpd gas or vapor density, lb/ft3 liquid or oil density, lb/ft3 water-phase density lb/ft3 total salt content in the production water and dilution water, lb/day... [Pg.118]

The correlation coefficient is nearly unity in both the cases. It can be seen from Fig. 6a,b that the H-bonded clusters having SE in the range of 5-25 kcal/ mol show three sets of clusters in the electron density region between 0.020 and 0.125e/aQ corresponding to the dimers, trimers, and tetramers, respectively. It is interesting to observe from the linear fit that the total density of the phenol and phenol-water mixed clusters is comparable to that of the water clusters. [Pg.23]

The experiments by Toney and coworkers are very important since they provide at the present time the only direct experimental evidence for the layering of water molecules in the vicinity of metal surfaces. However, they also have been highly controversial because of the extreme increase in density. Simulations show an increase in correlation, not in total density. The discrepancies are probably an indication for specific adsorption or another yet unknown electrode process in the experiments. In the near future another series of experiments will be performed by Ocko and coworkers which will hopefully resolve the controversy. [Pg.25]

Ad 5.1 eV/mol is the H2O dissociation energy. The total chain reaction rate obviously depends on the chain length, which can be numerically estimated as v >= 100 at vibrational temperature 7(, = 0.5 eV and water vapor density [H2O] = 3 10 cm . The total chain reaction rate can be calculated by taking into account both the chain initiation rate (5-115) and the chain length as follows ... [Pg.320]

In this relation, Xj(p, T) = rii/no is the relative concentration (molar fraction for ideal gases) of the i component of the mixture of the H2O dissociation products /, is the total enthalpy of component i no is the total density of the quasi-equilibrium gas mixture. Based on (5-136)-(5-138), the final formula for the calculation of the energy efficiency of water dissociation and hydrogen production in thermal plasma with absolute quenching of the process products can be presented as... [Pg.326]

One of the merits of a water cooled plant is its compactness, i.e., that there is no need for wide cooling channels with a resulting decrease of the total density. The water pipes, as contrasted with the gas channels, reduce rather than increase the migration length of the neutrons. This results in a partial compensation of the decrease in A , as far as the size of the pile is concerned, even at low temperatures. [Pg.284]

The motion of the air implies that the position (x, y, z), of an individual air parcel changes with time. The velocity components in the eastward, northward, and upward directions are then defined asu=dx/dt, v = dy/dt, and w — dz/dt, called the zonal, meridional, and vertical wind components, respectively. In vector form, the velocity is given as V = Ml + D] + wk, where i, j, and k are unit vectors pointing east, north, and up, respectively. The pressure is commonly denoted by p, the total density by p, and the temperature by T. In the course of studying dynamic meteorology many new quantities are introduced and are denoted by new symbols however, they may all be derived from the basic dependentvariables V, p, p, and T. When phase changes of water are important, then Pe (partial density) is an additional variable. [Pg.223]

Fig. 2 Normalized bead density profiles in the direction perpendicular to the air/water interface at T = 338 K. Results for the original Karaborni and Toxvaerd model and the improved force field are shown as solid and dotted lines, respectively. Thf left-hand pair of bead density profiles with a peak at z — 2.4 A are only for the carboxylic headgroups, the right-hand pair of curves are the bead density profiles for the terminal methyl groups, and the shallow curves depict the total density profiles summing over all beads, including the head and tail groups... Fig. 2 Normalized bead density profiles in the direction perpendicular to the air/water interface at T = 338 K. Results for the original Karaborni and Toxvaerd model and the improved force field are shown as solid and dotted lines, respectively. Thf left-hand pair of bead density profiles with a peak at z — 2.4 A are only for the carboxylic headgroups, the right-hand pair of curves are the bead density profiles for the terminal methyl groups, and the shallow curves depict the total density profiles summing over all beads, including the head and tail groups...
Since the densities of alcohol and water differ by only 20%, then one may assume that the total density remains constant such that... [Pg.277]

What is the approximate molarity of a saturated solution of phenol, CsHsOKfor which 87.0 g can be dissolved in 100 ml of water The density of phenol is 1.06 g/cm assume ideal behavior with respect to the total volume of the solution. [Pg.220]

Density is determined by weighing in air, and again totally submerged in water (the density of water =1.0 g/mL), or by determining the volume of the body by its displacement of water when submerged. Neither procedure is particularly pleasant for the experimental subject, and considerable precision is necessary in the measurements at 10% of body weight as fat, which is extremely low, density = 1.08 g/mL, while at 50% fat, which is very high, density = 1.00 g/mL. [Pg.176]

