Sulfur dioxide: analysis

Single-Bed Isothermal Catalysts. Detailed analyses of exit gases from single-bed isothermal catalysts were determined with 2 g of red bauxite at 475°C. The inlet gas contained 3.4% sulfur dioxide, 5.9% carbon monoxide, and 90.7% helium. Figure 2 (Section A) shows that the sulfur dioxide analysis decreased from 3.4 to 0.8. In other words, about 76% of the sulfur dioxide was removed in the dry state at a carbon monoxide ratio, r, of 0.87. However, when 3% water vapor was added (Section B), the sulfur dioxide in the exhaust gas increased to 1.9%, illustrating the poisoning effect of water. When water vapor flow was stopped, the sulfur dioxide exhaust analyses decreased slowly (Section... 

When performed manually, the West-Gaeke method for sulfur dioxide analysis is cumbersome and complicated. However, the method has been refined to the point that it can be done automatically with continuous-monitoring equipment. A block diagram of such an analyzer is shown in Figure 18.17. 

Another important example of a redox titration for inorganic analytes, which is important in industrial labs, is the determination of water in nonaqueous solvents. The titrant for this analysis is known as the Karl Fischer reagent and consists of a mixture of iodine, sulfur dioxide, pyridine, and methanol. The concentration of pyridine is sufficiently large so that b and SO2 are complexed with the pyridine (py) as py b and py SO2. When added to a sample containing water, b is reduced to U, and SO2 is oxidized to SO3. 

Reference methods for criteria (19) and hazardous (20) poUutants estabHshed by the US EPA include sulfur dioxide [7446-09-5] by the West-Gaeke method carbon monoxide [630-08-0] by nondispersive infrared analysis ozone [10028-15-6] and nitrogen dioxide [10102-44-0] by chemiluminescence (qv) and hydrocarbons by gas chromatography coupled with flame-ionization detection. Gas chromatography coupled with a suitable detector can also be used to measure ambient concentrations of vinyl chloride monomer [75-01-4], halogenated hydrocarbons and aromatics, and polyacrylonitrile [25014-41-9] (21-22) (see Chromatography Trace and residue analysis). 

Commercial boron trifluoride is usually approximately 99.5% pure. The common impurities are air, siUcon tetrafluoride, and sulfur dioxide. An excellent procedure for sampling and making a complete analysis of gaseous boron trifluoride has been developed (57). 

A method suitable for analysis of sulfur dioxide in ambient air and sensitive to 0.003—5 ppm involves aspirating a measured air sample through a solution of potassium or sodium tetrachloromercurate, with the resultant formation of a dichlorosulfitomercurate. Ethylenediaminetetraacetic acid (EDTA) disodium salt is added to this solution to complex heavy metals which can interfere by oxidation of the sulfur dioxide. The sample is also treated with 0.6 wt % sulfamic acid to destroy any nitrite anions. Then the sample is treated with formaldehyde and specially purified acid-bleached rosaniline containing phosphoric acid to control pH. This reacts with the dichlorosulfitomercurate to form an intensely colored rosaniline—methanesulfonic acid. The pH of the solution is adjusted to 1.6 0.1 with phosphoric acid, and the absorbance is read spectrophotometricaHy at 548 nm (273). 

Assay of hydrogen cyanide can be done by specific gravity or silver nitrate titration. Sulfur dioxide in hydrogen cyanide can be deterrnined by infrared analysis or by reaction of excess standard iodine solution and titration, using standard sodium thiosulfate or by measurement of total acidity by... 

Sulfur Dioxide EPA Method 6 is the reference method for determining emissions of sulfur dioxide (SO9) from stationary sources. As the gas goes through the sampling apparatus (see Fig. 25-33), the sulfuric acid mist and sulfur trioxide are removed, the SO9 is removed by a chemical reaction with a hydrogen peroxide solution, and, finally, the sample gas volume is measured. Upon completion of the rim, the sulfuric acid mist and sulfur trioxide are discarded, and the collected material containing the SO9 is recovered for analysis at the laboratory. The concentration of SO9 in the sample is determined by a titration method. 

