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Radical Reactions of Aromatic Compounds with Captodative Substitution

6 Radical Reactions of Aromatic Compounds with Captodative Substitution [Pg.372]

3-aryl-1-propanol 108d in high yield (90%) and under standard conditions (AIBN, BusSnH) [56], The mechanism involves favorable 5-exo-thg ipso intramolecular attack by 104 to form the captodative spiro hexadienyl radical 106. This is the only pathway followed starting from 103d, whereas for the other substrates 103a-c, where the radical 106 is not captodative, competitive reduction of 104 to form 105 is also observed. [Pg.374]




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Aromatic compounds reactions

Aromatic compounds substituted aromatics

Aromatic compounds substitutents

Aromatic compounds substitution reactions

Aromatic radical substitution

Captodative

Captodative radicals

Captodative substitution

Of aromatic compounds

Radical reaction substitution

Radical reactions aromatic substitution

Radical reactions, aromatic compounds

Radicals 3-substituted

Reaction with aromatic

Reaction with aromatic compounds

Reaction with aromatics

Reaction with radicals

Reactions of radicals

Substituted Compounds

Substituted reaction with

Substitution compounds

Substitution radical

Substitution reactions aromatic

With aromatic compounds

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