Residues from production

V. E. Ignateva, A. G. Telin, N. I. Khisamutdinov, S. V. Safronov, V. N. Artemev, and Y. A. Ermilov. Composition for oil extraction—contains hydrocarbon- or alcohol-containing solvent, water and vat residue from production of glycerine or ethylene glycol. Patent RU 2065941-C, 1996. 

E. A. Konovalov, Y. A. Ivanov, T. N. Shumilina, V. F. Pichugin, and N. N. Komarova. Lubricating reagent for drilling solutions—contains agent based on spent sunflower oil, water, vat residue from production of oleic acid, and additionally water glass. Patent SU 1808861-A, 1993. 

Organic agriculture aims to eliminate residues from production systems, rather than meeting maximum permissible values. Owing to the risks of contamination being introduced onto farms from external sources (e.g. with feed, via air pollution and/or irrigation water) and with greater accuracy of pollution measurement/detection systems, this aim appears to be more and more difficult to achieve. 

Nowadays the electronic appliances used for entertainment, telecommunications and data processing are widespread in daily life. Typical examples include televisions, video recorders, hi-fi systems and fax machines, not to mention computers with their peripherals such as monitors and printers, scanners and copiers. These devices are predominantly made of polymeric components and materials which might contain additives, such as flame retardants and plasticizers (Wensing, Uhde and Salthammer, 2005) to obtain specific desired properties. In addition, there will also be chemical residues from production and processing aids, such as residual monomers and solvents. Especially under operating conditions these compounds can be released from electronic equipment into indoor air due to the heating-up of the device interior. In many cases, such emissions can be monitored via simple odor tests (Walpot, 1996). 

Differences in legal requirements limiting emissions and residues from production processes... 

Litsea cubeba oil. Lemon oil washed as residues from production of terpene-free oil is preferably used, as these contain still all components of the pure lemon oil. Also lemon terpenes and heads of distilled grapefruit oils could be found. Blending is done by using synthetic decanal, non-anal, octanal, and citronellal from Corymbia citriodora oil. Detection is made by GC-MS and mainly by multidimensional enantiomeric separation with various methods (see part of methods). Mondello (1998) reports some constituents with chiral ratios as follows (f )-(+)-p-pinene 6.3% (5) ( )-P"pinene 93.7% (f )-(+)-sabinene 14.9% (5)-(-)-sabinene 85.1% (5)-(-)-limonene 1.6% (K) (+)-limonene 98.4% (5)-(+)-terpinen-4-ol 24.7% (/ )-(-)-terpinen-4-ol 75.3% and (5)-( ) a terpineol 75.2% (R)-(+)-a-terpineol 75.2%. Further on, Dugo and Mondello (2011) gave the following data (/ )-(+)-a-pinene (25.5%-31.5%) (5)-(-)- -pinene (68.5%-74.5%) (15,4/ ) ( ) camphene (86.2%-92.4%) (l/ ,45)-(+)-camphene (7.6%-13.8%) (5)-(-)-p-pinene... 

All modern refineries have conversion units, designed to transform black effluent streams into lighter products gas, gasoline, diesel fuel. Among these conversion units, coking processes take place by pyrolysis and push the cracking reaction so far that the residue from the operation is very heavy it is called coke . 

Feedstocks for this very flexible process are usually vacuum distillates, deasphalted oils, residues (hydrotreated or not), as well as by-products from other processes such as extracts, paraffinic slack waxes, distillates from visbreaking and coking, residues from hydrocracking, converted in mixtures with the main feedstock. 

Simple conventional refining is based essentially on atmospheric distillation. The residue from the distillation constitutes heavy fuel, the quantity and qualities of which are mainly determined by the crude feedstock available without many ways to improve it. Manufacture of products like asphalt and lubricant bases requires supplementary operations, in particular separation operations and is possible only with a relatively narrow selection of crudes (crudes for lube oils, crudes for asphalts). The distillates are not normally directly usable processing must be done to improve them, either mild treatment such as hydrodesulfurization of middle distillates at low pressure, or deep treatment usually with partial conversion such as catalytic reforming. The conventional refinery thereby has rather limited flexibility and makes products the quality of which is closely linked to the nature of the crude oil used. 

The product e e is the sum of squares of residuals from the vector of residuals. The vai iance is... 

Add 1 ml. of the alcohol-free ether to 0-1-0-15 g. of finely-powdered anhydrous zinc chloride and 0 5 g. of pure 3 5-dinitrobenzoyl chloride (Section 111,27,1) contained in a test-tube attach a small water condenser and reflux gently for 1 hour. Treat the reaction product with 10 ml. of 1-5N sodium carbonate solution, heat and stir the mixture for 1 minute upon a boiling water bath, allow to cool, and filter at the pump. Wash the precipitate with 5 ml. of 1 5N sodium carbonate solution and twice with 6 ml. of ether. Dry on a porous tile or upon a pad of filter paper. Transfer the crude ester to a test-tube and boil it with 10 ml. of chloroform or carbon tetrachloride filter the hot solution, if necessary. If the ester does not separate on cooling, evaporate to dryness on a water bath, and recrystallise the residue from 2-3 ml. of either of the above solvents. Determine the melting point of the resulting 3 5 dinitro benzoate (Section 111,27). 

