Reactions of peroxy radicals with polyfunctional molecules

Reactions of peroxy radicals with polyfunctional molecules 

Comparison of rate coefficients, experimental (k) and calculated according to the additivity rule (Sfe ), of cumylperoxy radical reactions with esters at 140°C [322,323] 

for the rate coefficient, one will have the equation 

The reaction between RCV and a monofunctional compound may be taken as the reaction for comparison. In this case, AG will be the difference between AG for two and polydipole systems, i.e. the free energy of dipole—dipole interaction in multidipole systems. The value of AG may 

Rate coefficients for the reaction of sec-hexadecylperoxy radicals with alcohols at 130°C 

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