Relative Humidity RH

Knowing the saturation and the partial water vapour pressure at each time point and place, the relative humidity RH can be calculated using the following equation  

Ps = Saturation vapour pressure Pd = Partial water vapour pressure 

The yearly mean RH values have been obtained by using the yearly mean values for Pd and Ps calculated as described above. 

As the saturation vapour pressure increases with increasing temperature, the relative humidity decreases with increasing temperature at constant partial vapour pressure. As an example, the decrease of the relative humidity with increasing temperature is shown in Fig. 4.1 at a constant Pd of 26.0 hPa. 

This correlation is of importance when the appropriate relative humidity is calculated for stability testing by keeping the mean partial vapour pressure constant and increasing the temperature to the testing temperature of 30°C. 

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Relative Humidity (rh). Relative humidity is the ratio of the mole fraction of water vapor present in the air to the mole fraction of water vapor present in saturated air at the same temperature and barometric pressure it approximately equals the ratio of the partial pressure (or density) of the water vapor in the air to the saturation pressure (or density) of water vapor at the same temperature. 

Since surfactant-type antistats function by attracting atmospheric moisture to the plastic, the relative humidity (rh) has a significant effect on antistat performance (Fig. 6). Relative humidity also has an effect on charge generation (Table 7). 

The water-vapor transmission rate (WVTR) is another descriptor of barrier polymers. Strictly, it is not a permeabihty coefficient. The dimensions are quantity times thickness in the numerator and area times a time interval in the denominator. These dimensions do not have a pressure dimension in the denominator as does the permeabihty. Common commercial units for WVTR are (gmil)/(100 in. d). Table 2 contains conversion factors for several common units for WVTR. This text uses the preferred nmol/(m-s). The WVTR describes the rate that water molecules move through a film when one side has a humid environment and the other side is dry. The WVTR is a strong function of temperature because both the water content of the air and the permeabihty are direcdy related to temperature. Eor the WVTR to be useful, the water-vapor pressure difference for the value must be reported. Both these facts are recognized by specifying the relative humidity and temperature for the WVTR value. This enables the user to calculate the water-vapor pressure difference. Eor example, the common conditions are 90% relative humidity (rh) at 37.8°C, which means the pressure difference is 5.89 kPa (44 mm Hg). 

Here is an equation for relative humidity (RH) and a short BASIC computer program that enhances its value. The average difference between the equation and actual values runs only 0.33 percentage points and the highest absolute difference seen in comparisons w as 2 percentage points. 

PRINT Meaningless Result for % RH. PRINT 210 PRINT USING Relative Humidity, RH =. % RH 220 END... 

An example of interaction stiffness and force curves for a Si surface with a native oxide at 60% relative humidity (RH) is shown in Fig. 12 [104]. The stiffness and force data show an adhesive interaction between the tip and substrate. The hysteresis on retraction is due to a real change in contact area from surface oxide deformation and is not an experimental artifact. The adhesive force observed during retraction was consistent with capillary condensation and the surface energy measured from the adhesive force was close to that of water. 

Critical Humidity—the relative humidity (RH) at and above which the atmospheric corrosion rate of a metal increases significantly. 

Air quality requirements may be set as content of particles and as content of chemical substances. Other requirements for temperature, humidity, and air speed could be set. One example is the spray painting process, which is very dependent on a minimum relative humidity (RH) level to... 

Relative humidity (RH) is the degree of saturation (0-100%) at any dry-bulb temperature. 

For the above polyol blend viscosity (Brookfield, ASTM D-2196) = 1500 mPa-S at 23° C. For the reaction mixture working (pot) life 20 min Gardner circular dry times [72°F, 54% relative humidity (RH)] surface dry = 1.0 h, hard dry = 2.0 h, mar free = 3.5 h. For the finished coating gloss (ASTM D-523) = 90+ at 60° impact (ASTM D-2794) = 60 in.-lb direct, 10 in.-lb reverse Tabor abrasion (ASTMD-4060,1000 g load, 1000cycles, CS-17 wheel) = 95.6 mg pendulum hardness = 180 s MEK double rubs (ASTM D4752-95, 50 double rubs) = softened. 

