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Radicals, unsaturated, reactions with nitric oxide

Much evidence has been accumulated that the ozone-olefin reaction has a predominant role in aerosol formation from alkenes, cyclic olefins, diolefins, and other unsaturated compounds. Free radicals are formed in the reaction and can react further, along with nitric oxide and nitrogen dioxide, either with the various intermediates or with the olefin itself (see the recent review by Pitts and Finlayson ). [Pg.72]

In the presence of various metal ions, 2-(fluoroenone)benzothiazoline has been found to rearrange to A-2-mercaptophenylenimine, while a free radical mechanism involving the homolysis of C-S and C-N bonds has been invoked to explain the formation of 3-phenyl-1,2,4-triazole derivatives from the thermal fragmentation and rearrangement of 2-(arylidenehydrazino)-4-(5//)-thiazolone derivatives. The cycloadducts (36) formed from the reaction of 3-diethylamino-4-(4-methoxyphenyl)-5-vinyl-isothiazole 1,1-dioxide (34) with nitric oxides or miinchnones (35) have been found to undergo pyrolytic transformation into a, jS-unsaturated nitriles (38) by way of pyrrole-isothiazoline 1,1-dioxide intermediates (37). [Pg.502]

For example, the distonic anion radical of cyclopentadienylidene trimethylen-emethane reacts under mass spectrometer gaseous-phase conditions with carbon disulfide by sulfur abstraction and with nitric oxide by NO-radical addition. The first reaction characterizes the distonic anion radical mentioned as a nucleophile bearing a negative charged moiety. The second reaction describes the same anion radical as a species having a group with radical unsaturation (Zhao et al. 1996). [Pg.161]

Sherwood AG, Gunning HE (1963) Reactions of unsaturated Ixee radicals with nitric oxide. Radical-induced scission of caibon-triple bonds. J Am Chem Soc 85(21) 3506-3508... [Pg.110]

When oxides of nitrogen come in contact with water, both nitrous and nitric acids are formed (18) (Table IV). Toxic reactions may result from pH decrease. Other toxic reactions may be a consequence of deamination reactions with amino acids and nucleic acid bases. Another consideration is the reactions of oxides of nitrogen with double bonds (Table IV). The cis-trans isomerization of oleic acid exposed to nitrous acid has been reported (19). Furthermore, the reaction of nitrogen dioxide with unsaturated compounds has resulted in the formation of both transient and stable free radical products (20, 21) (Table V). A further possibility has been raised in that nitrite can react with secondary amines to form nitrosamines which have carcinogenic properties (22). Thus, the possible modes of toxicity for oxides of nitrogen are numerous and are not exhausted by this short list. [Pg.45]


See other pages where Radicals, unsaturated, reactions with nitric oxide is mentioned: [Pg.166]    [Pg.953]    [Pg.953]    [Pg.156]    [Pg.83]    [Pg.21]    [Pg.309]    [Pg.283]    [Pg.290]    [Pg.339]   
See also in sourсe #XX -- [ Pg.286 ]




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Nitric oxide radical

Nitric oxide reaction

Nitric oxide reaction with

Nitric oxide, reaction with radicals

Nitric reaction

Oxidation radical

Oxidative radical reaction

Oxide Radicals

Radical reactions oxidation

Reaction with radicals

Reaction with unsaturated

Reactions unsaturated

Unsaturated oxidation

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