Ventilation materials

Lignocellulosics reach temperatures around 80 C in many ways besides. For example, planer shavings and peat insulation around hot pipes or in walls of dry kilns easily attain 100 C, and forest product industries stack still hot wood-base panels at temperatures around 80 C. In many cases the temperatures of the hot materials later on rose above the initial 80 or 100"C, first to levels of smoldering combustion, and finally to those of open flames. In air-exposed and ventilated materials oxidation could cause the heating above 80 or 100 C, but inside tight packs of panels pyrolysis must have been the heat source. 

Carbasalate calcium is a relatively unstable solid active substance, as it degrades through hydrolysis in the presence of moisture. Upon degradation, salicylic acid and acetic acid are formed. The latter can be smelt in very low quantities. To prevent patients becoming needlessly worried, carbasalate calcium powders should be packaged in lightly ventilating material such as paper. 

Care must be taken in handling radon, as with other radioactive materials. The main hazard is from inhalation of the element and its solid daughters which are collected on dust in the air. Good ventilation should be provided where radium, thorium, or actinium is stored to prevent build-up of the element. Radon build-up is a health consideration in uranium mines. Recently radon build-up in homes has been a concern. Many deaths from lung cancer are caused by radon exposure. In the U.S. it is recommended that remedial action be taken if the air in homes exceeds 4 pCi/1. 

The following cautions should be observed Do not destroy or remove inhibitor. Do not contaminate with alkaline or strongly acidic materials. Do not store in the presence of a water layer. In the event of spillage or misuse that cause a release of product vapor to the atmosphere, thoroughly ventilate the area, especially near floor levels where vapors will collect. 

Transportation. Ammonium nitrate is safely transported by rad, road, and water. However, its transportation on U.S. navigable waterways is restricted. Good ventilation must be provided and precautions taken against leakage and contamination. The material must be completely isolated from other cargo and must be kept free of extraneous combustible materials. 

Titanium trifluoride can be stored in tightly closed polyethylene containers for several years. Shipping regulations classify the material as a corrosive sohd and it should be handled in a fully ventilated area or in a chemical hood. The ACGIH adopted toxicity values (1992—1993) for TiF is as TWA for fluorides as F 2.5 mg/m. ... 

A typical large three-phase ferroalloy furnace using prebaked carbon electrodes is shown in Eigure 4. The hearth and lower walls where molten materials come in contact with refractories are usually composed of carbon blocks backed by safety courses of brick. In the upper section, where the refractories are not exposed to the higher temperatures, superduty or regular firebrick may be used. The walls of the shell also may be water-cooled for extended life. Usually, the furnace shell is elevated and supported on beams or on concrete piers to allow ventilation of the bottom. When normal ventilation is insufficient, blowers are added to remove the heat more rapidly. The shell also may rest on a turntable so that it can be oscillated slightly more than 120° at a speed equivalent to 0.25—1 revolution per day in order to equalize refractory erosion or bottom buildup. 

Options. Traditional control options for overexposure are material substitution, process change, containment, enclosure, isolation, source reduction, ventilation, provide personal protection, change work practices, and improve housekeeping. A simple way of looking at selection of control options is to find the cheapest option that results in the desired amount of exposure reduction. It is not actually that simple, however, because the various options differ in ways other than cost and degree of control. Some of the other factors to consider in selection of control options are operabiUty, rehabiUty, and acceptabihty. 

Personnel involved in the handling of methanol require eye and skin protection from the irritating properties of methanol in the event of a spill. Contact lenses should not be worn, since plastic lens materials may absorb and concentrate methanol against the eye. Additional respiratory protection is not required with adequate local explosion-proof ventilation. 

Dry oxahc acid is packed and sold in polyethylene-lined, multilayered 25-kg paper bags or in polyethylene-lined 300—600-kg PVC flexible containers. It should be stored in a cool, dry, ventilated place. For storage of its solutions at ordinary temperature, 316 stainless steel is often used as a constmction material. 

Health and Safety Factors. Terephthahc acid has a low order of toxicity. Inhalation by rats for 6 h/d, 5 d/wk for 4 wk produced no fatahties at a dust exposure level of 25 mg/m. The mean acute oral toxicity for rats is over 18 g/kg (86), and for mice over 6 g/kg (87). When terephthahc acid was fed as 3% of the diet to rats, urinary calcuh formed in 90 d, some of which led to cancer. High doses of terephthahc acid lead to formation of calcium terephthalate at levels exceeding its solubihty in urine. This insoluble material leads to the calcuh and provides a threshold below which cancer is not observed (88). Normal precautions used in handling industrial chemicals should be observed with terephthahc acid. If ventilation is inadequate, a toxic-dust respirator should be used to avoid prolonged exposure. 

Eor toxic materials, it usually is advisable to provide ventilated sampling hoods or breathing-air stations and masks, to assure that the sampler is adequately protected from toxic or flammable vapors and dusts. Special provision for access to and exit from sampling points also may be needed at elevated locations and to avoid tripping or bumping ha2ards and to ensure that the sampler does not transverse areas not intended as walkways, eg, tank covers or roofs. 

---