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Reactions with Radicals

Reactions with Radicals and Electron-deficient Species, Reactions at Surfaces... [Pg.40]

Reaction with radicals and electron-deficient species reaction at surfaces... [Pg.167]

Reactions with Radicals S.06.3.7.1 Radical attack on sulfur... [Pg.166]

The thermal decompositions described above are unimolecular reactions that should exhibit first-order kinetics. Under many conditions, peroxides decompose at rates faster than expected for unimolecular thermal decomposition and with more complicated kinetics. This behavior is known as induced decomposition and occurs when part of the peroxide decomposition is the result of bimolecular reactions with radicals present in solution, as illustrated below specifically for diethyl peroxide. [Pg.672]

The ability of carotenoids to act as antioxidants is closely related to their long-chain conjugated polyene structures (see Section 2.2 in Chapter 2). Two main types of antioxidant actions can be distinguished singlet oxygen quenching and reactions with radicals. The first mechanism occurs in vivo in plants and has been extensively studied in vitro. Reactions with radicals of different types have also been extensively studied in vitro under different conditions but their occurrence in vivo is still a matter of discussion. [Pg.178]

Reactions with Radicals and Electron-Deficient Species Reactions at Surfaces 494... [Pg.487]

The only significant reactions that have appeared regarding this section involve reducing agents. For additional information on reactions with radicals and electron-deficient species, refer to CHEC(1984) <1984CHEC(6)513> and CHEC-II(1996) <1996CHEC-II(4)355>. [Pg.529]

Reaction with Radicals and Cyclic Transition States 581... [Pg.567]

Although reactions with radicals to give formaldehyde and another product could be included, they would have only a very minor role. They have large rate constants, but concentration factors in reacting systems keep these rates slow. [Pg.115]

The radical scavenging methods require the general caution that the stoichiometry of the reaction between scavenger and radical must be established. A problem with some scavengers is that their reaction with radicals may not be quantitative. The DPPH radical is an extremely efficient scavenger in many systems. It completely stops vinyl acetate and styrene polymerizations even at concentrations below 10 4M [Bartlett and Kwart, 1950]. However, the scavenging effect of DPPH is not universally quantitative for all monomers. [Pg.234]


See other pages where Reactions with Radicals is mentioned: [Pg.157]    [Pg.166]    [Pg.1284]    [Pg.268]    [Pg.591]    [Pg.610]    [Pg.612]    [Pg.622]    [Pg.132]    [Pg.915]    [Pg.915]    [Pg.52]    [Pg.246]    [Pg.551]    [Pg.551]    [Pg.560]    [Pg.563]    [Pg.782]    [Pg.699]    [Pg.732]    [Pg.809]    [Pg.90]    [Pg.89]    [Pg.293]    [Pg.224]   
See also in sourсe #XX -- [ Pg.901 ]




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1- Alkylimidazoles, reaction with alkyl radicals

