Single layers

L. Bar, G.M. Daalmans, R BartheL, L. Feichland, M. Selent, M. Kiilml, D. Uhl Single layer and integrated YBCO gradtometer coupled SQLJIDs Supercond. Sci. TechnoL 9 (1996) A87-A91... 

The basic assumption is that the Langmuir equation applies to each layer, with the added postulate that for the first layer the heat of adsorption Q may have some special value, whereas for all succeeding layers, it is equal to Qu, the heat of condensation of the liquid adsorbate. A furfter assumption is that evaporation and condensation can occur only from or on exposed surfaces. As illustrated in Fig. XVII-9, the picture is one of portions of uncovered surface 5o, of surface covered by a single layer 5, by a double-layer 52. and so on.f The condition for equilibrium is taken to be that the amount of each type of surface reaches a steady-state value with respect to the next-deeper one. Thus for 5o... 

Molecular adsorbates usually cover a substrate with a single layer, after which the surface becomes passive with respect to fiirther adsorption. The actual saturation coverage varies from system to system, and is often detenumed by the strength of the repulsive interactions between neighbouring adsorbates. Some molecules will remain intact upon adsorption, while others will adsorb dissociatively. This is often a frinction of the surface temperature and composition. There are also often multiple adsorption states, in which the stronger, more tightly bound states fill first, and the more weakly bound states fill last. The factors that control adsorbate behaviour depend on the complex interactions between adsorbates and the substrate, and between the adsorbates themselves. 

Fig. 7. Schematic of light emitting diodes (a) single-layer device (b) single heteiostmctuie (c) double heteiostmctuie.

Single layer OLEDs have been fabricated with a variety of emitter molecules and conjugated polymers such as poly(phenylene vinylene) (PPV). 

Fig. 10. Typical design for single-layer photovoltaic device.

Sound-Isolating Constructions. Although some materials are used alone in single-layer constmctions for sound-isolating purposes, most sound-isolating constmctions contain two or more parts, frequentiy separated by an airspace. 

The similarity of M0S2 to graphite has been noted. Like elemental carbon, which has been found to form nanotubular stmctures, M0S2 has also been found to form nested stmctures upon exposure to the electron beam in an electron microscope (23). Moreover, M0S2 displays a variety of intercalation reactions typical of layered materials. Single-layer M0S2 has been successfully prepared and manipulated (22). 

Antireflection coatings are used over the silicon surface which, without the coating, reflects ca 35% of incident sunlight. A typical coating consists of a single layer of a transparent dielectric material with a refractive index of ca 2, which is between the index of siUcon and ait or cover material. Materials such as titanium dioxide, tantalum pentoxide, Ta20, or siUcon nitride, Si N, ca 0.08-p.m thick are common. The coating and a physically textured... 

In most coatiag operatioas a single layer is coated. Whea more than one layer must be appHed one can make multiple passes, or use tandem coaters where the next layer is appHed at another coatiag statioa ioimediately foUowiag the dryer sectioa for the previous layer, or a multilayer coatiag statioa can be used. Slot, extmsion, sHde, and curtain coaters are used to apply multiple layers simultaneously. SHde and curtain coaters can apply an unlimited number of layers simultaneously, whereas slot and extmsion coaters are limited by the complexity of the die internals. 

Fig. 2. Schematics of (a) single-layer photoreceptor, where the + signs represent the corona-deposited charge, D the photoconductor, and 1 the conductive substrate and (b), the CdS Sej (Katsuragawa) photoreceptor, where D represents the insulating layer, the CdS Sej, and I the...

Blown film is made similarly to blow-molded articles the molten resia is extmded coatiauously as a parisoa, which is blowa to form a coatiauous film cyliader. This cyliader can be roUed up as a two-layer stmcture or sHt to form one large or two smaller single layers. 

FIG. 25-17 Schematic flowsheet illustrating the individual elements of an open, single-layer hiofilter system. Particulate filtration and/or temperature adjustment is often combined with the equipment to adjust gas humidity content. 

In moving catalyst basket reactors, the flow regime is ill-defined and the contact between catalyst and gas can be poor even if well-mixed conditions for the fluid phase are achieved. Perhaps the most successful representative of this category is the Carberry reactor (1964, 1966). Even in this model only a single layer of catalyst can be charged in the cruciform catalyst basket because the fluid flows in a radial direction outward and... 

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