Only two possibilities exist for explaining the existence of cloud formation in the atmosphere. If there were no particles to act as cloud condensation nuclei (CCN), water would condense into clouds at relative humidities (RH) of around 300%. That is, air can remain supersaturated below 300% with water vapor for long periods of fime. If this were to occur, condensation would occur on surface objects and the hydrologic cycle would be very different from what is observed. Thus, a second possibility must be the case particles are present in the air and act as CCN at much lower RH. These particles must be small enough to have small settling velocity, stay in the air for long periods of time and be lofted to the top of the troposphere by ordinary updrafts of cm/s velocity. Two further possibilities exist - the particles can either be water soluble or insoluble. In order to understand why it is likely that CCN are soluble, we examine the consequences of the effect of curvature on the saturation water pressure of water. 

For a-C H coating, the friction coefficient is strongly influenced by H content in the coating, and by relative humidity (RH). At low humidity, the friction coefficient can be achieved as low as 0.02 [25]. The friction coefficient increases to 0.1 0.15 as the RH rises to 30 % and above. An ultra-low friction coefficient of 0.001 0.005 was reported to be achieved for high hydrogen content a-C H coating in... 

TABLE 1 Processing an Acid-Catalyzed Poly-(ortho ester) Under Different Relative Humidities (RH)... 

FIG. 11 Break-free length (distance B-C on inset) as a function of relative humidity for the clean Si(lOO) wafer (Si), the amorphous carbon film (AC), and the bonded perfluoropolyether film (Z-Dol). The inset depicts two dipping experiments on amorphous carbon, at 0% and 97% relative humidity (rH). (From Ref. 50. Copyright 1994 American Institute of Physics.)... 

In humid environments, the ellipsometry results of Beaglehole and Christenson [71] indicate that a film is formed with an average thickness of 2 A when the relative humidity (RH) is 50%. As discussed earlier, however, the lateral resolution of ellipsometry is limited by the size of the light spot on the sample, typically several tens of micrometers. In addition, thickness values are obtained from the measured changes in polarization angle by... 

FIG. 21 Pull-off force between a hydrophilic Si3N4 tip and mica as a function of the relative humidity (RH) at room temperature. The spring constant of the lever is 0.1 N/m. Estimated tip radius -200 A. Hysteresis is observed between increasing (open circles) and decreasing (closed circles) humidity. (From Ref. 51.)... 

Atmospheric aerosols have a direct impact on earth s radiation balance, fog formation and cloud physics, and visibility degradation as well as human health effect[l]. Both natural and anthropogenic sources contribute to the formation of ambient aerosol, which are composed mostly of sulfates, nitrates and ammoniums in either pure or mixed forms[2]. These inorganic salt aerosols are hygroscopic by nature and exhibit the properties of deliquescence and efflorescence in humid air. That is, relative humidity(RH) history and chemical composition determine whether atmospheric aerosols are liquid or solid. Aerosol physical state affects climate and environmental phenomena such as radiative transfer, visibility, and heterogeneous chemistry. Here we present a mathematical model that considers the relative humidity history and chemical composition dependence of deliquescence and efflorescence for describing the dynamic and transport behavior of ambient aerosols[3]. 

Gaseous sterilization Ethylene oxide (EO) Reactive chemical Indicator paper impregnated with a reactive chemical which undergoes a distinct colour change on reaction with EO in the presence of heat and moisture. With some devices rate of colour development varies with temperature and EO concentration Gas concentration, temperature, time (selected devices) NB a minimum relative humidity (rh) is required for device to function... 

Table II shows, as an example, the combinations of low and high levels for three factors selected by a design team for an accelerated test Involving photovoltaic solar cells. In column 2 the three factors are seen to be temperature T (50 C, 95 C), relative humidity RH (60%, 85%), and ultraviolet radiation UV (five suns, 15 suns). The eight combinations of the high and low levels are shown, together with the predicted months to failure for each combination. In this example the documentation to support each prediction is symbolically referenced as shown in the last column. The documentation includes assumptions, calculations, references to the literature, laboratory data, computer simulation results, and other related material. Such a factorial table is first completed by each scientist independently. Subsequently, the team alms to generate a single consensus factorial table has the same form as that shown in Table II.

Capillary forces increase in relationship to the relative humidity (RH) of the ambient air. At greater than 65% RH, fluid condenses in the space between adjacent particles. This leads to liquid bridges causing attractive forces due to the surface tension of the water. 