From the commencement of the fog and low visibility, many people experienced difficulty breathing, the effects occurring more or less simultaneously over a large area of hundreds of square kilometers. The rise in the number of deaths (Fig. 18-4) paralleled the mean daily smoke and sulfur dioxide concentrations daily deaths reached a peak on December 8 and 9, with many of them related to respiratory troubles. Although the deaths decreased when the concentrations decreased, the deaths per day remained considerably above the pre-episode level for some days. Would most of the persons who died have died soon afterward anyway If this were the case, a below-normal death rate would h ve occurred following the episode. This situation did not seem to exist, but detailed analysis was complicated by increased deaths in January and February 1953 which were attributed primarily to an influenza outbreak. 

For sources having a large component of emissions from low-level sources, the simple Gifford-Hanna model given previously as Eq. (20-19), X = Cqju, works well, especially for long-term concentrations, such as annual ones. Using the derived coefficients of 225 for particulate matter and 50 for SO2, an analysis of residuals (measured minus estimated) of the dependent data sets (those used to determine the values of the coefficient C) of 29 cities for particulate matter and 20 cities for SOj and an independent data set of 15 cities for particulate matter is summarized in Table 20-1. For the dependent data sets, overestimates result. The standard deviations of the residuals and the mean absolute errors are about equal for particulates and sulfur dioxide. For the independent data set the mean residual shows... 

Intramolecular cyclization of sulfonyl radicals is almost absent from literature. The fact that free radical cyclization has been the subject of a large number of studies and applications in the last decade in organic chemistry48 and that sulfonyl radicals add quickly to multiple bonds (vide infra) makes cyclization of sulfonyl radicals a rather attractive area. Recently, Johnson and Derenne49 studied the reaction of 6-methylhept-5-en-2-ylcobaloxime(III) with sulfur dioxide and, based on the product analysis, they suggested reaction 15 to be an intermediate step. 

The network is implemented by the participating countries through WHO. Sulfur Dioxide (SO,) and suspended particulate matter (SPN) data are routinely reported from each of the participating countries to WHO for entry into the global data base, which is maintained by the United States Environmental Protection Agency (U.S. EPA) at Research Triangle Park, North Carolina. Methods of collection and analysis varies by country. SPN is reported either as a gravimetric or a photometric (transmittance or reflectance) measurement converted to mass units. Since the accuracy of the conversion of the photometric measurement to mass units is... 

This is one source of acid rain, a serious environmental problem. The sulfur dioxide content of an air sample can be determined. A sample of air is bubbled through an aqueous solution of hydrogen peroxide to convert all of the SO2 to H2 SO4. H2 O2 + SO2 H2 SO4 Titration of the resulting solution completes the analysis (both H atoms of H2 SO4 are titrated). In one such case, the analysis of 1.55 X 10 Lof Los Angeles air gave a solution that required 5.70 mL of 5.96 X 10 M NaOH to complete the titration. Determine the number of grams of SO2 present in the air sample. 

In the wine industry, FTIR has become a useful technique for rapid analysis of industrial-grade glycerol adulteration, polymeric mannose, organic acids, and varietal authenticity. Urbano Cuadrado et al. (2005) studied the applicability of spectroscopic techniques in the near- and mid-infrared frequencies to determine multiple wine parameters alcoholic degree, volumic mass, total acidity, total polyphenol index, glycerol, and total sulfur dioxide in a much more efficient approach than standard and reference methods in terms of time, reagent, and operation errors. 

Hint 1. Although sulfur dioxide and oxygen do not appear to be present in equimolar amounts for several of the data points, you may assume, as Mathur and Thodos did, that they are close enough for the purposes of this qualitative analysis. 

Also, a CL reaction between sulfur dioxide and oxygen atoms was studied by Mulcahy and Williams [124] and proposed for the analysis of sulfur dioxide with a sensitivity of 0.001 ppm. However, a disadvantage of this analysis lies in the difficulty for finding a stable source of oxygen atoms. 

