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Carbonyl radicals, reaction with nitric

Since during the Purex process TBP, alkane, and aqueous nitric acid solution are in mixture or contact condition, the radiation chemical transformations depend on the composition, concentration of nitric acid, contaminant metal ions, irradiation conditions, and oxygen concentration (Triphathi and Ramanujam 2003 Katsumura 2004). Under aerated condition, the organic radicals react with oxygen forming peroxy radicals. After successive reactions a variety of alcohols, ketones, peroxides, and carbonyl compounds form. The ratio of nitration products to oxidation products is 0.8, and the ratio increases if there is no sufficient supply of O2. [Pg.1316]

See other pages where Carbonyl radicals, reaction with nitric is mentioned: [Pg.151]    [Pg.715]    [Pg.678]    [Pg.274]    [Pg.164]    [Pg.1565]    [Pg.184]    [Pg.4955]    [Pg.4954]    [Pg.715]    [Pg.20]    [Pg.143]    [Pg.295]    [Pg.829]    [Pg.64]    [Pg.830]    [Pg.212]    [Pg.359]    [Pg.612]   


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Carbonylation radical

Carbonylation reactions, radical

Nitric reaction

Radical carbonylations

Reaction with carbonyl radicals

Reaction with radicals

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