These critical curves are a sort of envelope of the two-phase region. At the high temperature side of the curves, the components are completely miscible at all total densities. Above 400 C the rare gases, nitrogen and light alkanes all appear to be miscible with water. Two of the curves have a different character than the others. Benzene-water has a critical curve with a minimum below 300 C at about 200 bar. Thus, dense homogeneous mixtures of water with benzene and other similar aromatic compounds can be obtained relatively easily (10). The curve for H2O-CO2 also proceeds to... [Pg.101]

We have shown [19] that, actually, the amphiphilic C ions only are surface active, but their interfacial density depends on the nature of the counter ion. Indeed, the structure of the Pi ion is very similar to the nitrobenzene molecules and the partition coefficient of CiePi Pwater is about 10 times larger than this of C15CI. Thus for the same water total concentration, there are two very different distributions of C (figure 5) [20]. Now, the... [Pg.238]

The proton transfer reaction selected for smdy is the diffusion of a hydroxide ion in a solution of methanol in water (pH 7). The model contains a methanol molecule dissolved in a cubic periodic water box of 15 A side containing 112 water molecules and one (Na, OBT) dissociated ion pair. This gives a total density of 1.03 kg/L and an ajjproximate pH around 13.3. [Pg.79]

We next consider vibrational relaxation at the interface between water and an immiscible liquid. Though total density remains relatively constant on transferring the solute from bulk water across the interface, the change in the hydration shell structure produces a change in the vibrational lifetime that follows the same principle discussed above, namely, that an ionic solute is able to keep its hydration shell. This principle manifests itself in the increase in surface roughness on ion transfer across the liquid/liquid interface, as noted earlier. [Pg.257]

Boundary conditions were set as follows room temperature of 293 K (20°C) in each part of the facility and atmospheric pressure of 1 bar. The level in the pools is at the elevation of 10 m, which is the equivalent of 2.85 m measured from the bottom of the pool. The initial velocity of the fluid is 0 m/s everywhere in the facility. The input heating power was 99 kW in equal radial distribution in the 3 heated channels of the core. Upper plenum was filled with water totally. Table II shows the performed scenarios and status of the isolation valves. The initial condition of the experiments did not fully correspond the condition of the reference reactor in a LOCA situation after the depressurization period. The initial temperature is close to room temperature when density differences, which create the natural circulation, doesn t exist yet. [Pg.178]

Cholesterol is biosynthesized in the liver trans ported throughout the body to be used in a va riety of ways and returned to the liver where it serves as the biosynthetic precursor to other steroids But cholesterol is a lipid and isn t soluble in water How can it move through the blood if it doesn t dis solve in if The answer is that it doesn t dissolve but IS instead carried through the blood and tissues as part of a lipoprotein (lipid + protein = lipoprotein) The proteins that carry cholesterol from the liver are called low density lipoproteins or LDLs those that return it to the liver are the high-density lipoproteins or HDLs If too much cholesterol is being transported by LDL or too little by HDL the extra cholesterol builds up on the walls of the arteries caus mg atherosclerosis A thorough physical examination nowadays measures not only total cholesterol con centration but also the distribution between LDL and HDL cholesterol An elevated level of LDL cholesterol IS a risk factor for heart disease LDL cholesterol is bad cholesterol HDLs on the other hand remove excess cholesterol and are protective HDL cholesterol IS good cholesterol... [Pg.1096]

Dichloroacetic acid [79-43-6] (CI2CHCOOH), mol wt 128.94, C2H2CI2O2, is a reactive intermediate in organic synthesis. Physical properties are mp 13.9°C, bp 194°C, density 1.5634 g/mL, and refractive index 1.4658, both at 20°C. The Hquid is totally miscible in water, ethyl alcohol, and ether. Dichloroacetic acid K = 5.14 X 10 ) is a stronger acid than chloroacetic acid. Most chemical reactions are similar to those of chloroacetic acid, although both chlorine... [Pg.88]


See other pages where Water total density is mentioned: [Pg.45]    [Pg.131]    [Pg.30]    [Pg.134]    [Pg.392]    [Pg.52]    [Pg.465]    [Pg.52]    [Pg.260]    [Pg.233]    [Pg.250]    [Pg.848]    [Pg.162]    [Pg.448]    [Pg.341]    [Pg.10]    [Pg.583]    [Pg.572]    [Pg.93]    [Pg.148]    [Pg.1643]    [Pg.2617]    [Pg.217]    [Pg.335]    [Pg.179]    [Pg.5]    [Pg.15]    [Pg.389]   
See also in sourсe #XX -- [ Pg.250 ]




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