The above intermediate (8 g, 0.03 mol) in THF (80 ml) was stirred with Raney nickel (40g) for 2h and then carefully filtered. [CAUTION Raney nickel can ignite during filtrationf Cone. HCl (2 drops) was added to the filtrate and it was evaporated in vacuo. Recrystallization of the residue from 2-propanol gave the product (6,0 g) in 89% yield. 

Properties. The properties of naphtha, gas od, and H-od products from an H-coal operation are given in Table 7. These analyses are for Hquids produced from the syncmde operating mode. Whereas these Hquids are very low in sulfur compared with typical petroleum fractions, they are high in oxygen and nitrogen levels. No residual od products (bp > 540° C) are formed. 

Larch Gum. Larch gum [37320-79-9] (larch arabinogalactan) is obtained by water extraction of the western larch tree, iLarix occidentalism the heartwood of which contains 5—35% on a dry wood basis. In the early 1960s, a countercurrent hot water extraction system was developed, and the gum was produced commercially by the St. Regis Paper Co. under the trade name Stractan. The potential production capacity of this gum is 10,000 t/yr based on the wood residues from the lumber industry. However, the product could not compete with gum arabic, and commercial production is now limited to small batches for a specific medical appHcation. 

Water as coolant in a nuclear reactor is rendered radioactive by neutron irradiation of corrosion products of materials used in reactor constmction. Key nucHdes and the half-Hves in addition to cobalt-60 are nickel-63 [13981 -37-8] (100 yr), niobium-94 [14681-63-1] (2.4 x 10 yr), and nickel-59 [14336-70-0] (7.6 x lO" yr). Occasionally small leaks in fuel rods allow fission products to enter the cooling water. Cleanup of the water results in LLW. Another source of waste is the residue from appHcations of radionucHdes in medical diagnosis, treatment, research, and industry. Many of these radionucHdes are produced in nuclear reactors, especially in Canada. 

If the economics of recycling were improved, that option would become preferable for spent fuel because the permanent repository issues of the residual fission products would be simpler. The economic value of the energy generated from the recycled plutonium and uranium would substantially allay the costs of the repository as compared to the spent fuel throwaway option. 

The wide range of types of paper products results in a variety of sludges. SoHd wastes result from several sources within the mill, eg, bark, sawdust, dirt, knots, pulpwood rejects, flyash, cinders, slag, and sludges. Sludges often are disposed of in combination with residuals from other sources. Approximately 300 kg of soHd waste per ton of finished product is generated by the pulp and paper industry. 

Scrap that is unsuitable for recycling into products by the primary aluminum producers is used in the secondary aluminum industry for castings that have modest property requirements. Oxide formation and dross buildup are encountered in the secondary aluminum industry, and fluxes are employed to assist in the collection of dross and removal of inclusions and gas. Such fluxes are usually mixtures of sodium and potassium chlorides. Fumes and residues from these fluxes and treatment of dross are problems of environmental and economic importance, and efforts are made to reclaim both flux and metal values in the dross. 

Coal tar is the condensation product obtained by cooling to approximately ambient temperature, the gas evolved in the destmctive distillation of coal. It is a black viscous Hquid denser than water and composed primarily of a complex mixture of condensed ring aromatic hydrocarbons. It may contain phenoHc compounds, aromatic nitrogen bases and their alkyl derivatives, and paraffinic and olefinic hydrocarbons. Coal-tar pitch is the residue from the distillation of coal tar. It is a black soHd having a softening point of 30—180°C (86—359°F). 

Wood is one of our most important renewable biomass resources. Unlike most biomass sources, wood is available year round and is more stable on storage than other agricultural residues. In the United States, wood residues from iadustrial by-products totaled 60.8 x 10 metric tons ia 1993 (73). Increasiagly, residues are iacorporated iato manufactured wood products and are used as a fuel, replacing petroleum, especially at wood-iadustry plants (73) some is converted to charcoal but most is used ia the pulp and paper iadustry. Residues are also available for manufacturiag chemicals, generally at a cost equivalent to their fuel value (see Fuels frombiomass Fuels fromwaste). 

Propane Asphalt. As noted above, cmde oils contain different quantities of residuum (Fig. 2) and, hence, asphalt. Asphalt is also a product of the propane deasphalting and fractionation process (5,6,21,22) which involves the precipitation of asphalt from a residuum stock by treatment with propane under controlled conditions. The petroleum charge stock is usually atmospheric-reduced residue from a primary distillation tower. 

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