A deliquescent material takes up moisture freely in an atmosphere with a relative humidity above a specific, well-defined critical point. That point for a given substance is defined as the critical relative humidity (RH0). Relative humidity (RH) is defined as the ratio of water vapor pressure in the atmosphere divided by water vapor pressure over pure water times 100% [RH = (PJP0) X 100%]. Once moisture is taken up by the material, a concentrated aqueous solution of the deliquescent solute is formed. The mathematical models used to describe the rate of moisture uptake involve both heat and mass transport. 

Figure 11 Vapor pressure profile for a surface relative humidity RH of 40% and chamber RH of 80%, with a diffusion film thickness of 1 cm.

For most practical purposes, however, humidity is expressed as the relative humidity (RH), the percentage of moisture in the air at a given temperature in relation to the amount of moisture that the air could hold at that temperature before condensing as dew. Since the latter amount is dependent on the temperature, the relative humidity is a function of both moisture content and temperature. A value of 50% RH, for example, means that the air holds half the water vapor it can hold at the prevailing temperature. At 100% RH, moisture condenses and falls as rain. The relative humidity is measured with instruments known as a hygrometers. 

Air relative humidity (RH) increases toward the interior, reaching values up to 7 times higher than those at the edge (up to 53% relative humidity (RH)). The differences are significant (H = 5.41 p = 0.048). 

In cellulose II with a chain modulus of 88 GPa the likely shear planes are the 110 and 020 lattice planes, both with a spacing of dc=0.41 nm [26]. The periodic spacing of the force centres in the shear direction along the chain axis is the distance between the interchain hydrogen bonds p=c/2=0.51 nm (c chain axis). There are four monomers in the unit cell with a volume Vcen=68-10-30 m3. The activation energy for creep of rayon yarns has been determined by Halsey et al. [37]. They found at a relative humidity (RH) of 57% that Wa=86.6 kj mole-1, at an RH of 4% Wa =97.5 kj mole 1 and at an RH of <0.5% Wa= 102.5 kj mole-1. Extrapolation to an RH of 65% gives Wa=86 kj mole-1 (the molar volume of cellulose taken by Halsey in his model for creep is equal to the volume of the unit cell instead of one fourth thereof). 

The utilization of IR spectroscopy is very important in the characterization of pseudopolymorphic systems, especially hydrates. It has been used to study the pseudopolymorphic systems SQ-33600 [36], mefloquine hydrochloride [37], ranitidine HC1 [38], carbovir [39], and paroxetine hydrochloride [40]. In the case of SQ-33600 [36], humidity-dependent changes in the crystal properties of the disodium salt of this new HMG-CoA reductase inhibitor were characterized by a combination of physical analytical techniques. Three crystalline solid hydrates were identified, each having a definite stability over a range of humidity. Diffuse reflectance IR spectra were acquired on SQ-33600 material exposed to different relative humidity (RH) conditions. A sharp absorption band at 3640 cm-1 was indicative of the OH stretching mode associated with either strongly bound or crystalline water (Fig. 5A). The sharpness of the band is evidence of a bound species even at the lowest levels of moisture content. The bound nature of this water contained in low-moisture samples was confirmed by variable-temperature (VT) diffuse reflectance studies. As shown in Fig. 5B, the 3640 cm-1 peak progressively decreased in intensity upon thermal... 

When stored under increasing relative humidities (RH), cromolyn sodium absorbed water, resulting in a continuous series of interstitial solid solutions [11]. The amount of water absorbed was proportional to the relative humidity of the environment and could be up to about nine molecules of water per molecule of drug. Such an unusual system was characterized by combining XPD with single-crystal x-ray studies. The unit cell parameters of cromolyn sodium were obtained from single-crystal x-ray studies, and this permitted the authors to index the powder pattern. The b axis spacing was found to increase dramatically as a function of the relative humidity up to 20% RH (Table 2). Above 40% RH, the unit cell dimensions were nearly constant. 

The range of application of shear cell testing methodology is seen in Tables 2-6. Table 3 relates the flow properties of mixtures of spray-dried lactose and bolted lactose. These mixtures, in combination with the excipients tested, cover a broad range of flow. Tables 4 and 5, for example, show lot to lot variations in the flow properties of several materials, and Table 6 shows the variation in flow properties of bolted starch, sucrose, and phenacetin at different relative humidities (RH). Figure 8 presents the yield loci of sucrose at four different consolidation loads. Also shown in the figure are the shear indices determined at each consolidation load. 

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