The reactions of sulfides with ROOH give rise to products that catalyze the decomposition of hydroperoxides [31,38-47]. The decomposition is acid-catalyzed, as can be seen from the analysis of the resulting products cumyl hydroperoxide gives rise to phenol and acetone, while 1,1-dimethylethyl hydroperoxide gives rise to 1,1-dimethylethyl peroxide, where all the three are the products of acid-catalyzed decomposition [46-49]. It is generally accepted that the intermediate catalyst is sulfur dioxide, which reacts with ROOH as an acid [31,46-50]. 

Heating pure TBMS, TBS and TBSS films at 130 C gave no volatile products. Pyrolysis at 725°C gave rise to both deprotection (as determined by the evolution of isobutene and carbon dioxide), and depolymerization to afford the respective monomers, sulfur dioxide, 4-hydroxystyrene, or 4-hydroxy-a-methylstyrene. The compounds, 4-hydroxystyrene and 4-hydroxy-a-methylstyrene, were identified on the basis of their mass spectra, which were consistent with those reported in the literature for these materials (22,23). Additionally, TGA analysis confirmed that all three polymers undergo complete volatilization upon heating to >400 C. 

Many of the undesirable substances present in gaseous or liquid streams form volatile weak electrolytes in aqueous solution. These compounds include ammonia, hydrogen sulfide, carbon dioxide and sulfur dioxide. The design and analysis of separation processes involving aqueous solutions of these materials require accurate representation of the phase equilibria between the solution and the vapor phase. Relatively few studies of these types of systems have been published concerning solutions of weak electrolytes. This paper will review the methods that have been used for such solutions and, as an example, consider the alkanolamine solutions used for the removal of the acid gases (H2S and C02) from gas streams. 

A dramatic departure of ozone measurements from total oxidant measurements has b Mi reported for the Houston, Texas, area. Side-by-side measurements suggested that either method was a poor predictor of the other. Consideration was given to known interferences due to oxides of nitrogen, sulfur dioxide, or hydrogen sulfide, and the deviations still could not be accounted for. In the worst case, the ozone measurements exceeded the national ambient air quality standard for 3 h, and the potassium iodide instrument read less than 15 ppb for the 24-h period. Sulfur dioxide was measured at 0.01-0.04 ppm throughout the day. Even for a 1 1 molar influence of sulfur dioxide, this could not explain the low oxidant values. Regression analysis was carried out to support the conclusion that the ozone concentration is often much higher than the nonozone oxidant concentration. 

Saltzman, B. E., and A. F. Wartburg, Jr. Absorption tube fm removal of interfering sulfur dioxide in analysis of atmospheric oxidant. Anal. Chem. 37 779-782, 1965. 

The dependence of the local and average transfer coefficients on the square root of the average airflow rate is supported by the experimental data and analysis of Aharonson et al. for ozone, acetone, ether, and sulfur dioxide. 

Further studies are needed to give better dose-response information and to provide a frequency distribution of the population response to oxidants alone and in combination with other pollutants at various concentrations. Such studies should include the effects of mixed pollutants over ranges corresponding to the ambient atmosphere. With combinations of ozone and sulfur dioxide, the mixture should be carefully characterized to be sure of the effects of trace pollutants on sulfate aerosol formation. The design of such studies should consider the need to use the information for cost-benefit analysis and for extrapolation from animals to humans and from small groups of humans to populations. Recent research has indicated the possibility of human a ptation to chronic exposure to oxidants. Further study is desirable. 

Mulik, J. D., Todd, G Estes, E., Puckett, R Sawicki, E., Ion Chromatographic Determination of Atmospheric Sulfur Dioxide. Ion Chromatographic Analysis of Environmental Pollutants. Edited by Sawicki, E., Mulik, f. D., Wittgenstein, E., Ann Arbor Science Publishers, Ann Arbor, MI (1978). 

Cole JE, Fairbanks RG, Shen GT (1993) The spectrum of recent variability in the southern oscillation results from a Tarawa atoll. Science 260 1790-1793 Coleman ML, Moore MP (1978) Direct reduction of sulfates to sulfur dioxide for isotope analysis. Anal Chem 50 1594-1595... 

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