1- Methyl pyridine reaction with radicals

2 -deoxyguanosine reaction with hydroxyl radical

Acetaldehyde reaction with hydroxyl radicals

Acetic acid anhydride, reaction with radical

Acetylene, reaction with hydroxyl radicals

Acrylate esters reaction with radicals

Acrylates reaction with radicals

Addition Reactions of Radicals with Substituted Alkenes

Alcohols reaction with hydroxyl radical

Aliphatic carbon-centered radicals reaction with transition metal

Alkanes reaction with radicals

Alkene radical cations, kinetics nucleophiles, reaction with

Alkenes reactions with hydroxyl radical

Alkenes reactions with nitrate radical

Alkenes reactions with peroxy radicals

Alkenes, radical halogenation reaction with peroxides

Alkenes, reaction with acyl radicals

Alkoxy radicals reaction with

Alkoxy radicals reactions with oxygen

Alkoxyl radical reactions with nitrogen

Alkoxyl radical reactions with oxygen

Alkoxyl radical, reaction with nitric oxide

Aminyl radicals reaction with

Ammonia radical, reaction with nitric

Ammonia radical, reaction with nitric oxide

Anion radical reactions with organic

Aromatic amines reactions with carbonate radical

Aromatic amines reactions with hydroxyl radical

Aromatic hydrocarbons reactions with nitrate radical

Aryl radicals reaction with monomers

Benzyl radical reaction with

Benzyl radicals reaction with nitroxides

Boranes radical reactions with

CH3O with radicals, reactions

CH3O2 with radicals, reactions

CIO radical reaction with

CYCLIZATION, free radical 2+2] Cycloaddition reactions, with

Carbon monoxide, reaction with hydroxyl radicals

Carbon-centered alkyl radicals reaction with

Carbon-centered radical, reactions with silicon hydrides

Carbon-hydrogen bonds radical reaction with

Carbonates reaction with hydroxyl radical

Carbonyl radicals, reaction with nitric

Carbonyl radicals, reaction with nitric oxide

Carboxylic acids hydroxyl radical reactions with

Cyanoisopropyl radicals reaction with monomers

Cyclopropanes reaction with radicals

Dimethyl sulfoxide hydroxyl radical, reaction with

Double bonds radical reactions with

Electron transfer reaction, radicals with

Electron transfer reaction, radicals with diphenyliodonium salts

Electron-Transfer Reactions with Participation of Ion-Radical Aggregates

Ethers, vinyl reaction with radicals

Ethylene reaction with methyl radicals

Fluoro-olefins reaction with radicals

Formaldehyde reaction with hydroxyl radicals

Formation of radical-ions and their reaction with monomers

Free Radical Reactions with DNA

Free radical reactions with pepsins

Free radical reactions, competition with

Free radicals oxidizing agents, reaction with

Free radicals, reaction with hydrogen, specific

Free-Radical Grafting Reactions to Polymers with Double Bonds

Free-radical reaction with alcohols

Fullerene reactions with radicals

Group 14 elements reactions with radical

HO2 radical reaction with

HOCO radical reaction with

Halides reaction with radical anions

Halides reaction with radical ions

Halo-olefins reaction with radicals

Halogens reaction with radicals

Heterocycles, acylation radical reaction with

Hydrogen atom, free-radical transfer reactions with

Hydrogen, reaction with hydroxyl radicals

Hydroperoxy radical, reaction with

Hydroxamates, O-acyl thiocarboxyl radicals from reaction with tris phosphorus

Hydroxy radicals reaction with monomers

Hydroxy-bearing radicals, reaction with

Hydroxyl radical reaction with

Hydroxyl radical reaction with alkanes

Hydroxyl radical reaction with bromide

Hydroxyl radical reaction with nitric oxide

Hydroxyl radical reaction with nucleic acids

Hydroxyl radical reaction with nucleobases

Hydroxyl radical reactions with aromatic compounds

Hydroxyl radical reactions with nitrogen oxides

Hydroxyl radical with hydrogen peroxide, reaction

Hydroxyl radicals atom reaction with

Hydroxyl radicals reaction with gaseous

Hydroxyl radicals reactions with hydrocarbons

Hydroxyl radicals, reaction with methane

Hydroxyl reaction with sulfate radical

Imidazoles reaction with alkyl radicals

Indirect Photolysis in the Atmosphere (Troposphere)— Reactions with Hydroxyl Radical (HO)

Inorganic Ion-Radicals in Reactions with Organic Substrates

Intramolecular reactions of 2-indolylacyl radicals with aromatic and heteroaromatic systems

Iron chloride, radical reactions with organic

Isocyanides reactions with radicals

Metal ions reactions with peroxy radicals

Methane reaction with methyl radical

Methyl acrylate reaction with phenyl radicals

Methyl methacrylate reaction with phenyl radicals

Methyl methacrylate reaction with radicals

Methyl radical reaction with hydroxyl

Methyl radical reaction with molecular oxygen

Methyl radicals reaction with propionic acid

Methyl, free-radical transfer reactions with

Methylperoxy radical reaction with

NO3 radical reaction with

Nitrate radical reaction with alcohols

Nitrate radical reaction with alkanes

Nitrate radical reaction with aromatic compound

Nitrate radical reaction with esters

Nitrate radical reaction with ethers

Nitrate radical reaction with inorganic radicals

Nitrate radical reaction with inorganic species

Nitrate radical reaction with isoprene

Nitrate radical reaction with organic compound

Nitrate radical reaction with peroxy radicals

Nitrate radical reactions with unsaturated

Nitrate radical sodium chloride, reaction with

Nitrate radical sulfur , reaction with

Nitric oxide, reaction with radicals

Nitro compounds reaction with hydroxyl radical

Nitrogen reaction with carbonate radical

Nitroxide with alkyl radicals, reaction

Nitroxides reaction with radicals

Nitroxides reactions with thiyl radicals

Olefinic cation radicals, reaction with triplet

Organic peroxy radical reaction with

Oxazole reaction with free radicals

Oxygen radical reactions with

Oxygen reaction with alkyl radicals

Peroxy radical reaction with

Peroxy radicals reactions with organic compounds

Peroxyacetyl radical reaction with

Peroxyl radical reaction with epigallocatechin

Peroxyl radical reaction with epigallocatechin gallate

Peroxyl radical, reaction with nitric oxide

Perylene cation radical, reaction with

Petroleum reactions with hydroxyl radical

Phenyl radicals, reactions rates with substituted

Polar molecules, reactions with ions free radical

Porphyrins reactions with radicals

Propane reaction with hydroxyl radicals

Pulse radiolysis free radical reactions with

Pyrazine reactions with radicals

Pyridines reactions with alkyl radicals

Pyridinium salts reactions with alkyl radicals

Quinaldine reaction with alkyl radicals

Quinoline reaction with alkyl radicals

Quinone diimines reaction with radicals

Quinones reactions with phenoxy radicals

Quinoxaline reactions with radicals

Radical Conversions of p-benzoquinones in Reactions with NO

Radical Reactions of Aromatic Compounds with Captodative Substitution

Radical Reactions of Organic Azides with Tributyltin Hydride

Radical addition reactions with boron compounds

Radical addition reactions with trifluoroacetic acid

Radical anions reactions with

Radical anions reactions with electrophiles

Radical cations reactions with alkenes

Radical paths reactions with neutrals

Radical photochemical reaction with silane

Radical reactions amino acids with peroxidized

Radical reactions with organic halides

Radical reactions with selenium precursors

Radical reactions with unsaturates

Radical reactions with unsaturates isomerization

Radical-cations from arenes reactions with nucleophiles

Radicals reaction with alkenes

Radicals reaction with hydrocarbons

Radicals reaction with silanes

Radicals reaction with tributyltin hydride

Radicals substitution reactions with hydrocarbons

Radicals, coupling reactions with alkyl halides

Radicals, coupling reactions with alkynes

Radicals, reaction with nucleophiles

Radicals, unsaturated, reactions with

Radicals, unsaturated, reactions with nitric oxide

Reaction acylperoxyl radicals with

Reaction of HA with HO Radicals

Reaction of Merocyanines with Free Radicals

Reaction of n-Heptyl Radicals with Tetramethylethylene

Reaction of radical with unsaturated molecule

Reaction with Free Radicals Hydrogen Atom Abstraction and One- or Three-Electron Bonding

Reaction with Kolbe radicals

Reaction with OH radicals

Reaction with Radicals and Electron-deficient Species

Reaction with SO radicals

Reaction with alkyl radicals

Reaction with carbonyl radicals

Reaction with difluoromethyl radical

Reaction with free radicals

Reaction with halogenated methyl radicals

Reaction with methyl radicals

Reaction with nitrate radical

Reaction with nitrogen-bearing radicals

Reactions of 0 anion radicals with electron donors

Reactions of G(-H) Radicals with Nucleophiles

Reactions of Heterocycles with Nucleophilic Radicals

Reactions of Inorganic Radicals with Organic Substrates

Reactions of MA with Free Radicals

Reactions of NO anion radical with electron acceptors

Reactions of Organic Free Radicals with Metal Complexes

Reactions of Radicals with Germanium Hydrides

Reactions of Radicals with Silicon Hydrides

Reactions of Radicals with Tin Hydrides

Reactions of cation radicals with

Reactions of cation radicals with nucleophiles

Reactions of free radicals with hyaluronic acid in simple solutions

Reactions of free radicals with molecular oxygen

Reactions of peroxy radicals with polyfunctional molecules

Reactions with Alkyl and Thiyl Radicals

Reactions with Atoms, Free Radicals and Carbenes

Reactions with Electrophilic Radicals

Reactions with Oxygen- and Nitrogen-containing Radicals

Reactions with Peroxyl Radicals

Reactions with Radical Reagents

Reactions with carbenoids and radicals

Sigma bonds radical reaction with

Silane reaction with silyl radical

Silane reaction with thiyl radical

Silicon radicals reactions with

Specificity Observed in the Reactions of Oxygen-Centered Radicals with Various Monomers at

Structural and biological impact of radical addition reactions with DNA

Subject reaction with carbonate radical

Sulfuric acid reaction with hydroxyl radicals

Superoxide anion radical reaction with FADH

Superoxide reaction with sulfur radicals

Superoxide, reactions, with radicals

The reaction of alkyl radicals with

Thiyl radical reaction with oxygen

Thiyl radical reactions with

Tocopherol reaction with peroxy radical

Toluene reaction with /-butoxy radicals

Triethylsilane, reaction with radicals

Trifluoromethyl radicals reaction with ethylene

Trifluoromethyl radicals reaction with fluoro-olefins

Triphenylmethyl reaction with methyl radicals

Tunneling reactions of biphenyl anion radical with electron acceptor organic molecules

Types of Free Radicals and their Reactions with Nucleic Acids

Vinyl double bonds reaction with secondary radicals

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